Citrus Clean

Hazard statements (CLP)

H314, H315, H316, H319, H335, H336

Code

Statements

H314

Causes severe skin burns and eye damage

2.1 Classification of the substance or mixture

Placard Key word

Hazard statements

Skin Corrosion/Irritation, Category 1C Corrosive Danger Causes severe skin burns and eye damage Serious Eye Damage/Eye Irritation, Category 2A Exclamation Point Warning Causes serious eye irritation. Target Organ Systemic Toxicity (single exposure), Category 3 Exclamation Point Warning May cause respiratory irritation, or may cause drowsiness and dizziness. H315 - Causes skin irritation. H319 - Causes serious eye irritation. H335 - May cause respiratory irritation. H336 - May cause drowsiness or dizziness. GHS 07 GHS 05 H316 - Causes mild skin irritation. H314 - Causes severe skin burns and eye damage.

Precautionary statements

P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P264 - Wash hands thoroughly after handling. P280 - Wear protective gloves/clothing and eye/face protection as specified by the manufacturer/supplier or the competent authority. P271 - Use only outdoors or in a well- ventilated area. P260 - Do not breathe dust/fume/gas/mist/vapors/spray.

Response

P302+352 - IF ON SKIN: Wash with plenty of soap and water. P321 - Specific treatment (see ... on this label) ... reference to supplemental first aid instruction - if immediate administration of antidote is required. P332+313 - If skin irritation occurs, get medical advice/attention. P362 - Take off contaminated clothing and wash before re- use. P305+351+338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+313 - If eye irritation persists, get medical advice/attention. P309+311 - Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353 - IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363 - Wash contaminated clothing before reuse. P301+330+331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P310 - Immediately call a POISON CENTER or doctor/physician.

Storage

P405 - Store locked up. P403+233 - Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere. P501 - Dispose of contents/container (in accordance with local/regional/national/international regulation).

Principle Routes of Exposure

Inhalation? Yes Skin? Yes Eyes? Yes Ingestion? Yes Eye Contact: Causes severe eye burns. May cause irreversible eye injury. Contact may cause ulceration of the conjunctiva and cornea. Eye damage may be delayed. May cause chemical conjunctivitis and corneal damage. Prolonged or repeated eye contact may cause conjunctivitis. Skin Contact: Causes skin irritation. Skin sensitization testing with human volunteers produced negative results. Skin Contact: May cause deep, penetrating ulcers of the skin. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color. Prolonged or repeated skin contact may cause dermatitis. Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause severe and permanent damage to the digestive tract. May cause systemic effects. Causes symptoms similar to those of inhalation. Inhalation: May cause lung damage. Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. Effects may be delayed. Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Skin Contact May be harmful if absorbed through the skin. Causes skin irritation. Eye Contact Causes eye irritation. Ingestion May be harmful if swallowed. LD 50 / LC 50 Ingredient CAS# 111-76-2, Ethanol, 2-Butoxy-: Humans are less susceptible than rodents to 2-butoxyethanol exposure. 2-Butoxyethanol gives toxic results when tested on rabbits and rats. It does not behave the same when humans are exposed to it. This is explained by the different makeup of the red blood cells of test animals vs. humans. Test animal red blood cells are hypersensitive to 2-butoxyethanol when compared to humans.

Potential health effects

Acute and Chronic)