SANITIZER

Hazard statements (CLP)

H226

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Flammable liquids : Category 3 GHS label elements Hazard pictograms Signal word : Warning Hazard statements - H226 Flammable liquid and vapour. Precautionary statements : Prevention: - P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. Response: P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage: P403 + P235 Store in a well-ventilated place. Keep cool. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components CAS-No. Chemical. name = ‘Concentration (%) >= 20 -<35 64-17-5 Ethyl Alcohol >= 1 -<5 67-63-0 lsopropyl Alcohol SECTION 4. FIRST AID MEASURES In the case of accident or if you feel unwell, seek medical General advice - advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled - Ifinhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact - Wash with water and soap as a precaution. Get medical attention if irritation develops and persists. In case of eye contact - In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. if easy to do, remove contact lens, if worn. Seek medical advice. lf swallowed - If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Protection of first-aiders - First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing : High volume water jet media Specific hazards during Do not use a solid water stream as it may scatter and spread firefighting fire. Cool closed containers exposed to fire with water spray. Flash back possible over considerable distance. May form explosive mixtures in air. Exposure to decomposition products may be a hazard to health. Specific extinguishing : Use extinguishing measures that are appropriate to local methods circumstances and the surrounding environment, Use water spray to cool unopened containers. Further information - Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment - In the event of fire, wear self-contained breathing apparatus. for firefighters Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, - Use personal protective equipment. protective equipment and Ensure adequate ventilation. emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for - Non-sparking tools should be used. containment and cleaning up Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : Avoid contact with eyes. Conditions for safe storage : No smoking. Take measures to prevent the build up of electrostatic charge. Keep container tightly closed in a dry and well-ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Value type Control Basis Components CAS-No. (Form of parameters / exposure) Permissible concentration 64-17-5 TWA 1,000 ppm NIOSH REL Ethyl Alcohol! 1,900 mg/m3 TWA 4,000 ppm OSHA Z-1 4,900 mg/m3 STEL 4,000 ppm ACGIH 67-63-0 TWA 200 ppm ACGIH Isopropyl Alcohol 400 ppm ACGIH STEL 400 ppm NIOSH REL TWA 980 mag/m3 ST 500 ppm NIOSH REL 1,225 mg/m3 TWA 400 ppm OSHA Z-1 980 mag/m3 Biological occupational exposure limits CAS-No. | Control Biological | Samplin Permissible | Basis Gomponents |g time concentratio parameters |specimen n Urine End of 40 mg/l ACGIH Isopropyl Alcohol 67-63-0 Acetone shift at BEI end of workwee kK Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. : No special measures necessary provided product is used Eye protection correcily. Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special measures necessary provided product is used correctly. Protective measures - Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Ensure that eye flushing systems and safety showers are located close to the working place. When using do not eat, drink or smoke. Hygiene measures - Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : colourless : alcohol-like Odour Odour Threshold : No data available 12.6-12.9, (24 °C) pH Melting point/freezing point - No data available Initial boiling point and boiling : 77°C range Flash point : 30.8 °C Method: Pensky-Martens closed cup Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit : 19 %(V) Lower explosion limit : 3.3 %(V) Vapour pressure - No data available Relative vapour density - No data available Relative density : No data available Density : 0.952 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- : Not applicable octanol/water Auto-ignition temperature - not determined Thermal decomposition - The substance or mixture is not classified self-reactive. Viscosity Viscosity, dynamic : 2.6mPa.s Explosive properties : Not explosive Oxidizing properties - The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity - Not classified as a reactivity hazard. Possibility of hazardous : Vapours may form explosive mixture with air. reactions Conditions to avoid : Heat, flames and sparks. incompatible materials : Oxidizing agents Hazardous decomposition - No hazardous decomposition products are known. products SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Skin contact Eye contact Acute toxicity Not classified based on available information. Components: Ethyl Alcohol: Acute oral! toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity - LCO50 (Rat): 124.7 mg/l Exposure time: 4 h Test atmosphere: vapour Isopropyl Alcohol: Acute oral toxicity - LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity - LC50 (Rat): 72.6 mg/l Exposure time: 4h Test atmosphere: vapour SURFACE SANITIZER PURELL® FOODSERVICE Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Result: No skin irritation Components: Ethyl Alcohol: Species: Rabbit ; Method: OECD Test Guideline 404 Result: No skin irritation Isopropyl Alcohol: Species: Rabbit Result: No skin irritation Serious eye damageleye irritation Not classified based on available information. Components: Ethyl Alcohol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Method: OECD Test Guideline 405 Isopropyl Alcohol: Species: Rabbit Result: Irritation to eyes, reversing within 21 days Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: Ethyl! Alcohol: Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative isopropyl Alcohol: Test Type: Buehler Test Exposure routes: Skin contact Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Germ cell mutagenicity Not classified based on available information. Components: Ethyl Alcohol: : Test Type: Jn vitro mammalian cell gene mutation test Genotoxicity in vitro Result: negative Type: Rodent dominant lethal test (germ cell) (in vivo) Genotoxicity in vivo : Test Test species: Mouse Application Route: Ingestion Result: negative Isopropyl Alcohol: Genotoxicity in vitro - Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo - Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Intraperitoneal injection Result: negative Carcinogenicity Not classified based on available information. Components: Isopropyl Alcohol: Species: Rat Application Route: inhalation (vapour) Exposure time: 104 weeks Method: OECD Test Guideline 451 Result: negative IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or OSHA equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or NTP equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Ethyl Alcohol: Effects on fertility : Test Type: Two-generation reproduction toxicity study Species: Mouse Application Route: Ingestion Method: OECD Test Guideline 416 Result: negative Isopropyl Alcohol: toxicity study Effects on fertility : Test Type: Two-generation reproduction Species: Rat Application Route: Ingestion Result: negative Effects on foetal : Test Type: Embryo-foetal development development Species: Rat Application Route: Ingestion Result: negative STOT - single exposure Not classified based on available information. Components: Isopropyl Alcohol: Assessment: May cause drowsiness or dizziness. STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: Ethyl Alcohol: Species: Rat NOAEL: 2,400 mg/kg Application Route: Ingestion Exposure time: 2 y Isopropyl Alcohol: Species: Rat NOAEL: 5000 ppm Application Route: inhalation (vapour) Exposure time: 104 w Method: OECD Test Guideline 413 Aspiration toxicity Not classified based on available information. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: Ethyl Alcohol: Toxicity to fish - LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l Exposure time: 96 h Toxicity to daphnia and other: EC50 (Daphnia magna (Water flea)): > 1,000 mg/l aquatic invertebrates Exposure time: 48 h : ECS50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l Toxicity to algae Exposure time: 72 h Method: OECD Test Guideline 201 Toxicity to daphnia and other - NOEC (Daphnia magna (Water flea)): 9.6 mg/l aquatic invertebrates Exposure time: 9 d (Chronic toxicity) Toxicity to bacteria EC50 (Photobacterium phosphoreum): 32.1 mg/l Exposure time: 0.25 h Isopropyl Alcohol: Toxicity to fish - LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l Exposure time: 96 h Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l aquatic invertebrates Exposure time: 24 h Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l Exposure time: 16h Persistence and degradability Components: Ethyl Alcohol: Biodegradability : Result: Readily biodegradable. Biodegradation: 84 % Exposure time: 20 d Isopropy! Alcohol: Biodegradability : Result: rapidly degradable Bioaccumulative potential Components: Ethyl! Alcohol: Partition coefficient: n- : log Pow: -0.35 octanol/water isopropyl Alcohol: Partition coefficient: n- : log Pow: 0.05 octanol/water Mobility in soil No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class | Substances Remarks This product neither contains, nor was manufactured with a Class | or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR UN/ID No. : UN 1987 Proper shipping name : Alcohols, n.o.s, (Ethanol, Propan-2-ol) Class “3 Packing group > Ill Packing instruction (cargo : 366 aircraft) Packing instruction > 355 (passenger aircraft) IMDG-Code UN number : UN 1987 Proper shipping name : ALCOHOLS, N.O.S. (Ethanol, Propan-2-ol) Class ng Packing group : Ul Labels E 3 EmS Code : F-E, S-D Marine pollutant : no National Regulations 49 CFR UN/ID/NA number : UN 1987 Proper shipping name : Alcohols, n.o.s. Class 2 3 Packing group : It ERG Code : 127 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity CAS-No. Component RQ Calculated product RQ ‘Components (Ibs) 1310-58-3 1000 Potassium Hydroxide * *. Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This materia! does not contain any compo nents with a section 304 EHS RQ. SARA 311/312 Hazards : Fire Hazard SARA 302 - No chemicals in this material are subject to the reporting requirements of SARA Title Ill, Section 302. SARA 313 - The following components are subject to reporting levels established by SARA Title Ill, Section 313: Isopropyl Alcohol 67-63-0 1.42 % Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defin ed by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemica Is listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): 29.4 % Ethyl Alcohol 64-17-5 4.42 % Isopropyl Alcohol 67-63-0 any VOC exemptions listed unde r the U.S. Clean Air Act Section This product does not contain 450. Clean Water Act This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 Section 311, are liste d under the U.S. CleanWater Act, The following Hazardous Substances Table 116.4A: 1310-58-3 0.35 % Potassium Hydroxide The following Hazardous Chemicals are listed under th e U.S. CleanWater Act, Section 311, Table 117.3: 1310-58-3 0.35 % Potassium Hydroxide Massachusetts Right To Know Ethyl Alcohol! 64-17-5 20 - 35 % Isopropyl Alcohol 67-63-0 1-5% Pennsylvania Right To Know Water (Aqua) 7732-18-5 70 - 90 % 64-17-5 Ethyl Alcohol 20 - 35 % lsopropyl Alcohol 67-63-0 1-5% 1310-58-3 0.1-1% Potassium Hydroxide New Jersey Right To Know

Signal word

vapour. - H226 Flammable liquid and

Prevention

heat/sparks/open flames/hot surfaces. - P210 Keep away from No smoking. Keep container tightly closed. P233 container and receiving equipment. P240 Ground/bond electrical/ ventilating/ lighting/ P241 Use explosion-proof equipment. P242 Use only non-sparking tools. measures against static discharge. P243 Take precautionary

Response

sand, dry chemical or P370 + P378 In case of fire Use dry alcohol-resistant foam for extinction

Storage

in a well-ventilated place. Keep cool. P403 + P235 Store

Disposal

to an approved waste P501 Dispose of contents/ container disposal plant

Other hazards

None known. COMPOSITION/INFORMATION 3 ON INGREDIENTS