OEL

Giuseppe Di Maria S.p.A

Revision date : 2020-09-21

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Health risk rating 1
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

203-961-6/112-34-5

Name of the chemical

2-(2-butoxyethoxy)ethanol

Concentration

0,3≤x<0,35

EC/CAS

215-647-6/1336-21-6

Name of the chemical

ammonium hydroxide

Concentration

0≤x<0,05

EC/CAS

203-473-3/107-21-1

Name of the chemical

Ethane-1,2-diol

Concentration

0≤x<0,05 27,40%

General Information

Revision date

2020-09-21

Product name

OEL

1.2.1 Relevant identified uses

Does not meet the classification criteria for this hazard class 15. Regulation (EU) 2018/1480 (XIII Atp. CLP)

Icons in SDS

Company Information

company name

Giuseppe Di Maria S.p.A

Section 2

2.1 Classification of the substance or mixture

Protect hands with category III work gloves (see standard EN 374). Changed TLVs in section 8.1 for following countries: Solubility in water - EmS: Emergency Schedule ETHANEDIOL 1000 - 10000 mg/l SKIN: Remove contaminated clothing. Rinse skin with a shower immediately. Get medical advice/attention. places in which people eat. Not applicable The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability. ESP, GBR, ITA, EU, TLV-ACGIH, FRA, Corrodes: aluminium,iron,zinc,copper,copper alloys. 10.2. Chemical stability Rapidly degradable - GHS: Globally Harmonized System of classification and labeling of chemicals INGESTION: Have the subject drink as much water as possible. Get medical advice/attention. Do not induce vomiting unless explicitly LD50 (Oral) > 2000 mg/kg Rat The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on - IATA DGR: International Air Transport Association Dangerous Goods Regulation The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). LD50 (Dermal) 9530 mg/kg Rabbit 7.2. Conditions for safe storage, including any incompatibilities 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code authorised by a doctor. the duration and type of use. However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data AMMONIA - IC50: Immobilization Concentration 50% However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety data INHALATION: Get medical advice/attention immediately. Remove victim to fresh air, away from the accident scene. If the subject stops The product is stable in normal conditions of use and storage. SKIN PROTECTION sheet with appropriate information, compliant to (EU) Regulation 2015/830. Degradability: information not available - IMDG: International Maritime Code for dangerous goods sheet with appropriate information, compliant to (EU) Regulation 2015/830. AMMONIA breathing, administer artificial respiration. Take suitable precautions for rescue workers. Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away Information not relevant Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body 10.3. Possibility of hazardous reactions - IMO: International Maritime Organization from any incompatible materials, see section 10 for details. LD50 (Oral) 350 mg/kg Rat Hazard classification and indication: with soap and water after removing protective clothing. 2-(2-BUTOXYETHOXY)ETHANOL - INDEX NUMBER: Identifier in Annex VI of CLP Hazard classification and indication: -- 4.2. Most important symptoms and effects, both acute and delayed EYE PROTECTION 7.3. Specific end use(s) SECTION 15. Regulatory information Solubility in water - LC50: Lethal Concentration 50% No hazardous reactions are foreseeable in normal conditions of use and storage. 2-(2-BUTOXYETHOXY)ETHANOL 1000 - 10000 mg/l Wear airtight protective goggles (see standard EN 166). Rapidly degradable - LD50: Lethal dose 50% LD50 (Oral) 3384 mg/kg Rat Specific information on symptoms and effects caused by the product are unknown. RESPIRATORY PROTECTION

2.2 Label elements

OEL: Occupational Exposure Level LD50 (Dermal) 2700 mg/kg Rabbit Information not available 2-(2-BUTOXYETHOXY)ETHANOL If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 12.3. Bioaccumulative potential

PBT Substances

Persistent bioaccumulative and toxic as REACH Regulation 4.3. Indication of any immediate medical attention and special treatment needed A filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases May react with oxidising substances.May form peroxides with oxygen.Develops hydrogen on contact with aluminium.May form explosive Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. SKIN CORROSION / IRRITATION - PEC: Predicted environmental Concentration Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. or vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required. Seveso Category - Directive 2012/18/EC: mixtures with: air. None SECTION 8. Exposure controls/personal protection - PEL: Predicted exposure level Information not available AMMONIA

Hazard pictograms

Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the Does not meet the classification criteria for this hazard class ETHANEDIOL - PNEC: Predicted no effect concentration -- 8.1. Control parameters threshold values considered. The protection provided by masks is in any case limited. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Risk of explosion on contact with strong acids,iodine.May react dangerously with strong bases 10.4. Conditions to avoid Partition coefficient: n-octanol/water - REACH: EC Regulation 1907/2006 -1,36

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