Do not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. Not applicable. - CAS NUMBER: Chemical Abstract Service Number As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is 7.3. Specific end use(s). The vapours may also form explosive mixtures with the air. INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly - CE50: Effective concentration (required to induce a 50% effect)

2.1 Classification of the substance or mixture

well aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable STOT - REPEATED EXPOSURE. 14.4. Packing group. authorised by a doctor. Information not available. - CE NUMBER: Identifier in ESIS (European archive of existing substances) standards. Does not meet the classification criteria for this hazard class. ACETIC ACID INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops - CLP: EC Regulation 1272/2008 The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). HAND PROTECTION ACETIC ACID risk of explosion on contact with chromium (IV) oxide, potassium permanganate, sodium peroxide, perchloric acid, The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). breathing, administer artificial respiration. Take suitable precautions for rescue workers. - DNEL: Derived No Effect Level Protect hands with category III work gloves (see standard EN 374).

Aspiration hazard

Not applicable. SECTION 8. Exposure controls/personal protection. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data phosphorus chloride, hydrogen peroxide. Can react dangerously with: alcohols, bromine pentafluoride, chlorosulphuric acid, However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data - EmS: Emergency Schedule The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. Does not meet the classification criteria for this hazard class. sheet with appropriate information, compliant to EC Regulation 1907/2006 and subsequent amendments. 4.2. Most important symptoms and effects, both acute and delayed.

Environmental hazards

dichromate-sulphuric acid, ethane diamine, ethylene glycol, potassium hydroxide, strong bases, sodium hydroxide, strong oxidising agent, - GHS: Globally Harmonized System of classification and labeling of chemicals 8.1. Control parameters. The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on nitric acid, ammonium nitrate, potassium tert-butoxide, oleum. Forms explosive mixtures with air. Specific information on symptoms and effects caused by the product are unknown. - IATA DGR: International Air Transport Association Dangerous Goods Regulation the duration and type of use. Hazard classification and indication: - IC50: Immobilization Concentration 50% --

ECOLOGICAL INFORMATION

For symptoms and effects caused by the contained substances, see chap. 11. Not applicable. Regulatory References: SKIN PROTECTION 10.4. Conditions to avoid. - IMDG: International Maritime Code for dangerous goods Wear category I professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or 4.3. Indication of any immediate medical attention and special treatment needed. 14.6. Special precautions for user. - IMO: International Maritime Organization DEU with soap and water after removing protective clothing. Deutschland MAK-und BAT-Werte-Liste 2012

2.2 Label elements

Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. contaminate soil or vegetation. - INDEX NUMBER: Identifier in Annex VI of CLP Information not available. FRA EYE PROTECTION France Not applicable. - LC50: Lethal Concentration 50% HUN Wear airtight protective goggles (see standard EN 166). Magyarország 50/2011. (XII. 22.) NGM rendelet a munkahelyek kémiai biztonságáról Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. ACETIC ACID Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. - LD50: Lethal dose 50% POL RESPIRATORY PROTECTION Polska ROZPORZĄDZENIE MINISTRA PRACY I POLITYKI SPOŁECZNEJ z dnia 16 grudnia 2011r 12.1. Toxicity. 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code. SECTION 5. Firefighting measures. ACETIC ACID: avoid exposure to sources of heat and naked flames. - OEL: Occupational Exposure Level

Hazard pictograms

EU If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type OEL EU -- Directive 2009/161/EU; Directive 2006/15/EC; Directive 2004/37/EC; Directive 2000/39/EC. 5.1. Extinguishing media.

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases TLV-ACGIH ACGIH 2016 10.5. Incompatible materials. ACETIC ACID Information not relevant. - PEC: Predicted environmental Concentration or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.

Signal word

SUITABLE EXTINGUISHING EQUIPMENT LC50 - for Fish. -- > 310 mg/l/96h - PEL: Predicted exposure level Extinguishing substances are: carbon dioxide, foam, chemical powder. For product loss or leakage that has not caught fire, water spray can Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the CITRIC ACID ACETIC ACID EC50 - for Crustacea. - PNEC: Predicted no effect concentration > 310 mg/l/48h Daphnia SECTION 15. Regulatory information.

Hazard statements

be used to disperse flammable vapours and protect those trying to stem the leak. Predicted no-effect concentration - PNEC. threshold values considered. The protection provided by masks is in any case limited. ACETIC ACID: carbonates, hydroxides, many oxides and phosphates. Oxidising substances and bases. EC50 - for Algae / Aquatic Plants. - REACH: EC Regulation 1907/2006 > 310 mg/l/72h UNSUITABLE EXTINGUISHING EQUIPMENT If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an EUH210 Normal value in fresh water Safety data sheet available on request. 0,44 - RID: Regulation concerning the international transport of dangerous goods by train Do not use jets of water. Water is not effective for putting out fires but can be used to cool containers exposed to flames to prevent emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing mg/l Normal value in marine water 0,044 mg/l 10.6. Hazardous decomposition products. CITRIC ACID - TLV: Threshold Limit Value 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. Precautionary statements: explosions. apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. EC50 - for Crustacea. Precautionary statements: Normal value for fresh water sediment -- 1535 mg/l/48h Daphnia Magna 34,6 - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. ENVIRONMENTAL EXPOSURE CONTROLS. mg/Kg In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. Normal value for marine water sediment 3,46 - TWA STEL: Short-term exposure limit The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure mg/Kg