Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2020-08-26
Product name
GorillaPro PU5 Part A
CAS No.
101-68-8
1.2.1 Relevant identified uses
Isocyanate based product
Icons in SDS
Company Information
company name
H.B. Fuller Engineering Adhesives
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
OSHA Emergency Overview Appearance liquid Color light yellow Odor characteristic
2.1 Classification of the substance or mixture
Acute toxicity (Inhalation) : Category 4 Skin irritation : Category 2 Eye irritation : Category 2A Respiratory sensitization : Category 1 Skin sensitization : Category 1 Specific target organ toxicity - : Category 3 (Respiratory system) single exposure Specific target organ toxicity - : Category 2 (Respiratory Tract) repeated exposure (Inhalation)
Signal word
Danger
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs (Respiratory Tract) through prolonged or repeated exposure if inhaled.
Prevention
P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing must not be allowed out of the workplace. P280 Wear protective gloves/ eye protection/ face protection. P285 In case of inadequate ventilation wear respiratory protection.
Response
P302 + P352 IF ON SKIN Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists Get medical advice/ attention. P342 + P311 If experiencing respiratory symptoms Call a POISON CENTER/ doctor. P362 Take off contaminated clothing and wash before reuse.
Storage
P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant
Medical Conditions Generally Aggravated by Exposure
None known. Symptoms of Overexposure : Breathing difficulties Carcinogenicity: IARC No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA’s list of regulated carcinogens. NTP No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP.