Acetic Acid 80%

Hazard statements (CLP)

H226, H314

Code

Statements

H226

Flammable liquid and vapour

Health hazards

Skin Corrosion/Irritation Category 1B Serious Eye Damage/Eye Irritation Category 1 OSHA Specified Hazards: not applicable Warning label items including precautionary statement:

Hazard pictograms

SAFETY Words: DANGER!

Hazard statements

H226: Flammable liquid and vapor. H314: Causes severe skin burns and eye damage.

Prevention

P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P264: Wash hands thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection.

Response

P370+P378: In case of fire; Use water spray, carbon dioxide, dry chemical or alcohol foam for extinction. P303+P361+P353 IF ON SKIN (or hair) Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting. P363: Wash contaminated clothing before reuse. P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310: Immediately call a POISON CENTER or doctor/physician. P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Storage

P403+P235: Store in a well-ventilated place. Keep cool. P405: Store locked up.

Disposal

P501: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Hazard(s) not otherwise None known.

Classified (HNOC)

Substances / Mixtures General information: Chemical name Concentration Additional identification Notes acetic acid 50 - 80% CAS-No.: 64-19-7 # Signal * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 20 - 50% CAS-No.: 7732-18-5 # This substance has workplace exposure limit(s). Description of first aid measures Inhalation: Move to fresh air. If breathing stops, provide artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. In case of irritation from airborne exposure, move to fresh air. Get medical attention if symptoms persist. Skin contact: Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Ingestion: Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. Most important symptoms and May irritate and cause redness and pain. effects, both acute and delayed: Indication of any immediate medical attention and special treatment needed

SECTION 2: Hazards identification

None known. Treatment: Treat symptomatically. General Fire Hazards: Flammable liquid and vapor. Extinguishing media Suitable extinguishing Water spray. Dry chemical. Carbon Dioxide. Alcohol foam. media: Unsuitable extinguishing None known. media: Special hazards arising from Vapors may cause a flash fire or ignite explosively. Vapors may travel the substance or mixture: considerable distance to a source of ignition and flash back. Prevent buildup of vapors or gases to explosive concentrations. Advice for firefighters Special fire fighting Water may be ineffective in fighting the fire. Use water spray to keep fire- procedures: exposed containers cool. Special protective Self-contained breathing apparatus and full protective clothing must be equipment for fire-fighters: worn in case of fire. water

Precautionary statements

Wear appropriate personal protective equipment. protective equipment and emergency procedures: Environmental Precautions: Avoid release to the environment. Methods and material for Eliminate sources of ignition. Absorb spill with vermiculite or other inert containment and cleaning material, then place in a container for chemical waste. Large Spillages: Use up: water spray to disperse vapors and dilute spill to a nonflammable mixture. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. SECTION 7: Handling and storage: Precautions for safe handling: Avoid breathing mists or vapors. Do not get in eyes, on skin, on clothing. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. Conditions for safe storage, Keep container tightly closed and in a well-ventilated place. including any incompatibilities: Specific end use(s): Solvent Control Parameters Occupational Exposure Limits Country specific exposure limits have not been established or are not applicable unless listed below. Chemical name type Exposure Limit Values Source acetic acid TWA 10 ppm US. ACGIH Threshold Limit Values (01 2010) STEL 15 ppm US. ACGIH Threshold Limit Values (01 2010) PEL 10 ppm 25 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Exposure controls Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. controls: Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment General information: Eye bath. Washing facilities. Safety shower. Personal protection: Use safety goggles and face shield in case of splash risk. Wear a full-face respirator, if needed. Skin protection Hand Protection: Wear chemical-resistant gloves, footwear, and protective clothing appropriate for the risk of exposure. Contact health and safety professional or manufacturer for specific information. Other: Physical state: No data available. liquid Respiratory Protection: If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA Standard 63 FR 1152, January 8, 1998. Respirator type: Air- purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Contact health and safety professional or manufacturer for specific information. Hygiene measures: Observe good industrial hygiene practices. Environmental Controls: No data available. Information on basic physical and chemical properties Appearance Form: liquid Color: Colorless Odor: Pungent, vinegar Odor Threshold: 0.48 ppm pH: 2.4 (60 g/l, ) Freezing Point: 16.64 °C Boiling Point: 117.9 °C Flash Point: 39 °C Evaporation Rate: Not determined. Flammability (solid, gas): not applicable Flammability Limit - Upper (%)–: 19.9 %(V) Flammability Limit - Lower (%)–: 4 %(V) Vapor pressure: 20.79 hPa (25 °C) Vapor density (air=1): Specific Gravity: 1.0446 (25 °C) Solubility(ies) Solubility in Water: 602.9 g/l (25 °C) Solubility (other): No data available. Partition coefficient (n-octanol/water): log Pow: -0.17 Autoignition Temperature: 463 °C Eye/face Temperature: Thermal stability not tested. Low stability hazard expected at normal operating temperatures. Dynamic viscosity: No data available. Kinematic viscosity: 1.011 mm2/s Explosive properties: Not classified. Oxidizing properties: Not classified. Reactivity: None known. Chemical Stability: Stable Possibility of Hazardous None known. Reactions: Conditions to Avoid: Heat, sparks, flames. Incompatible Materials: Strong oxidizing agents. Hazardous Decomposition Carbon Dioxide. Carbon Monoxide. Products: Information on likely routes of exposure Inhalation: Severely irritating to respiratory system. Ingestion: May cause burns of the gastrointestinal tract if swallowed. Skin contact: Causes severe skin burns. Eye contact: Causes serious eye damage. Information on toxicological effects Oral Product: No data available. Specified substance(s): acetic acid Oral LD-50 (Rat) 3,320 mg/kg Dermal Product: No data available. Specified substance(s): acetic acid Dermal LD-50 (Rabbit) 1,060 mg/kg Product: No data available. Inhalation Specified substance(s): acetic acid LC50 (Rat, 4 h): > 16000 ppm Repeated dose toxicity Decomposition No data available. Specified substance(s): acetic acid NOAEL (Rat, Oral Study): 290 mg/kg NOAEL (Rat, Dermal Study): 30 mg/kg Product: No data available. Skin Corrosion/Irritation Specified substance(s): acetic acid (Rabbit, 24 h): Severe Product: No data available. Serious Eye Damage/Eye Irritation Specified substance(s): acetic acid (Rabbit): Severe Product: No data available. Respiratory or Skin Sensitization Specified substance(s): acetic acid There is no data available to indicate sensitizing potential for this substance. Product: This product does not contain any carcinogens or potential carcinogens as Carcinogenicity listed by OSHA, IARC or NTP. Product: No data available. Toxicity to reproduction Product: No data available. Developmental toxicity Specified substance(s): acetic acid Rat; NOAEL: 345 mg/kg; Ingestion Product: No data available. Germ Cell Mutagenicity In vitro Specified substance(s): acetic acid Salmonella typhimurium assay (Ames test) (Bacterial Reverse Mutation Assay): negative Chromosomal aberration (In vitro Mammalian Chromosome Aberration Test): negative In vivo Product: No data available. Specified substance(s): acetic acid Chromosomal aberration Inhalation - vapor (Rat): Read-across from a similar material negative Product: Target Organ Toxicity - Single Exposure Product: No data available. Specific Target Organ Toxicity - Repeated Exposure Product: No data available. Product: No data available. Aspiration Hazard Product: No data available. Other effects: No data available. Ecotoxicity: Acute hazards to the aquatic environment: Fish Specified substance(s): acetic acid LC-50 (Fathead Minnow, 96 h): 300.82 mg/l Aquatic Invertebrates Product: No data available. Specified substance(s): acetic acid EC-50 (daphnid, 48 h): > 300.82 mg/l Chronic hazards to the aquatic environment: Product: No data available. Fish Product: No data available. Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Specified substance(s): acetic acid EC-50 (Alga, 72 h): 300.82 mg/l Product: No data available. Persistence and Degradability Biodegradation Specified substance(s): acetic acid 96 % (20 d) Readily biodegradable BOD/COD Ratio Product: No data available. Specific Potential Bioconcentration Factor (BCF) Product: No data available. Specified substance(s): acetic acid Bioconcentration Factor (BCF): 3.16 Partition Coefficient n-octanol / water (log Kow) Product: Log Kow: -0.17 20 °C acetic acid Log Koc: 0.062 (QSAR model) Mobility in Soil: No data available. Known or predicted distribution to environmental compartments Other Adverse Effects: No data available. Waste treatment methods General information: No data available. Disposal methods: Dispose of waste and residues in accordance with local authority requirements. Mix with compatible chemical which is less flammable and incinerate. Since emptied containers retain product residue, follow label warnings even after container is emptied. Residual vapors may explode on ignition; do not cut, drill, grind, or weld on or near this container. Important Note: Shipping descriptions may vary based on mode of transport, quantities, package size, and/or origin and destination. Consult your company's Hazardous Materials/Dangerous Goods expert for information specific to your situation. DOT Reportable Quantity: 2,837 kg (acetic acid) Possible Shipping Description(s): UN 2790 Acetic acid solution 8 II IMDG - International Maritime Dangerous Goods Code Possible Shipping Description(s): UN 2790 ACETIC ACID SOLUTION 8 II IATA Bioaccumulative Shipping Description(s): UN 2790 Acetic acid solution 8 II Safety, health and environmental regulations/legislation specific for the substance or mixture.: This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. WHMIS (Canada) Status: controlled WHMIS (Canada) Hazard Classification: B/2, E SARA 311-312 Hazard Classification(s): immediate (acute) health hazard fire hazard US EPCRA (SARA Title III) Section 313 - Toxic Chemical List NONE OSHA: hazardous TSCA (US Toxic Substances Control Act): All components of this product are listed on the TSCA inventory. Any impurities present in this product are exempt from listing. DSL (Canadian Domestic Substances List) and CEPA (Canadian Environmental Protection Act): All components of this product are listed on the DSL. Any impurities present in this product are exempt from listing. AICS / NICNAS (Australian Inventory of Chemical Substances and National Industrial Chemicals Notification and Assessment Scheme): All components of this product are listed on AICS or otherwise comply with NICNAS. MITI (Japanese Handbook of Existing and New Chemical Substances): All components of this product are listed in the Handbook or have been approved in Japan by new substance notification. ECL (Korean Toxic Substances Control Act): All components of this product are listed on the Korean inventory or otherwise comply with the Korean Toxic Substances Control Act. Philippines Inventory (PICCS) : All components of this product are listed on the Philippine inventory or otherwise comply with PICCS. HMIS® Hazard Ratings: Health - 3, Flammability - 2, Chemical Reactivity - 0 Possible rating involves data interpretations that may vary from company to company. They are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately with the safe handling of this material, all the information contained in this MSDS must be considered. Revision Information: Not relevant. Key literature references and No data available. sources for data: Training information: No data available. Issue Date: 5-30-2015 SDS No.: Disclaimer: This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. HMIS®