Note: Ingredients listed on restricted chemical lists
General Information
Version
V1.0.0.1
Revision date
2019-07-31
Product name
Colour Tattoos
REACH No
applicable
1.2.1 Relevant identified uses
Please consult manufacturer
1.2.2. Uses advised against
Please consult manufacturer
Icons in SDS
Company Information
company name
Guangzhou Fitprint Enterprise., Ltd
e-mail address of the competent person responsible for the Safety Data Sheet
sale@tiebeauty.com.cn
GHS Information
Signal word
Not applicable
Section 2
SECTION 2: Hazards identification
Hazard pictograms
Not applicable None
Signal word
Not applicable Not applicable
Hazard statements
Not applicable Not applicable
Prevention
Not applicable Not applicable
Response
Not applicable Not applicable
Storage
Not applicable Not applicable
Disposal
Not applicable Not applicable
2.3 Other hazards
Not applicable 3 Component Component Cas No. EC No. Ethylene/Acrylic Acid 9010-77-9 - Copolymer Cellulose Acetate 9004-36-8 - Butyrate Dipropylene glycol 27138-31-4 248-258-5 dibenzoate Sucrose acetate iso- 126-13-6 204-771-6 butyrate Paraffinum liquidum 8012-95-1 232-384-2 Acetyl Tributyl CitrateI 77-90-7 201-067-0 Isobornyl Acrylate 5888-33-5 227-561-6 Polyurethane butyral 63148-65-2 272-808-3 Glycine Soja Oil 8001-22-7 232-274-4 Glyceryl Rosinate 8050-31-5 232-482-5 Titanium dioxide 13463-67-7 236-675-5 Red 7 5281-4-9 226-109-5 Black Iron Oxide 12227-89-3 235-442-5 FD&C blue 1 3844-45-9 223-339-8 FD&C yellow 5 1934-21-0 217-699-5 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 - Not Classified 77.8 - Not Classified 10 - Not Classified 2.5 - Not Classified 1.5 - Not Classified 1.7 - Not Classified 1.2 - Not Classified 0.8 - Not Classified 0.8 - Not Classified 0.6 - Not Classified 0.6 - Not Classified 0.5 - Not Classified 0.5 - Not Classified 0.5 - Not Classified 0.5 - Not Classified Version V1.0.0.1 Revision Date: 2019/07/31 4 First aid measures |Description of first aid measures General advice Immediate medical attention is required. Show this safety data sheet (SDS) to the doctor in attendance. Eye contact First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. Skin contact Rinse skin with plenty of water or shower. Ingestion Rinse mouth. Inhalation Fresh air, rest. Protecting of first-aiders Ensure that medical personnel are aware of the substance involved. Take precautions to protect themselves and prevent spread of contamination. | Most important symptoms and effects, both acute and delayed 1 Please see section 11. | Indication of any immediate medical attention and special treatment needed 1 Treat symptomatically. 2 Symptoms may be delayed. 5 Firefighting measures | Extinguishing media Suitable extinguishing Use extinguishing media suitable for surrounding area. media Unsuitable There is no restriction on the type of extinguisher which may be used. extinguishing media Specific hazards arising from the substance or mixture Not combustible, not considered a significant fire risk, however containers may burn Development of hazardous combustion gases or vapor possible in the event of fire Advice for firefighters As in any fire, wear self-contained breathing apparatus(MSHA/NIOSH approved or equivalent) and full protective gear Fight fire from a safe distance, with adequate cover Prevent fire extinguishing water from contaminating surface water or the ground water system Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak Use personal protective equipment. Avoid breathing vapours, mist or gas Environmental precautions Prevent further leakage or spillage if safe to do so Discharge into the environment must be avoided Methods and materials for containment and cleaning up Version : V1.0.0.1 Revision Date : 2019/07/31 Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a spill by bunding Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment Handling and storage Precautions for handling Protective measures Handling is performed in a well-ventilated place Avoid contact with skin and eyes Measures to prevent fire Keep away from heat/sparks/open flames/ hot surfaces Measures to prevent aerosol and dust generation Avoid formation of dust and aerosols Provide appropriate exhaust ventilation at places where dust is formed Advice on general occupational hygiene Wash hands and face after using of the substances Replace the contaminated clothing immediately Conditions for safe storage, including any incompatibilities Keep containers tightly closed Keep containers in a dry, cool and well-ventilated place Keep away from heat/sparks/open flames/hot surfaces Store away from incompatible materials and foodstuff containers Specific end uses In addition to use mentioned in the first parts, unforeseen other specific end uses Exposure controls/personal protection Control parameters Occupational Exposure limit values Component Country/Region Limit value - Eight hours Limit value - Short term ppm mg/m³ ppm mg/m³
Product definition
Product Name Tattoo Wipes CAS No. —— EC No. —— Molecular Formula —— Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use for skins Uses advised against Use for skins Details of the supplier of the Safety Data Sheet Name of the company Guangzhou Fitprint Enterprise.,Ltd Address of the Building A3, No.,17 Tangxi Road, Tangbian Village, Shapu, Xintang Town, company Zengcheng District, Guangzhou Post code 510663 Telephone number 020-32199898 Fax number 020-32199898 E-mail address sale@tiebeauty.com.cn Emergency phone number Emergency phone 020-32199898 number Hazards identification
Precautionary statements
1/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 14 of 22
Other hazards
Not applicable 3 Component Component Cas No. EC No. Index No.
2.1 Classification of the substance or mixture
1 Not combustible, not considered a significant fire risk, however containers may burn. 2 Development of hazardous combustion gases or vapor possible in the event of fire. | Advice for firefighters 1 As in any fire, wear self-contained breathing apparatus(MSHA/NIOSH approved or equivalent) and full protective gear. 2 Fight fire from a safe distance, with adequate cover. 3 Prevent fire extinguishing water from contaminating surface water or the ground water system. 6 Accidental release measures | Personal precautions, protective equipment and emergency procedures 1 Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. 2 Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. 3 Use personal protective equipment. Avoid breathing vapours, mist or gas. | Environmental precautions 1 Prevent further leakage or spillage if safe to do so. 2 Discharge into the environment must be avoided. | Methods and materials for containment and cleaning up Version:V1.0.0.1 Revision Date:2019/07/31 1 Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a spill by bunding. 2 Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations. 3 Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. 7 Handling and storage | Precautions for handling Protective measures 1 Handling is performed in a well-ventilated place. 2 Avoid contact with skin and eyes. Measures to prevent fire 1 Keep away from heat/sparks/open flames/ hot surfaces. Measures to prevent aerosol and dust generation 1 Avoid formation of dust and aerosols. 2 Provide appropriate exhaust ventilation at places where dust is formed. Advice on general occupational hygiene 1 Wash hands and face after using of the substances. 2 Replace the contaminated clothing immediately. | Conditions for safe storage, including any incompatibilities 1 Keep containers tightly closed. 2 Keep containers in a dry, cool and well-ventilated place. 3 Keep away from heat/sparks/open flames/hot surfaces. 4 Store away from incompatible materials and foodstuff containers. | Specific end uses 1 In addition to use mentioned in the first parts, unforeseen other specific end uses. 8 Exposure controls/personal protection | Control parameters Occupational Exposure limit values Component Country/Region Limit value - Eight hours Limit value - Short term ppm mg/m³ ppm mg/m³ USA - OSHA - 15 - Titanium dioxide South Korea - 10 - 13463-67-7 Ireland - 10 - France - 11 - Denmark - 6 - 12 Australia - 10 - Version:V1.0.0.1 Revision Date:2019/07/31 Biological limit values Biological limit values No relevant regulations Monitoring methods EN 14042 Workplace atmospheres. Guide for the application and use of procedures for the assessment 1 of exposure to chemical and biological agents. 2 GBZ/T 160.1~GBZ/T 160.81-2004 Determination of toxic substances in workplace air(Series standard). Derived No effect level(DNEL) Component Route of DNEL for Workers exposure Acute effects Chronic effects (local) (systemic) (local) (systemic) 9010-77-9 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 9004-36-8 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 27138-31-4 Inhalation No data available No data available No data available 1.7 mg/m3 Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 126-13-6 Inhalation No data available No data available 2 mg/m3 1~2 mg/m3 Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 8012-95-1 Inhalation No data available 10 mg/m3 Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 77-90-7 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 5888-33-5 Inhalation No data available 10 mg/m3 No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 63148-65-2 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 8001-22-7 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 8050-31-5 Inhalation No data available No data available No data available No data available Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 13463-67-7 Inhalation No data available 4.4 mg/m3 Oral No data available No data available No data available No data available Dermal No data available No data available No data available No data available 5281-4-9 Inhalation No data available 10 mg/m3 Oral No data available No data available No data available No data available Version:V1.0.0.1 Revision Date:2019/07/31 Dermal No data available 12227-89-3 Inhalation No data available Oral No data available Dermal No data available 3844-45-9 Inhalation No data available 4 mg/m3 Oral No data available Dermal No data available 1934-21-0 Inhalation No data available 10 mg/m3 Oral No data available Dermal No data available Predicted No Effect Concentration(PNEC) Predicted No Effect Concentration(PNEC) No information available | Engineering controls 1 Ensure adequate ventilation, especially in confined areas. 2 Ensure that eyewash stations and safety showers are close to the workstation location. 3 Use explosion-proof electrical/ventilating/lighting/equipment. 4 Set up emergency exit and necessary risk-elimination area. | Personal protection equipment General requirement No special requirements, please see the description below. Eye protection In general situation, eye protection is not needed. In the production process, when contacting with dust, tightly fitting safety goggles (approved by EN 166(EU) or NIOSH (US). Hand protection In general situation, hand protection is not needed. Respiratory protection In general situation, respiratory protection is not needed. If exposure limits are exceeded or if irritation or other symptoms are experienced, use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges. Skin and body In general situation, skin and body protection are not needed. protection 9 Physical and chemical properties | Physical and chemical properties Appearance Colorful Solid. Odor Odorless Odor threshold No information available pH No information available Melting point/freezing No information available point(℃ ) Initial boiling point and No information available boiling range(℃ ) Flash point(Closed Not applicable cup,℃ ) Evaporation rate Not applicable Flammability No information available Version:V1.0.0.1 Revision Date:2019/07/31 Upper/lower explosive Upper limit:No information available;Lower limit:No information available limits[%(v/v)] Vapor pressure Not applicable Vapor density(Air=1) Not applicable Relative No information available density(Water=1) Solubility(mg/L) No information available n-octanol/water No information available partition coefficient Auto-ignition No information available temperature(℃) Decomposition No information available temperature(℃) Viscosity(mm2 /s) Not applicable Explosive properties Not explosive Oxidizing properties Not oxidizing Version:V1.0.0.1 Revision Date:2019/07/31 10 Stability and reactivity | Stability and reactivity Reactivity Contact with incompatible substances can cause decomposition or other chemical reactions. Chemical stability Stable under proper operation and storage conditions. Possibility of hazardous Reacts with active metals and poses an explosive potential or fire. reactions Conditions to avoid Incompatible materials, heat, flame and spark. Incompatible materials Active metal, alcohols, aldehydes, carbon disulfide, carbon, sulfur, phosphorus, boron, reducing agents, metallic acetylenes and metallic carbonates. Hazardous Under normal conditions of storage and use, hazardous decomposition products decomposition products should not be produced. 11 Toxicological information | Acute toxicity Acute No information available toxicity | Carcinogenicity ID Cas No. Component IARC NTP 1 9010-77-9 Ethylene/Acrylic Acid Copolymer Not Listed 2 9004-36-8 Cellulose Acetate Butyrate Not Listed 3 27138-31-4 Dipropylene glycol dibenzoate Not Listed 4 126-13-6 Sucrose acetate iso-butyrate Not Listed 5 8012-95-1 Paraffinum liquidum Not Listed 6 77-90-7 Acetyl Tributyl CitrateI Not Listed 7 5888-33-5 Isobornyl Acrylate Not Listed 8 63148-65-2 Polyurethane butyral Not Listed 9 8001-22-7 Glycine Soja Oil Not Listed 10 8050-31-5 Glyceryl Rosinate Not Listed 11 13463-67-7 Titanium dioxide Not Listed 12 5281-4-9 Red 7 Not Listed 13 12227-89-3 Black Iron Oxide Not Listed 14 3844-45-9 FD&C blue 1 Not Listed 15 1934-21-0 FD&C yellow 5 Not Listed Version:V1.0.0.1 Revision Date:2019/07/31 | Others Skin corrosion/irritation Based on available data, the classification criteria are not met Serious eye Based on available data, the classification criteria are not met damage/irritation Skin sensitization Based on available data, the classification criteria are not met Respiratory sensitization Based on available data, the classification criteria are not met Reproductive toxicity Based on available data, the classification criteria are not met STOT-single exposure Based on available data, the classification criteria are not met STOT-repeated exposure Based on available data, the classification criteria are not met Aspiration hazard Based on available data, the classification criteria are not met Germ cell mutagenicity Based on available data, the classification criteria are not met Reproductive Based on available data, the classification criteria are not met toxicity(additional) 12 Ecological information | Acute aquatic toxicity Acute aquatic toxicity No information available | Chronic aquatic toxicity Chronic aquatic toxicity No information available | Persistence and degradability Chronic aquatic toxicity No information available | Bioaccumulative potential Chronic aquatic toxicity No information available | Mobility in soil Chronic aquatic toxicity No information available Version:V1.0.0.1 Revision Date:2019/07/31 | Results of PBT and vPvB assessment Component Cas No. Results of PBT and vPvB assessment (according to (EC) No 2015/830) Ethylene/Acrylic Acid Copolymer 9010-77-9 not PBT/vPvB Cellulose Acetate Butyrate 9004-36-8 not PBT/vPvB Dipropylene glycol dibenzoate 27138-31-4 not PBT/vPvB Sucrose acetate iso-butyrate 126-13-6 not PBT/vPvB Paraffinum liquidum 8012-95-1 not PBT/vPvB Acetyl Tributyl CitrateI 77-90-7 not PBT/vPvB Isobornyl Acrylate 5888-33-5 not PBT/vPvB Polyurethane butyral 63148-65-2 not PBT/vPvB Glycine Soja Oil 8001-22-7 not PBT/vPvB Glyceryl Rosinate 8050-31-5 not PBT/vPvB Titanium dioxide 13463-67-7 not PBT/vPvB Red 7 5281-4-9 not PBT/vPvB Black Iron Oxide 12227-89-3 not PBT/vPvB FD&C blue 1 3844-45-9 not PBT/vPvB FD&C yellow 5 1934-21-0 not PBT/vPvB 13 Disposal considerations | Disposal considerations Waste chemicals Before disposal should refer to the relevant national and local laws and regulation. Recommend the use of incineration disposal. Contaminated Containers may still present chemical hazard when empty. Keep away from hot packaging and ignition source of fire. Return to supplier for recycling if possible. Disposal Refer to section 13.1and 13.2. recommendations 14 Transport information | Label and Mark Transporting Label Not applicable | IMDG-CODE IMDG- NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS CODE | ICAO/IATA-DGR ICAO/IATA- NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS DGR | UN-ADR UN-ADR NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Version:V1.0.0.1 Revision Date:2019/07/31 15 Regulatory information | International chemical inventory Component EINECS TSCA DSL IECSC NZIoC PICCS KECI AICS ENCS Dipropylene glycol dibenzoate × √ Sucrose acetate iso-butyrate × √ Paraffinum liquidum √ Acetyl Tributyl CitrateI √ Isobornyl Acrylate × √ × Polyurethane butyral × Glycine Soja Oil √ × Glyceryl Rosinate √ Titanium dioxide √ Red 7 √ Black Iron Oxide √ FD&C blue 1 √ FD&C yellow 5 √ 【 EINECS 】 European Inventory of Existing Commercial Chemical Substances 【TSCA】 United States Toxic Substances Control Act Inventory 【DSL】 Canadian Domestic Substances List 【 IECSC 】 China Inventory of Existing Chemical Substances 【 NZIoC 】 New Zealand Inventory of Chemicals 【 PICCS 】 Philippines Inventory of Chemicals and Chemical Substances 【KECI】 Existing and Evaluated Chemical Substances 【AICS】 Australia Inventory of Chemical Substances 【ENCS】 Existing And New Chemical Substances Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 11 / 11 13 of 22 Version:V1.0.0.1 Revision Date:2019/07/31 | European chemical inventory Component A B C D E F G Dipropylene glycol dibenzoate × √ × Sucrose acetate iso-butyrate × √ × Paraffinum liquidum × √ × Acetyl Tributyl CitrateI × √ × Isobornyl Acrylate × √ × Polyurethane butyral × √ × Glycine Soja Oil × √ × Glyceryl Rosinate × √ × Titanium dioxide × √ × Red 7 × √ × Black Iron Oxide × √ × FD&C blue 1 × √ × FD&C yellow 5 × √ × 【A】 Candidate list of Substances of Very High Concern for authorization under EU REACh regulation 【 B 】 Substances requiring authorisation under EU REACh regulation 【 C 】 Substances restricted under EU REACh 【 D 】 Pre-registered substances under EU REACh 【 E 】 Registered substances under EU REACh 【 F 】 Substance Evaluation – CoRAP under EU REACh 【G】 List of priority substances under EU water policy (Directive 2455/2001/EC) Note “√” Indicates that the substance included in the regulations “×” That no data or included in the regulations Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 12 of 22 12 / 13 Version:V1.0.0.1 Revision Date:2019/07/31 16 Others | Information on revision Creation Date 2019/07/31 Revision Date 2019/07/31 Reason for revision - | Reference [1]IPCS: The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home. [2]IARC,website: http://www.iarc.fr/. [3]OECD: The Global Portal to Information on Chemical Substances, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en. [4]CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple. [5]NLM: ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp. [6]EPA: Integrated Risk Information System, website: http://cfpub.epa.gov/iris/. [7]U.S. Department of Transportation: ERG, website: http://www.phmsa.dot.gov/hazmat/library/erg. [8]Germany GESTIS-database on hazard substance, website: http://gestis-en.itrust.de/. | Abbreviations and acronyms CAS –Chemical Abstracts Service CMR - Carcinogens, mutagens or substances toxic to reproduction PC-STEL- Short term exposure limit PC-TWA - Time Weighted Average DNEL - Derived No Effect Level IARC - International Agency for Research on Cancer RPE - Respiratory Protective Equipment PNEC –Predicted No Effect Concentration LC50 - Lethal Concentration 50% LD50 - Lethal Dose 50% NOEC -No Observed Effect Concentration EC50 - Effective Concentration 50% PBT - Persistent, Bioaccumulative, Toxic POW - Partition coefficient Octanol: Water BCF - Bioconcentration factor (BCF) vPvB - very Persistent, very Bioaccumulative IMDG-International Maritime Dangerous Goods ICAO/IATA-International Civil Aviation Organization/International Air Transportation Association UN-The United Nations ACGIH-American Conference of Governmental Industrial Hygienists NFPA-National Fire Protection Association OECD-Organization for Economic Co-operation and Development | Disclaimer This Safety Data Sheet (SDS) was prepared according to REACh Regulation. The data included was derived from international authoritative database and provided by the enterprise. Other information was based on the present state of our knowledge. We try to ensure the correctness of all information. However, due to the diversity of information sources and the limitations of our knowledge, this document is only for user’s reference. Users should make their independent judgment of suitability of this information for their particular purposes. We do not assume responsibility for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. 13 / 13 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 13 of 22 Version:V1.0.0.1 Creation Date:2019/06/25 Revision Date:2019/06/25 *Prepared according to EU regulation No. 2015/830 1 Identification of the substance/mixture and of the company/undertaking | Product identifier Product Name Tattoo Wipes CAS No. —— EC No. —— Molecular Formula —— | Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use for skins. Uses advised against Use for skins. | Details of the supplier of the Safety Data Sheet Name of the company Guangzhou Fitprint Enterprise.,Ltd Address of the Building A3, No.,17 Tangxi Road, Tangbian Village, Shapu, Xintang Town, company Zengcheng District, Guangzhou. Post code 510663 Telephone number 020-32199898 Fax number 020-32199898 E-mail address sale@tiebeauty.com.cn | Emergency phone number Emergency phone 020-32199898 number 2 Hazards identification | CLP classification according to Regulation(EC)No. 1272/2008 According to Regulation (EC) No 1272/2008 and its amendments. Not classified as a dangerous substance. | Label elements Hazard pictograms None | Hazard statements Signal word Not applicable Hazard statements Not applicable | Precautionary statements 1/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 14 of 22 Prevention Prevention Not applicable Response Response Not applicable Storage Storage Not applicable Disposal Disposal Not applicable | Other hazards Not applicable 3 Component Component Cas No. EC No. Index No. Hazard Concentrati on classification (weight according to CLP percent, %) Isopropyl Pamitate 142-91-6 205-571-1 - Not Classified 86.30 Glycerine 56-81-5 - Not Classified 10.62 Butyl butoxyacetate 10397-22-5 - Not Classified 3.00 Lemon oil 8008-56-8 289-753-6 - Not Classified 0.08 4 First aid measures |Description of first aid measures General advice Immediate medical attention is required. Show this safety data sheet (SDS) to the doctor in attendance. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician if feel uncomfortable. Skin contact Take off contaminated clothing and shoes immediately. Wash off with plenty of water for at least 15 minutes and consult a physician if feel uncomfortable. Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or Poison Control Center immediately. Move victim into fresh air. If breathing is difficult, give oxygen. Do not use mouth to Inhalation mouth resuscitation if victim ingested or inhaled the substance. If not breathing, give artificial respiration and consult a physician immediately. Protecting of first-aiders Ensure that medical personnel are aware of the substance involved. Take precautions to protect themselves and prevent spread of contamination. | Most important symptoms and effects, both acute and delayed 1 Please see section 11. | Indication of any immediate medical attention and special treatment needed 1 Treat symptomatically. 2 Symptoms may be delayed. 5 Firefighting measures 2/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 15 of 22 | Extinguishing media Suitable extinguishing Use extinguishing media suitable for surrounding area. media Unsuitable extinguishing There is no restriction on the type of extinguisher which may be used. media | Specific hazards arising from the substance or mixture 1 Not flammable, not considered a significant fire risk, however containers may burn. | Advice for firefighters 1 As in any fire, wear self-contained breathing apparatus(MSHA/NIOSH approved or equivalent) and full protective gear. 2 Fight fire from a safe distance, with adequate cover. 3 Prevent fire extinguishing water from contaminating surface water or the ground water system. | Personal precautions, protective equipment and emergency procedures 1 Ensure adequate ventilation. Remove all sources of ignition. Take precautionary measures against static discharges. 2 Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. 3 Use personal protective equipment. Avoid breathing vapours, mist, gas or dust. 6 Accidental release measures | Environmental precautions 1 Prevent further leakage or spillage if safe to do so. 2 Discharge into the environment must be avoided. | Methods and materials for containment and cleaning up 1 Absorb spilled material in dry sand or inert absorbent. In case of large amount of spillage, contain a spill by bunding. 2 Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations. 3 Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. 7 Handling and storage | Precautions for handling Protective measures 1 Handling is performed in a well ventilated place. 2 Wear suitable protective equipment. 3 Avoid contact with skin and eyes. Measures to prevent fire 1 Keep away from heat/sparks/open flames/ hot surfaces. Measures to prevent aerosol and dust generation 1 Avoid formation of dust and aerosols. 2 Provide appropriate exhaust ventilation at places where dust is formed. Advice on general occupational hygiene 1 Wash hands and face after using of the substances. 2 Replace the contaminated clothing immediately. 3/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 16 of 22 | Conditions for safe storage, including any incompatibilities 1 Keep containers tightly closed . 2 Keep containers in a dry, cool and well-ventilated place. 3 Keep away from heat/sparks/open flames/hot surfaces. 4 Store away from incompatible materials and foodstuff containers. | Specific end uses 1 In addition to use mentioned in the first parts, unforeseen other specific end uses. 8 Exposure controls/personal protection | Control parameters Occupational Exposure limit values Occupational Exposure limit No information available values Biological limit values Biological limit values No information available Monitoring methods EN 14042 Workplace atmospheres. Guide for the application and use of procedures for the assessment 1 of exposure to chemical and biological agents. 2 GBZ/T 160.1~GBZ/T 160.81-2004 Determination of toxic substances in workplace air(Series standard). Derived No effect level(DNEL) Cas No. Route of DNEL for Workers exposure Acute effects Chronic effects (local) (systemic) (local) (systemic) Inhalation No data available 142-91-6 Oral No data available Dermal No data available Inhalation No data available 56-81-5
Principle Routes of Exposure
DNEL for Workers Acute effects
Potential chronic health
(local) (systemic) (local) (systemic) Inhalation No data available 142-91-6 Oral No data available Dermal No data available Inhalation No data available 56-81-5 Oral No data available Dermal No data available Inhalation No data available 10397-22-5 Oral No data available Dermal No data available Inhalation No data available 8008-56-8 Oral No data available Dermal No data available Predicted No Effect Concentration(PNEC) Predicted No Effect Concentration(PNEC) No information available | Engineering controls 1 Ensure adequate ventilation, especially in confined areas. 2 Ensure that eyewash stations and safety showers are close to the workstation location. 3 Use explosion-proof electrical/ventilating/lighting/equipment. 4/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 4 Set up emergency exit and necessary risk-elimination area. Page 17 of 22 | Personal protection equipment General requirement Eye protection Tightly fitting safety goggles (approved by EN 166(EU) or NIOSH (US). Hand protection Wear protective glove( s such as butyl rubber), passing the tests according to EN 374(EU), US F739 or AS/NZS 2161.1 standard. Respiratory protection If exposure limits are exceeded or if irritation or other symptoms are experienced, use a full-face respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges. Skin and body protection Wear fire/flame resistant/retardant clothing and antistatic boots. 9 Physical and chemical properties | Physical and chemical properties Appearance Colorless liquid Odor Weak odor Odor threshold No information available pH No information available Melting point/freezing No information available point(℃ ) Initial boiling point and No information available boiling range(℃ ) Flash point(Closed No information available cup,℃) Evaporation rate No information available Flammability Not flammable Upper/lower explosive Upper limit No information available;Lower limit No information available limits[%(v/v)] Vapor pressure No information available Vapor density(Air=1) No information available Relative 0.86-0.95 density(Water=1) Solubility(mg/L) Miscible with water n-octanol/water No information available partition coefficient Auto-ignition No information available temperature(℃) Decomposition No information available temperature(℃) Viscosity(mm2/s) No information available Explosive properties Not explosive Oxidizing properties Not oxidizing 10 Stability and reactivity 5/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 18 of 22 | Stability and reactivity Reactivity Contact with incompatible substances can cause decomposition or other chemical reactions. Chemical stability Stable under proper operation and storage conditions. Possibility of hazardous In contact with oxidants causes severe reactions, and may cause a fire or explosion. In contact with active metals (alkali metals, Na, Ca etc.) causes a reactions reaction and release hydrogen. Conditions to avoid Incompatible materials, heat, flame and spark. Incompatible materials Oxidants, alkali metals, alkaline earth metals and aluminum. Alkali, sodium, calcium, and other active metal, halogen, metal oxide, nonmetal oxide, acyl halide and metal phosphide. Hazardous Under normal conditions of storage and use, hazardous decomposition decomposition products products should not be produced. 11 Toxicological information | Acute toxicity No information available Acute toxicity | Carcinogenicity ID Cas No. Component IARC NTP 1 142-91-6 Isopropyl Pamitate Not Listed 2 56-81-5 Glycerine Not Listed 3 10397-22-5 Butyl butoxyacetate Not Listed 8008-56-8 Lemon oil Not Listed |Others Skin corrosion/irritation Based on available data, the classification criteria are not met Serious eye Based on available data, the classification criteria are not met damage/irritation Skin sensitization Based on available data, the classification criteria are not met Respiratory sensitization Based on available data, the classification criteria are not met Reproductive toxicity Based on available data, the classification criteria are not met STOT-single exposure Based on available data, the classification criteria are not met STOT-repeated exposure Based on available data, the classification criteria are not met Aspiration hazard Based on available data, the classification criteria are not met Germ cell mutagenicity Based on available data, the classification criteria are not met Reproductive Based on available data, the classification criteria are not met toxicity(additional) 12 Ecological information | Acute aquatic toxicity Acute aquatic toxicity No information available 6/9 Item Numbers: 81397-1001, 81397-1002, 81397-1003, 81397-1004 Page 19 of 22 | Chronic aquatic toxicity Chronic aquatic toxicity No information available