Note: Ingredients listed on restricted chemical lists
EC/CAS
14808-60-7
Name of the chemical
Silica, crystalline
Concentration
1-5%
General Information
Version
14
Revision date
2016-08-16
Product name
None HM001882
1.2.1 Relevant identified uses
Cement
supplier name
address and
Emergency telephone
61 1 800 686 951
Icons in SDS
Company Information
company name
Halliburton Australia Pty. Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
fdunexchem@halliburton.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H318, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
Hazard statements
Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG. Classification of the hazardous chemical Skin Corrosion/Irritation Serious Eye Damage/Irritation Category 2 - H315 Category 1 - H318 Skin Sensitization Category 1 - H317 Carcinogenicity Category 2 - H351 Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335 Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373 Label elements, including precautionary statements H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H335 - May cause respiratory irritation H351 - Suspected of causing cancer if inhaled H373 - May cause damage to organs through prolonged or repeated exposure if inhaled
Signal word
Danger
Prevention
P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/eye protection/face protection P281 - Use personal protective equipment as required
Response
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER/doctor/physician if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P308 + P313 - IF exposed or concerned: Get medical advice/attention P314 - Get medical attention/advice if you feel unwell
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up
Disposal
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations
Contains
Substances Portland cement Crystalline silica, quartz CAS Number 65997-15-1 14808-60-7
Other hazards which do not result in classification
None known For the full text of the H-phrases mentioned in this Section, see Section 16
2.1 Classification of the substance or mixture
Classification of the hazardous chemical Skin Corrosion/Irritation Category 2 - H315 Serious Eye Damage/Irritation Category 1 - H318 Skin Sensitization Category 1 - H317 Carcinogenicity Category 2 - H351 Specific Target Organ Toxicity - (Single Exposure) Category 3 - H335 Specific Target Organ Toxicity - (Repeated Exposure) Category 2 - H373 Label elements, including precautionary statements Hazard pictograms Signal Word Danger Hazard Statements: H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H335 - May cause respiratory irritation H351 - Suspected of causing cancer if inhaled H373 - May cause damage to organs through prolonged or repeated exposure if inhaled Precautionary Statements Prevention P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves/eye protection/face protection P281 - Use personal protective equipment as required Response P302 + P352 - IF ON SKIN: Wash with plenty of soap and water P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312 - Call a POISON CENTER/doctor/physician if you feel unwell P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P308 + P313 - IF exposed or concerned: Get medical advice/attention P314 - Get medical attention/advice if you feel unwell Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up Disposal P501 - Dispose of contents/container in accordance with local/regional/national/international regulations Contains Substances CAS Number Portland cement 65997-15-1 Crystalline silica, quartz 14808-60-7 Other hazards which do not result in classification None known For the full text of the H-phrases mentioned in this Section, see Section 16 3. Composition/information on Ingredients Substances CAS Number PERCENT (w/w) GHS Classification - Australia Portland cement 65997-15-1 60 - 100% Skin Irrit. 2 (H315) Eye Corr. 1 (H318) Skin Sens. 1 (H317) STOT SE 3 (H335) Crystalline silica, quartz 14808-60-7 1 - 5% Carc. 2 (H351) STOT RE 1 (H372) 4. First aid measures Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention immediately after flushing. Skin In case of contact, immediately flush skin with plenty of soap and water for at least 30 minutes and remove contaminated clothing, shoes and leather goods immediately. Get medical attention immediately. Ingestion Under normal conditions, first aid procedures are not required. Symptoms caused by exposure Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. May cause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease. Medical Attention and Special Treatment Notes to Physician Treat symptomatically 5. Fire Fighting Measures Suitable extinguishing equipment Suitable Extinguishing Media None - does not burn. Extinguishing media which must not be used for safety reasons None known. Specific hazards arising from the chemical Special exposure hazards in a fire None anticipated Special protective equipment and precautions for fire fighters Special protective equipment for firefighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. 6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. 6.3. Methods and material for containment and cleaning up Collect using dustless method and hold for appropriate disposal. Consider possible toxic or fire hazards associated with contaminating substances and use appropriate methods for collection, storage and disposal. 7. Handling and storage 7.1. Precautions for safe handling Handling Precautions Avoid contact with eyes, skin, or clothing. This product contains quartz, cristobalite, and/or tridymite which may become airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty conditions. Use only with adequate ventilation to keep exposure below recommended exposure limits. Wear a NIOSH certified, European Standard En 149, or equivalent respirator when using this product. Material is slippery when wet. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Storage Information Use good housekeeping in storage and work areas to prevent accumulation of dust. Close container when not in use. Product has a shelf life of 24 months. Store in a cool, dry location. Other Guidelines No information available 8. Exposure Controls/Personal Protection Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Portland cement 65997-15-1 TWA: 10 mg/m3 TWA: 1 mg/m3 Crystalline silica, quartz 14808-60-7 TWA: 0.1 mg/m3 TWA: 0.025 mg/m3 Appropriate engineering controls Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain exposures below applicable exposure limits. Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this product. Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), AS/NZS 1715, or equivalent respirator when using this product. Hand Protection Normal work gloves. Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be laundered before reuse. Use precautionary measures to avoid creating dust when removing or laundering clothing. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions Eyewash fountains and safety showers must be easily accessible. Environmental Exposure Controls No information available 9. Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical State: Solid Color Gray Odor: Odorless Odor Threshold: No information available Property Values Remarks/ - Method pH: 12.4 Freezing Point / Range No data available Melting Point / Range No data available Boiling Point / Range No data available Flash Point No data available Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 3.15 Water Solubility Insoluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available 9.2. Other information VOC Content (%) No data available 10. Stability and Reactivity 10.1. Reactivity Not expected to be reactive. 10.2. Chemical stability Stable 10.3. Possibility of hazardous reactions Will Not Occur 10.4. Conditions to avoid Keep away from any contact with water. 10.5. Incompatible materials Hydrofluoric acid. 10.6. Hazardous decomposition products Amorphous silica may transform at elevated temperatures to tridymite (870 C) or cristobalite (1470 C). 11. Toxicological Information Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation. Symptoms related to exposure Most Important Symptoms/Effects Causes severe eye irritation which may damage tissue. Causes skin irritation. May cause allergic skin reaction. May cause respiratory irritation. Breathing crystalline silica can cause lung disease, including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease. Numerical measures of toxicity Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Portland cement 65997-15-1 > 2000 mg/kg (Rat) > 2000 mg/kg > 1 mg/L (Rat) 4h Crystalline silica, quartz 14808-60-7 > 15000 mg/kg (human) No information available No data available Immediate, delayed and chronic health effects from exposure Inhalation Inhaled crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (IARC, Group 1). There is sufficient evidence in experimental animals for the carcinogenicity of tridymite (IARC, Group 2A). Breathing silica dust may cause irritation of the nose, throat, and respiratory passages. Breathing silica dust may not cause noticeable injury or illness even though permanent lung damage may be occurring. Inhalation of dust may also have serious chronic health effects (See "Chronic Effects/Carcinogenicity" subsection below). Causes severe respiratory irritation. Eye Contact Causes severe eye irritation which may damage tissue. Skin Contact Causes skin irritation. Can dry skin. May cause alkali burns with confined contact. May cause an allergic skin reaction. Ingestion None known. Chronic Effects/Carcinogenicity Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. This disease is exacerbated by smoking. Individuals with silicosis are predisposed to develop tuberculosis. Cancer Status: The International Agency for Research on Cancer (IARC) has determined that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources can cause lung cancer in humans (Group 1 - carcinogenic to humans) and has determined that there is sufficient evidence in experimental animals for the carcinogenicity of tridymite (Group 2A - possible carcinogen to humans). Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibres (June 1997) in conjunction with the use of these minerals. The National Toxicology Program classifies respirable crystalline silica as "Known to be a human carcinogen". Refer to the 9th Report on Carcinogens (2000). The American Conference of Governmental Industrial Hygienists (ACGIH) classifies crystalline silica, quartz, as a suspected human carcinogen (A2). There is some evidence that breathing respirable crystalline silica or the disease silicosis is associated with an increased incidence of significant disease endpoints such as scleroderma (an immune system disorder manifested by scarring of the lungs, skin, and other internal organs) and kidney disease. Exposure Levels No data available Interactive effects Individuals with respiratory disease, including but not limited to asthma and bronchitis, or subject to eye irritation, should not be exposed to quartz dust. Data limitations No data available Substances CAS Number Skin corrosion/irritation Portland cement 65997-15-1 Irritating to skin. (Rabbit) Crystalline silica, quartz 14808-60-7 Non-irritating to the skin Substances CAS Number Serious eye damage/irritation Portland cement 65997-15-1 Corrosive to eyes Crystalline silica, quartz 14808-60-7 Mechanical irritation of the eyes is possible. No information available Substances CAS Number Skin Sensitization Portland cement 65997-15-1 May cause sensitization by skin contact Crystalline silica, quartz 14808-60-7 No information available. Substances CAS Number Respiratory Sensitization Portland cement 65997-15-1 No information available Crystalline silica, quartz 14808-60-7 No information available Substances CAS Number Mutagenic Effects Portland cement 65997-15-1 No data of sufficient quality are available. Crystalline silica, quartz 14808-60-7 Not regarded as mutagenic. Substances CAS Number Carcinogenic Effects Portland cement 65997-15-1 No data of sufficient quality are available. Crystalline silica, quartz 14808-60-7 Contains crystalline silica which may cause silicosis, a delayed and progressive lung disease. The IARC and NTP have determined there is sufficient evidence in humans of the carcinogenicity of crystalline silica with repeated respiratory exposure. Based on available scientific evidence, this substance is a threshold carcinogen with a mode of action involving indirect genotoxicity secondary to lung injury. Substances CAS Number Reproductive toxicity Portland cement 65997-15-1 No data of sufficient quality are available. Crystalline silica, quartz 14808-60-7 No information available Substances CAS Number STOT - single exposure Portland cement 65997-15-1 May cause respiratory irritation. Crystalline silica, quartz 14808-60-7 No significant toxicity observed in animal studies at concentration requiring classification. Substances CAS Number STOT - repeated exposure Portland cement 65997-15-1 No data of sufficient quality are available. Crystalline silica, quartz 14808-60-7 Causes damage to organs through prolonged or repeated exposure if inhaled: (Lungs) Substances CAS Number Aspiration hazard Portland cement 65997-15-1 Not applicable Crystalline silica, quartz 14808-60-7 Not applicable 12. Ecological Information Ecotoxicity Product Ecotoxicity Data No data available Substance Ecotoxicity Data Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates Microorganisms Portland cement 65997-15-1 No information available No information available No information available No information available Crystalline silica, 14808-60-7 EC50 (72 h) =440 mg/L LL0 (96 h) =10000 mg/L No information available LL50 (24 h) >10000 mg/L quartz (Selenastrum (Danio rerio) (Daphnia magna) capricornutum) 12.2. Persistence and degradability Substances CAS Number Persistence and Degradability Portland cement 65997-15-1 The methods for determining biodegradability are not applicable to inorganic substances. Crystalline silica, quartz 14808-60-7 The methods for determining biodegradability are not applicable to inorganic substances. 12.3. Bioaccumulative potential Substances CAS Number Log Pow Portland cement 65997-15-1 No information available Crystalline silica, quartz 14808-60-7 No information available 12.4. Mobility in soil Substances CAS Number Mobility Portland cement 65997-15-1 No information available Crystalline silica, quartz 14808-60-7 No information available 12.6. Other adverse effects Endocrine Disruptor Information This product does not contain any known or suspected endocrine disruptors 13. Disposal Considerations Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations. Disposal of any contaminated packaging Follow all applicable national or local regulations. Environmental regulations Not applicable 14. Transport Information Transportation Information UN Number Not restricted UN proper shipping name: Not restricted Transport Hazard Class(es): Not applicable Packing Group: Not applicable Environmental Hazards: Not applicable Special precautions during transport None HazChem Code None Allocated 15. Regulatory Information Safety, health and environmental regulations specific for the product International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or assessment certificate. New Zealand Inventory of All components are listed on the NZIoC or are subject to a relevant exemption, permit, or Chemicals assessment certificate. EINECS (European Inventory of This product, and all its components, complies with EINECS Existing Chemical Substances) US TSCA Inventory All components listed on inventory or are exempt. Canadian Domestic Substances List All components listed on inventory or are exempt. (DSL) Poisons Schedule number None Allocated International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply Stolkhom Convention - Persistent Organic Pollutants: Does not apply Rotterdam Convention - Prior Informed Consent: Does not apply Basel Convention - Hazardous Waste: Does not apply 16. Other information Date of preparation or review Revision Date: 21-Jun-2016 Revision Note SDS sections updated: 2 Full text of H-Statements referred to under sections 2 and 3 H315 - Causes skin irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H335 - May cause respiratory irritation H351 - Suspected of causing cancer if inhaled H372 - Causes damage to organs through prolonged or repeated exposure if inhaled H373 - May cause damage to organs through prolonged or repeated exposure if inhaled Additional information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at 1-580-251-4335. Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50 – Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed Effect Concentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL – Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 - milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day Key literature references and sources for data www.ChemADVISOR.com/ OSHA ECHA C&L Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. End of Safety Data Sheet Synonyms: None Product Code: HM000901 Recommended use of the chemical and restrictions on use Recommended Use Cement Retarder Uses Advised Against No information available Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd. 15 Marriott Road Jandakot WA 6164 Australia ACN Number: 009 000 775 Telephone Number: + 61 1 800 686 951 Fax Number: 61 (08) 9455 5300 E-Mail address: fdunexchem@halliburton.com Emergency phone number + 61 1 800 686 951 Australian Poisons Information Centre 24 Hour Service: - 13 11 26 Police or Fire Brigade: - 000 (exchange): - 1100 2. Hazard Identification Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the Globally Harmonised System of Classification and Labelling of Chemicals (GHS), Non-Dangerous Goods according to the criteria of ADG. Classification of the hazardous chemical Not classified Label elements, including precautionary statements Hazard Pictograms Signal Word Not Hazardous Hazard Statements Not Classified Precautionary Statements Prevention None Response None Storage None Disposal None Contains Substances CAS Number Contains no hazardous substances in concentrations above NA cut-off values according to the competent authority Other hazards which do not result in classification None known Australia Classification For the full text of the H-phrases mentioned in this Section, see Section 16 Classification Not Classified Risk Phrases None 3. Composition/information on Ingredients Substances CAS Number PERCENT (w/w) GHS Classification - Australia Contains no hazardous substances in concentrations NA 60 - 100% Not Applicable above cut-off values according to the competent authority 4. First aid measures Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Eyes In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Skin Wash with soap and water. Get medical attention if irritation persists. Ingestion Under normal conditions, first aid procedures are not required. Symptoms caused by exposure No significant hazards expected. Medical Attention and Special Treatment Notes to Physician Treat symptomatically 5. Fire Fighting Measures Suitable extinguishing equipment Suitable Extinguishing Media Water fog, carbon dioxide, foam, dry chemical. Extinguishing media which must not be used for safety reasons None known. Specific hazards arising from the chemical Special Exposure Hazards Decomposition in fire may produce harmful gases. Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. 6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas. 6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove. 7. Handling and storage 7.1. Precautions for Safe Handling Handling Precautions Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 7.2. Conditions for safe storage, including any incompatibilities Storage Information Store away from oxidizers. Keep container closed when not in use. Other Guidelines No information available 8. Exposure Controls/Personal Protection Control parameters - exposure standards, biological monitoring Exposure Limits Substances CAS Number Australia NOHSC ACGIH TLV-TWA Contains no hazardous substances in NA Not applicable concentrations above cut-off values according to the competent authority Appropriate engineering controls Engineering Controls Use in a well ventilated area. Personal protective equipment (PPE) Respiratory Protection Not normally necessary. Hand Protection Normal work gloves. Skin Protection Normal work coveralls. Eye Protection Wear safety glasses or goggles to protect against exposure. Other Precautions None known. Environmental Exposure Controls No information available 9. Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical State: Liquid Color: Dark brown Odor: Molasses Odor Threshold: No information available Property Values Remarks/ - Method pH: 9.5 Freezing Point/Range No data available Melting Point/Range No data available Boiling Point/Range No data available Flash Point > 98 °C / > 210 °F PMCC Evaporation rate No data available Vapor Pressure No data available Vapor Density No data available Specific Gravity 1.21 Water Solubility Soluble in water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition Temperature No data available Decomposition Temperature No data available Viscosity No data available Explosive Properties No information available Oxidizing Properties No information available 9.2. Other information VOC Content (%) No data available Liquid Density 10.08 lbs/gal 10. Stability and Reactivity 10.1. Reactivity Not expected to be reactive. 10.2. Chemical Stability Stable 10.3. Possibility of Hazardous Reactions Will Not Occur 10.4. Conditions to Avoid None anticipated 10.5. Incompatible Materials Strong oxidizers. 10.6. Hazardous Decomposition Products Oxides of sulfur. Carbon monoxide and carbon dioxide. 11. Toxicological Information Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation. Sympotoms related to exposure Most Important Symptoms/Effects No significant hazards expected. Numerical measures of toxicity Toxicology data for the components Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation Contains no hazardous NA No data available substances in concentrations above cut-off values according to the competent authority Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation. Eye Contact May cause mild eye irritation. Skin Contact None known. Ingestion None known. Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1% are chronic health hazards. Exposure Levels No data available Interactive effects None known. Data limitations No data available Substances CAS Number Skin corrosion/irritation Contains no hazardous NA Not applicable. substances in concentrations above cut-off values according to the competent authority Substances CAS Number Eye damage/irritation Contains no hazardous NA Not applicable. substances in concentrations above cut-off values according to the competent authority Substances CAS Number Skin Sensitization Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority Substances CAS Number Respiratory Sensitization Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority Substances CAS Number Mutagenic Effects Contains no hazardous NA Not applicable substances in concentrations above cut-off values according to the competent authority