PyroBubbles

2.1 Classification of the substance or mixture

Classification according to Not classified according to CLP-regulation regulation (EG) Nr. 1272/2008 Information concerning particular In solid form, this material is not hazardous. Dust generated from grinding hazards for human and environment etc. may cause irritation. Please note the information of this Material Safety Data Sheet. Void 2.3 Other Dangers Other dangers Continued contact with respirable dust in high concentration of this product can affect the lung function. This product is not respirable when being supplied. 3. Composition / Specification of the Elements 3.1 Chemical Characterization Description Multi cellular glass hollow spheres Dangerous substances None 4. First Aid Measures 4.1 Description of First Aid Measures General Information If symptoms persist or in case of doubt, seek medical advice After inhalation Supply fresh air, consult doctor in case of complaints After skin contact Wash with water and soap. Remove contaminated clothes and shoes. After eye contact Rinse the eyes with open eyelids for 10 - 15 minutes with water. Consult doctor in case of persistent complaints After swallowing Rinse mouth with water. Spit all liquid out again. Seek medical treatment. 4.2 Medical Treatment or special Treatment Most important symptoms and After swallowing: Irritant effect on the respiratory tract effects, both acute and delayed Irritation of mucous membranes Medical treatment or special Symptomatic treatment Treatment GENIUS Technologie GmbH • Am Theresenhof 2 • 15834 Rangsdorf / Germany Telefon + 49 (0) 3375 - 24 609 60 • Telefax + 49 (0) 3375 - 24 609 66 • info@genius-group.de • www.pyrobubbles.com Copyrighted • No duplication without prior approval • PyroBubbles® is a registered trademark All rights reserved © Genius Technologie GmbH 22.05.2017 5. Fire Fighting Measures 5.1 Extinguishing Agent Suitable extinguishing agents The product is not combustible and does not support combustion For safety reasons unsuitable High volume water jet extinguishing agents: 5.2 Special Dangers originating from the Product or Mixtures Special dangers None 5.3 Instructions for Fire Extinguishing

2.2 Label elements

Classification according to No labelling required regulation (EG) Nr. 1272/2008

Hazard pictograms

Void

Signal word

Void

Hazard statements

Void

Additional information

Self-contained breathing apparatus 6. Measures in Case of unintentional Emission 6.1 Precautions, Protection Equipment and applicable Methods in Case of Emergencies Person-related safety precautions Avoid contact with eyes and skin. Avoid formation of dust. Ensure adequate ventilation. Please notice chapter 8 6.2 Measures for Environmental Protection Measures for environmental No special measures required protection 6.3 Measures for Cleaning/Collecting Bulk material Recover and dispose in suitable containers. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ake sure to recycle or dispose of in suitable receptacles. Dispose contaminated material as waste according to item 13 6.4 References to other Chapters Information on safe handling See section 7 Information on personal protection See section 8 equipment The general limits of 3 mg/m³ for alveolar dust and 10 mg/m³ for inhalable dust fraction is to be heeded. For details see TRGS 900 8.2 Limitation and monitoring of Exposition Eyes- / face protection In case of dust formation, the use of protective googles is advised Skin- / hand protection The use of protective gloves is advised while handling the material Respiratory protection In case of unintentional release of the substance, exceeding the occupational exposure limit value, use short term filter device. particle filter P2 General protective- and hygienic Do not inhale dust/ smoke/ mist. Use skin protection cream for skin Other parameters listed in appendix 2 REACH regulation are not applicable GENIUS Technologie GmbH • Am Theresenhof 2 • 15834 Rangsdorf / Germany Telefon + 49 (0) 3375 - 24 609 60 • Telefax + 49 (0) 3375 - 24 609 66 • info@genius-group.de • www.pyrobubbles.com Copyrighted • No duplication without prior approval • PyroBubbles® is a registered trademark All rights reserved © Genius Technologie GmbH 22.05.2017 10. Stability and Reactivity 10.1 Reactivity Reactivity No dangers regarding to reactivity 10.2 Chemical Stability Chemical stability Stable under normal conditions 10.3 Possibility of dangerous Reactions Dangerous reactions No dangerous reactions known 10.4 Circumstances to Avoid Circumstances to avoid No special requirements 10.5 Incompatible Materials Incompatible materials No incompatible materials known 10.6 Dangerous Products of Decomposition Dangerous products of No dangerous products of decomposition are known decomposition 11. Potential Health Risks 11.1 Potential Health Risks Potential health risks Does not meet the requirements for classification “dangerous” according to regulation (EG) Nr. 1272/2008 (CLP). See section 7, 8 and 16 11.2 Acute Toxicity Acute toxicity Based on available data, the classification criteria are not met 11.3 Irritation: Skin, Eye Irritation No irritating effect; however, long or repeated mechanical contact may lead to redness an slight irritation Serious eye damage/irritation Eye irritation is possible after mechanical influence (dust) 11.4 Corrosion Corrosion No corroding effect 11.5 Sensitization Sensitization Based on available data, the classification criteria are not met 11.6 Toxicity repeated application Toxicity Non-toxic 11.7 Germ cell Mutagenicity Mutagenicity Based on available data, the classification criteria are not met 11.8 Carcinogenicity Carcinogenicity Based on available data, the classification criteria are not met 11.9 Reproductive Toxicity Reproductive Toxicity Based on available data, the classification criteria are not met GENIUS Technologie GmbH • Am Theresenhof 2 • 15834 Rangsdorf / Germany Telefon + 49 (0) 3375 - 24 609 60 • Telefax + 49 (0) 3375 - 24 609 66 • info@genius-group.de • www.pyrobubbles.com Copyrighted • No duplication without prior approval • PyroBubbles® is a registered trademark All rights reserved © Genius Technologie GmbH 22.05.2017 12. Environment related Information 12.1 Toxicity Toxicity Material is not classified as “dangerous”. No aquatic toxicity, not toxic for treatment plants 12.2 Persistence and Degradability Degradability Not applicable. The material is inorganic. The material is not photosensitive, no chemical or biological degradation is to be expected 12.3 Bioaccumulation Potential Bioaccumulation Not applicable. The material is inorganic. No significant bioaccumulation is to be expected 12.4 Mobility in Soil Mobility in soil No data available General Notes Generally not hazardous for water According to appendix 4 of VwVwS dated 17.05.1999(German regulation) 12.5 Results of the PBT- and vPvB-Evaluation Results of the evaluation No PBT- or vPvB-properties 12.6 Other Harmful Effects

Disposal

See chapter 13 7. Handling and Storage 7.1 Information for safe Handling Information for safe handling Avoid formation of dust, and must be regularly removed. Wear suitable protective gear (for example googles, gloves…). If dust concentration exceeds the regulated limits a suitable, approved breathing apparatus must be used. Prolonged exposure to the skin should be avoided. Wash hands after handling Information about protection against No special measures required. explosions and fires The product is non-combustible, non-oxidizing and not explosive 7.2 Requirements for safe Storage, considering Incompatibilities Requirements to be met by Not required storerooms and receptacles Information about storage in one common storage facility

Storage

Class 13 non-combustible solid (VCI) 7.3 Specific Applications Specific applications Avoid milling and other processes which may produce respirable dust GENIUS Technologie GmbH • Am Theresenhof 2 • 15834 Rangsdorf / Germany Telefon + 49 (0) 3375 - 24 609 60 • Telefax + 49 (0) 3375 - 24 609 66 • info@genius-group.de • www.pyrobubbles.com Copyrighted • No duplication without prior approval • PyroBubbles® is a registered trademark All rights reserved © Genius Technologie GmbH 22.05.2017 8. Limitation and monitoring of Exposition / Personal Protective Gear Additional information about design Mechanical ventilation/ exhaustion is recommended of technical systems 8.1 Monitoring of significant Parameters Components with threshold values The product does not contain any relevant quantities of materials with that require monitoring at the critical values that have to be monitored at the workplace workplace

Precautionary statements

protection. Do not eat, drink or smoke while working. Contaminated clothing should be cleaned with a vacuum cleaner, do not brush or blow the clothing. Wash hands bevor breaks and after work 9. Physical and chemical Properties 9.1 Information about elementary Physical and Chemical Properties Physical form Solid Shape Spherical Color White Odor Odorless Grain gross density (kg/m³) 380-520 Bulk density (kg/m³) 235 ± 10% Solubility in / Miscibility with Water Not miscible or difficult to mix