IPA HQ

Hazard statements (CLP)

H225, H226, H319, H335, H336

Code

Statements

H225

Highly Flammable liquid and vapour

2.1 Classification of the substance or mixture

and indication Classification 1272/2008 Flammable liquid, category 2 H225 Highly flammable liquid and vapour. Eye irritation, category 2 H319 Causes serious eye irritation. Specific target organ toxicity - single exposure, H336 May cause drowsiness or dizziness. category 3

2.2 Label elements

Hazard labelling pursuant to EC Regulation

Signal word

Danger

Hazard statements

H225 Highly flammable liquid and vapour. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P280 Wear protective gloves/ protective clothing / eye protection / face protection. © EPY 9.8.3- SDS 1004.11 98 2547 Revision nr.3 EN GREEN Dated 10/2018 as GREEN SOLUTIONS SRL Replaced revision:2 (Dated 03/05/2017) Solutions S.r.1. I Pp A H Q P370+P378 In case of fire: use sand, chemical powder or foam to extinguish. P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P233 Keep container tightly closed. P312 Calla POISON CENTRE / doctor if you feel unwell.

Contains

PROPAN-2-OL Sec-Butyl alcohol Identification x = Conc. % Classification

2.3 Other hazards

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 3.2. Mixtures

Principle Routes of Exposure

Acute Chronic Acute local Acute Chronic local systemic local systemic local systemic Oral VND 26 VND 26 mg/kg bw/d Inhalation VND 89 VND 500 mg/m3 Skin VND 319 VND 888 mg/kg bw/d mg/kg bw/d Threshold Limit Value Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm OEL EU 303 100 Predicted no-effect concentration - PNEC Normal value in fresh water 47,1 mg/l Normal value in marine water 47,1 mg/l Normal value for fresh water sediment 196,19 mg/kg/d Normal value for marine water sediment 196,19 mg/kg/d Normal value of STP microorganisms 161 mg/l Normal value for the food chain (Secondary poisoning) 1000 mg/kg Normal value for the terrestrial compartment 11,58 mg/kg/d Health - Derived no-effect level - DNEL / DMEL Effects on consumers Effects on workers Acute Chronic Acute local Acute Chronic local systemic local systemic local systemic Oral 15 mg/kg bw/d Inhalation 213 600 mg/m3 Skin 203 405 mg/kg bw/d mg/kg bw/d © EPY 9.8.3- SDS 1004.11 101 2550 GREEN x Solutions S.r.1. I Pp A H Q a ee ee (Dated 03/05/2017) Legend: (C)=CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA®= Thoracic Fraction. VND = hazard identified but no DNEL/PNEC available ; NEA=no exposure expected ; NPI =no hazard identified. 8.2. Exposure controls As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well aired through effective local aspiration. When choosing personal protective equipment, ask your chemical substance supplier for advice. Personal protective equipment must be CE marked, showing that it complies with applicable standards. Provide an emergency shower with face and eye wash station. HAND PROTECTION Protect hands with category III work gloves (see standard EN 374). The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. The work gloves’ resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the duration and type of use. SKIN PROTECTION Wear category | professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with soap and water after removing protective clothing. Consider the appropriateness of providing antistatic clothing in the case of working environments in which there is a risk of explosion. EYE PROTECTION Wear airtight protective goggles (see standard EN 166). RESPIRATORY PROTECTION If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, wear a mask with a type AX filter, whose limit of use will be defined by the manufacturer (see standard EN 14387). In the presence of gases or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the threshold values considered. The protection provided by masks is in any case limited. If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency, wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529. ENVIRONMENTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. 9.1. Information on basic physical and chemical properties Appearance liquid Colour transparent Odour mild Odour threshold Not available pH 5-9 Melting point / freezing point Not available Initial boiling point Not available Boiling range 80 - 100°C Flash point 13 °C Evaporation rate Not available Flammability (solid, gas) Not available Lower inflammability limit 2 % (V/V) Upper inflammability limit 12 % (V/V) Lower explosive limit Not available Upper explosive limit Not available Vapour pressure Not available Vapour density Not available Relative density 0,78 - 0,80 Solubility soluble in water Partition coefficient: n-octanol/water Not available Auto-ignition temperature 425 °C Decomposition temperature Not available Viscosity Not available Explosive properties Not available Oxidising properties Not available

Further information

© EPY 9.8.3- SDS 1004.11 102 2551 GREEN x Solutions S.r.1. I Pp A H Q a eee (Dated 03/05/2017) Information not available 10.1. Reactivity There are no particular risks of reaction with other substances in normal conditions of use. 10.2. Chemical stability The product is stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions The vapours may also form explosive mixtures with the air. 10.4. Conditions to avoid Avoid overheating. Avoid bunching of electrostatic charges. Avoid all sources of ignition. 10.5. Incompatible materials Information not available 10.6. Hazardous decomposition products In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be released. In the absence of experimental data for the product itself, health hazards are evaluated according to the properties of the substances it contains, using the criteria specified in the applicable regulation for classification. It is therefore necessary to take into account the concentration of the individual hazardous substances indicated in section 3, to evaluate the toxicological effects of exposure to the product. 11.1. Information on toxicological effects Metabolism, toxicokinetics, mechanism of action and other information Information not available Information on likely routes of exposure Information not available Delayed and immediate effects as well as chronic effects from short and long-term exposure Information not available Interactive effects Information not available ACUTE TOXICITY LC50 (Inhalation) of the mixture: Not classified (no significant component) LD50 (Oral) of the mixture: Not classified (no significant component) LD50 (Dermal) of the mixture: Not classified (no significant component) PROPAN-2-OL LD50 (Oral) 5840 mg/kg Rat LD50 (Dermal) 12800 mg/kg Rat LC50 (Inhalation) 5000 ppm/6h Rat Sec-Butyl alcohol LD50 (Oral) 2054 mg/kg Rat LD50 (Dermal) > 2000 mg/kg Rat LC50 (Inhalation) 16000 ppm/4h Rat © EPY 9.8.3- SDS 1004.11 103 2552 GREEN x Solutions S.r.1. I Pp A H Q i ee ee (Dated 03/05/2017) SKIN CORROSION / IRRITATION Does not meet the classification criteria for this hazard class SERIOUS EYE DAMAGE / IRRITATION Causes serious eye irritation RESPIRATORY OR SKIN SENSITISATION Does not meet the classification criteria for this hazard class GERM CELL MUTAGENICITY Does not meet the classification criteria for this hazard class CARCINOGENICITY Does not meet the classification criteria for this hazard class REPRODUCTIVE TOXICITY Does not meet the classification criteria for this hazard class STOT - SINGLE EXPOSURE May cause drowsiness or dizziness STOT - REPEATED EXPOSURE Does not meet the classification criteria for this hazard class ASPIRATION HAZARD Does not meet the classification criteria for this hazard class Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or contaminate soil or vegetation. 12.1. Toxicity PROPAN-2-OL LC50 - for Fish 9460 mg/I/96h Pimephales Promelas EC50 - for Crustacea > 10000 mg/I/24h Daphnia Magna Chronic NOEC for Algae / Aquatic Plants 1800 mg/l Scenedesmus quadricauda Sec-Butyl alcohol LC50 - for Fish 2993 mg/I/96h EC50 - for Crustacea 308 mg/l/48h Daphnia Magna EC50 - for Algae / Aquatic Plants 2029 mg/I/72h Scenedesmus quadricauda 12.2. Persistence and degradability PROPAN-2-OL Rapidly degradable 12.3. Bioaccumulative potential Information not available 12.4. Mobility in soil Information not available © EPY 9.8.3- SDS 1004.11 104 2553 GREEN x Solutions S.r.1. I Pp A H Q a eee (Dated 03/05/2017) 12.5. Results of PBT and vPvB assessment On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 12.6. Other adverse effects Information not available 13.1. Waste treatment methods Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. Waste transportation may be subject to ADR restrictions. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14.1. UN number ADR/ RID, IMDG, IATA: 1219 14.2. UN proper shipping name ADR/ RID: ISOPROPANOL (ISOPROPYL ALCOHOL) IMDG: ISOPROPANOL (ISOPROPYL ALCOHOL) IATA: ISOPROPANOL (ISOPROPYL ALCOHOL) 14.3. Transport hazard class(es) ADR / RID: Class: 3 Label: 3 IMDG: Class: 3 Label: 3 IATA: Class: 3 Label: 3 14.4. Packing group ADR/ RID, IMDG, IATA: lI 14.5. Environmental hazards ADR/ RID: NO IMDG: NO IATA: NO 14.6. Special precautions for user ADR / RID: HIN - Kemler: 33 Limited Quantities: 1 L Tunnel restriction code: (D/E) Special Provision: - IMDG: EMS: F-E, S-D Limited Quantities: 1 L IATA: Cargo: Maximum quantity: 60 L Packaging instructions: 364 Pass.: Maximum quantity: 5 L Packaging instructions: 353 Special Instructions: A180 14.7. Transport in bulk according to Annex Il of Marpol and the IBC Code Information not relevant © EPY 9.8.3- SDS 1004.11 105 2554 GREEN x Solutions S.r.1. I Pp A H Q i eee (Dated 03/05/2017) 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Seveso Category - Directive 2012/18/EC: P5c Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Product Point 3 - 40 Substances in Candidate List (Art. 59 REACH) On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. Substances subject to authorisation (Annex XIV REACH) None Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: None Substances subject to the Rotterdam Convention: None Substances subject to the Stockholm Convention: None Healthcare controls Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers’ health and safety are modest and that the 98/24/EC directive is respected. 15.2. Chemical safety assessment No chemical safety assessment has been processed for the mixture and the substances it contains. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Flam. Liq. 2 Flammable liquid, category 2 Flam. Liq. 3 Flammable liquid, category 3 Eye Irrit. 2 Eye irritation, category 2 STOT SE 3 Specific target organ toxicity - single exposure, category 3 H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. LEGEND: - ADR: European Agreement concerning the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive of existing substances) - CLP: EC Regulation 1272/2008 - DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification and labeling of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - 1050: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative and toxic as REACH Regulation - PEC: Predicted environmental Concentration © EPY 9.8.3- SDS 1004.11 106 2555 GREEN SOLUTIONS SRL of eessiitozn: Revision nr.3 EN G R = [= N Printed on 31/10/2018 Page n. 10/10 I PA H Q Repl eplaced revision:2 ision:2 Solutions S.r.b. (Dated (D 03/05/2017) /05/201 PEL Predicted exposure level- PNEC Predicted no effect concentration - REACH: EC Regulation 1907/2006 - RID: Regulation concerning the international transport of dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation - WGK: Water hazard classes (German). GENERAL BIBLIOGRAPHY . Regulation (EC) 1907/2006 (REACH) of the European Parliament = . Regulation (EC) 1272/2008 (CLP) of the European Parliament . Regulation (EU) 790/2009 (| Atp. CLP) of the European Parliament BRWDND . Regulation (EU) 2015/830 of the European Parliament . Regulation (EU) 286/2011 (Il Atop. CLP) of the European Parliament OO . Regulation (EU) 618/2012 (Ill Atop. CLP) of the European Parliament . Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament CON . Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament 12. Regulation (EU) 2016/1179 (IX Atp. CLP) 13. Regulation (EU) 2017/776 (X Atp. CLP) - The Merck Index. - 10th Edition - Handling Chemical Safety - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene and Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - IFA GESTIS website - ECHA website - Database of SDS models for chemicals - Ministry of Health and ISS (Istituto Superiore di Sanita) - Italy Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. Changes to previous review: The following sections were modified: 01/02/03/08/11/ 12. © EPY 9.8.3- SDS 1004.11 107