H410

GIORGIO BORMAC srl

Revision date : 2020-02-10

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Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

55965-84-9

Name of the chemical

3(2H)-Isothiazolone, 5-chloro-2-methyl-, mixt. with 2-methyl-3(2H)-isothiazolone

Concentration

N/A

General Information

Revision date

2020-02-10

Product name

H410

CAS No.

55965-84-9

1.2.1 Relevant identified uses

ASPIRATION HAZARD

supplier name

LD50: Lethal dose 50%

Icons in SDS

M10

Company Information

company name

GIORGIO BORMAC srl

e-mail address of the competent person responsible for the Safety Data Sheet

sds@giorgiobormac.com

GHS Information

Signal word

EYE

Section 2

SECTION 2: Hazards identification

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. SECTION 10. Stability and reactivity None - TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure. Corrosive to the rabbit SECTION 8. Exposure controls/personal protection SECTION 5. Firefighting measures

2.1 Classification of the substance or mixture

TWA STEL: Short-term exposure limit SERIOUS EYE DAMAGE / IRRITATION 12.3. Bioaccumulative potential 10.1. Reactivity Substances in Candidate List (Art. 59 REACH) 8.1. Control parameters - TWA: Time-weighted average exposure limit On the basis of available data, the product does not contain any SVHC in percentage greater than 0,1%. 5.1. Extinguishing media - VOC: Volatile organic Compounds The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). Does not meet the classification criteria for this hazard class 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one The product is not classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP). There are no particular risks of reaction with other substances in normal conditions of use.

vPvB Substances

Very Persistent and very Bioaccumulative as for REACH Regulation However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety Information not available Partition coefficient n-octanol / water log Pow -0.486 However, since the product contains hazardous substances in concentrations such as to be declared in section no. 3, it requires a safety Substances subject to authorisation (Annex XIV REACH) SUITABLE EXTINGUISHING EQUIPMENT - WGK: Water hazard classes (German). data sheet with appropriate information, compliant to (EU) Regulation 2015/830. 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one 10.2. Chemical stability None The extinguishing equipment should be of the conventional kind: carbon dioxide, foam, powder and water spray. 8.2. Exposure controls Corrosive to the rabbit Hazard classification and indication: UNSUITABLE EXTINGUISHING EQUIPMENT 12.4. Mobility in soil Hazard classification and indication: -- The product is stable in normal conditions of use and storage. Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: None in particular. Comply with the safety measures usually applied when handling chemical substances. GENERAL BIBLIOGRAPHY RESPIRATORY OR SKIN SENSITISATION None HAND PROTECTION 1. Regulation (EC) 1907/2006 (REACH) of the European Parliament Information not available 10.3. Possibility of hazardous reactions 5.2. Special hazards arising from the substance or mixture In the case of prolonged contact with the product, protect the hands with penetration-resistant work gloves (see standard EN 374). 2. Regulation (EC) 1272/2008 (CLP) of the European Parliament

2.2 Label elements

May produce an allergic reaction. Substances subject to the Rotterdam Convention: Work glove material must be chosen according to the use process and the products that may form. Latex gloves may cause sensitivity 3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament

Contains

No hazardous reactions are foreseeable in normal conditions of use and storage. None HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE reactions. 4. Regulation (EU) 2015/830 of the European Parliament Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure 13. Regulation (EU) 2017/776 (X Atp. CLP) CARCINOGENICITY May produce an allergic reaction. SECTION 13. Disposal considerations 10.6. Hazardous decomposition products A chemical safety assessment has not been performed for the preparation/for the substances indicated in section 3. Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with compliance with environmental standards. 14. Regulation (EU) 2018/669 (XI Atp. CLP) self-contained open circuit positive pressure compressed air breathing apparatus (BS EN 137). 15. Regulation (EU) 2018/1480 (XIII Atp. CLP) Does not meet the classification criteria for this hazard class Information not available 13.1. Waste treatment methods

Results of PBT and vPvB assessment

Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. Do not breathe combustion products. SKIN PROTECTION 5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 10.4. Conditions to avoid Substances subject to the Stockholm Convention: Wear category I professional long-sleeved overalls and safety footwear (see Regulation 2016/425 and standard EN ISO 20344). Wash body 6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament

Hazard pictograms

On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%. 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one -- None 5.3. Advice for firefighters with soap and water after removing protective clothing. 7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament None in particular. However the usual precautions used for chemical products should be respected. Causes sensitization in guinea pigs

Signal word

EYE PROTECTION 8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament -- Healthcare controls GENERAL INFORMATION Wear airtight protective goggles (see standard EN 166). 9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament GERM CELL MUTAGENICITY 10.5. Incompatible materials Information not available

Hazard statements

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for RESPIRATORY PROTECTION 10. Regulation (EU) 2015/1221 (VII Atp. CLP) of the European Parliament 5-cloro-2-metil-2H-isotiazol-3-one; 2-metil-2H-isotiazol-3-one health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of None required, unless indicated otherwise in the chemical risk assessment. 11. Regulation (EU) 2016/918 (VIII Atp. CLP) of the European Parliament Does not meet the classification criteria for this hazard class The product contains organic halogens EUH210 Safety data sheet available on request. Information not available 15.2. Chemical safety assessment contaminated water used for extinction and the remains of the fire according to applicable regulations. ENVIRONMENTAL EXPOSURE CONTROLS 12. Regulation (EU) 2016/1179 (IX Atp. CLP) EUH208

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