TOBACCO & VANILLE V2 FRAGRANCE 922457

Hazard statements (CLP)

H317, H318, H411

Code

Statements

H317

May cause an allergic skin reaction

H318

Causes serious eye damage.

H411

Toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

Classification under Regulation (EC) No 1272/2008 Classification of the substance or mixture Class and category of Eye Damage / Irritation Category 1

Signal word

Danger

Hazard statements

H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H411, Toxic to aquatic life with long lasting effects.

Additional information

EUH208, Contains ALPHA-ZINGIBERENE, CINNAMAL, COUMARIN, EUGENOL, HELIOTROPINE, TRANS-ANETHOLE. May produce an allergic reaction.

Precautionary statements

P261, Avoid breathing vapour or dust. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Other hazards

Sensitisers declared on a CLP ALPHA-ZINGIBERENE, CINNAMAL, COUMARIN, Hazard Label: EUGENOL, HELIOTROPINE, TRANS-ANETHOLE Hydrocarbon Concentration %: 0.000%

2.1 Classification of the substance or mixture

Class and category of Eye Damage / Irritation Category 1 Classification under Regulation (EC) No 1272/2008 danger: Sensitization - Skin Category 1 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H411, Toxic to aquatic life with long lasting effects. 10 2.2 Label elements Classification under Regulation (EC) No 1272/2008 Signal word: Danger Hazard statements: H317, May cause an allergic skin reaction. H318, Causes serious eye damage. H411, Toxic to aquatic life with long lasting effects. Supplemental EUH208, Contains ALPHA-ZINGIBERENE, CINNAMAL, COUMARIN, EUGENOL, Information: HELIOTROPINE, TRANS-ANETHOLE. May produce an allergic reaction. Precautionary P261, Avoid breathing vapour or dust. statements: P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310, Immediately call a POISON CENTER or doctor/physician. P333/313, If skin irritation or rash occurs: Get medical advice/attention. P363, Wash contaminated clothing before reuse. P391, Collect spillage. P501, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: 2.3 Other hazards Other hazards: Sensitisers declared on a CLP ALPHA-ZINGIBERENE, CINNAMAL, COUMARIN, Hazard Label: EUGENOL, HELIOTROPINE, TRANS-ANETHOLE Hydrocarbon Concentration %: 0.000% 10 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs 4-TERT- oral: ATE = 3370 BUTYLCYCLOHEXYL 32210-23-4 250-954-9 01-2119976286-24-xxxx 10-<20% SS 1B;H317,- mg/kg bw ACETATE (1S,2R,5S,7R,8R)-8- METHOXY-2,6,6,8- SS 1B-EH A1-EH C1; TETRAMETHYLTRICY 67874-81-1 267-510-5 5-<10% H317-H410,- CLO[5.3.1.0^{1,5}] UNDECANE 259-174-3, 54464-57-2, TETRAMETHYL 54464-59-4, 259-175-9, SCI 2-SS 1B-EH C1; ACETYLOCTAHYDRON 68155-66-8, 268-978-3, 01-2119489989-04-xxxx 5-<10% H315-H317-H410,- APHTHALENES 268-979-9, 68155-67-9 915-730-3 ETHYL VANILLIN 121-32-4 204-464-7 1-<5% EDI 2;H319,- oral: ATE = 3000 mg/kg bw dermal: ATE = 2600 VANILLIN 121-33-5 204-465-2 1-<5% EDI 2;H319,- mg/kg bw-oral: ATE = 3300 mg/kg bw OCTAHYDROCOUMAR dermal: ATE = 3500 IN 4430-31-3 224-623-4 1-<5% EDI 1;H318,- mg/kg bw-oral: ATE = 3900 mg/kg bw HELIOTROPINE 120-57-0 204-409-7 1-<5% SS 1B;H317,- oral: ATE = 2700 mg/kg bw ATO 4-ATI 4-EDI 2; inhalation: ATE = 4178 BENZYL ALCOHOL 100-51-6 202-859-9 01-2119492630-38-xxxx 1-<5% H302-H319-H332,- ppmV (gas)-oral: ATE = 1570 mg/kg bw DIMETHYL PHENETHYL 10094-34-5 233-221-8 01-2120742578-44-xxxx 1-<5% EH C2;H411,- BUTYRATE EUGENOL 97-53-0 202-589-1 0.1-<1% EDI 2-SS 1B;H317- oral: ATE = 2500 H319,- mg/kg bw ALPHA-ZINGIBERENE 495-60-3 0.1-<1% SS 1B;H317,- COUMARIN 91-64-5 202-086-7 0.1-<1% ATO 4-SS 1B-EH C3; oral: ATE = 500 mg/kg H302-H317-H412,- bw TRANS-ANETHOLE 4180-23-8 224-052-0 0.1-<1% SS 1B;H317,- oral: ATE = 3000 mg/kg bw SCI 2-EDI 2-SS 1A-EH oral: ATE = 2220 CINNAMAL 104-55-2 203-213-9 0.1-<1% C3;H315-H317-H319- mg/kg bw H412,- Substances with Community workplace exposure limits: Name Specific Conc. CAS EC REACH Registration % Classification for Limits, M-factors No. (CLP) 1272/2008 and ATEs DIETHYL PHTHALATE 84-66-2 201-550-6 01-2119486682-27-xxxx 20-<50% -;-,- Substances that are endocrine disruptors according to Regulation (EU) 2017/2100 or Regulation (EU) 2018/605, greater than 0.1%: Not Applicable 10 Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.1%: Not Applicable Section 4. First-aid measures 4.1 Description of first aid measures Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention. Eye exposure: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Skin exposure: IF ON SKIN: Wash with plenty of soap and water. Ingestion: Rinse mouth with water and obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye damage. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4.1 for further information. Section 5: Firefighting measures 5.1 Extinguishing media Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 10 6.4 Reference to other sections: Also refer to sections 8 and 13. Section 7. Handling and storage 7.1 Precautions for safe handling: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits: Ingredient CAS EC Description Value UK Long-term exposure limit (8-hour TWA) 5 mg/m³ (mg/m3) DIETHYL PHTHALATE 84-66-2 201-550-6 UK Short-term exposure limit (15-minute) 10 mg/m³ (mg/m3) 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. 10 Section 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Physical State/Colour: Clear colourless to pale yellow liquid Odour: Not determined Odour threshold: Not determined Melting point / freezing point: Not determined Boiling point or initial boiling point and boiling Not determined range: Flammability: Not determined Lower and upper explosion limit: Not determined Flash point: > 100 °C Auto-ignition temperature: Not determined Decomposition temperature: Not relevant pH: Not determined Kinematic viscosity: Not determined Solubility: Not determined Partition coefficient: n-octanol/water (log Not determined value): Vapour pressure: 0.01842898 mmHg Density and/or relative density: 1.0360 Relative vapour density: Not determined Particle characteristics: Not determined 9.2 Other information: None available Section 10. Stability and reactivity 10.1 Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 10.2 Chemical stability: Good stability under normal storage conditions. 10.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 10.4 Conditions to avoid: Avoid extreme heat. 10.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 10 10.6 Hazardous decomposition products: Not expected. Section 11. Toxicological information 11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008 This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 1272/2008 (CLP). Acute Toxicity: Based on available data the classification criteria are not met. Acute Toxicity Oral >5000 Acute Toxicity Dermal >5000 Acute Toxicity Inhalation Not Available Skin corrosion/irritation: Based on available data the classification criteria are not met. Serious eye damage/irritation: Eye Damage / Irritation Category 1 Respiratory or skin sensitisation: Sensitization - Skin Category 1 Germ cell mutagenicity: Based on available data the classification criteria are not met. Carcinogenicity: Based on available data the classification criteria are not met. Reproductive toxicity: Based on available data the classification criteria are not met. STOT-single exposure: Based on available data the classification criteria are not met. STOT-repeated exposure: Based on available data the classification criteria are not met. Aspiration hazard: Based on available data the classification criteria are not met. Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE LC50/ATE LC50 Dermal Inhalation Route BENZYL ALCOHOL 100-51-6 202-859-9 1570 Not available 4178 Gas Refer to Sections 2 and 3 for additional information. 11.2 Information on other hazards Not Applicable Section 12. Ecological information 12.1 Toxicity: Toxic to aquatic life with long lasting effects. 12.2 Persistence and degradability: Not available 12.3 Bioaccumulative potential: Not available 12.4 Mobility in soil: Not available 12.5 Results of PBT and vPvB assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 12.6 Endocrine disrupting properties: Not Applicable 10 12.7 Other adverse effects: Not available Section 13. Disposal considerations 13.1 Waste treatment methods: Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 14. Transport information 14.1 UN 14.2 UN Proper Shipping Name: 14.3 Sub Risk: 14.4 Packing number: Transport Group: hazard class (es): UN Model UN3082 ENVIRONMENTALLY HAZARDOUS 9 - III Regulations SUBSTANCE, LIQUID, N.O.S. ((1S,2R, 5S,7R,8R)-8-METHOXY-2,6,6,8- TETRAMETHYLTRICYCLO[5.3.1.0^ {1,5}]UNDECANE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENE S) IMDG UN3082 ENVIRONMENTALLY HAZARDOUS 9 - III SUBSTANCE, LIQUID, N.O.S. ((1S,2R, 5S,7R,8R)-8-METHOXY-2,6,6,8- TETRAMETHYLTRICYCLO[5.3.1.0^ {1,5}]UNDECANE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENE S) MARINE POLLUTANT ADR,RID,ADN UN3082 ENVIRONMENTALLY HAZARDOUS 9 - III SUBSTANCE, LIQUID, N.O.S. ((1S,2R, 5S,7R,8R)-8-METHOXY-2,6,6,8- TETRAMETHYLTRICYCLO[5.3.1.0^ {1,5}]UNDECANE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENE S) ICAO TI UN3082 ENVIRONMENTALLY HAZARDOUS 9 - III SUBSTANCE, LIQUID, N.O.S. ((1S,2R, 5S,7R,8R)-8-METHOXY-2,6,6,8- TETRAMETHYLTRICYCLO[5.3.1.0^ {1,5}]UNDECANE, TETRAMETHYL ACETYLOCTAHYDRONAPHTHALENE S) 14.5 Environmental hazards: This is classified as an environmentally hazardous substance under the UN Model Regulations. This is classified as a Marine Pollutant under the IMDG Code. 14.6 Special precautions for user: None additional 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable 10