SWELLPRUFE

SECTION 2: Hazards identification

Physical hazards

Not classified

Health hazards

Not classified

Environmental hazards

Not classified

Hazard pictograms

None.

Signal word

None.

Hazard statements

This product is considered an article and does not meet the criteria for classification.

Prevention

Observe good industrial hygiene practices.

Response

Wash hands after handling.

Storage

Store away from incompatible materials.

Disposal

Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC)

Additional information

Processing and/or heating of this product might generate fumes that are potentially irritating to the respiratory system and the eye.

2.1 Classification of the substance or mixture

Not classified. Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement This product is considered an article and does not meet the criteria for classification. Precautionary statement Prevention Observe good industrial hygiene practices. Response Wash hands after handling. Storage Store away from incompatible materials. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information Processing and/or heating of this product might generate fumes that are potentially irritating to the respiratory system and the eye. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Asphalt 8052-42-4 30 - 60 Calcium Carbonate 1317-65-3 10 - 30 Quartz (silica, crystalline) 14808-60-7 10 - 30 Chemical name Common name and synonyms CAS number % Styrene Butadiene Rubber 9003-55-8 3 - 7 (Benzene, ethenyl-, polymer with 1,3-butadiene) Hydrogen sulfide 7783-06-4 3 - 7 DISTILLATES (PETROLEUM), 64742-52-5 1 - 7 HYDROTREATED HEAVY NAPHTHENIC Composition comments The exact concentrations of the above listed chemicals are being withheld as a trade secret. All concentrations are in percent by weight. Non-classification as a carcinogen is based on the non-respirable form of the product. 4. First-aid measures Inhalation Respiration of particles is unlikely during normal use. Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Unlikely route of exposure. Rinse with water. Get medical attention if irritation develops and persists. Ingestion Unlikely route of exposure. Rinse mouth. Drink plenty of water. Get medical attention if symptoms occur. Most important Exposure to fume during installation may produce coughing. symptoms/effects, acute and delayed Indication of immediate medical Treat symptomatically. attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Not applicable. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, Ensure adequate ventilation. Keep unnecessary personnel away. For personal protection, see protective equipment and section 8 of the SDS. emergency procedures Methods and materials for Pick up mechanically; Send for recovery or disposal in suitable receptacles. For waste disposal, containment and cleaning up see section 13 of the SDS. Environmental precautions Avoid release to the environment. 7. Handling and storage Precautions for safe handling Provide adequate ventilation. Observe good industrial hygiene practices. Conditions for safe storage, Store away from incompatible materials (see Section 10 of the SDS). including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Table Z-1 Permissible Exposure Limits (PEL) for Air Contaminants (29 CFR 1910.1000) Components Type Value Form Calcium Carbonate (CAS PEL 5 mg/m3 Respirable fraction. 1317-65-3) 15 mg/m3 Total dust. DISTILLATES PEL 5 mg/m3 Mist. (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5) 2000 mg/m3 500 ppm Quartz (silica, crystalline) PEL 0.05 mg/m3 Respirable dust. (CAS 14808-60-7) US. OSHA Table Z-2 Permissible Exposure Limits (PEL) (29 CFR 1910.1000) Components Type Value Hydrogen sulfide (CAS Ceiling 20 ppm 7783-06-4) US. OSHA Table Z-3 Permissible Exposure Limits (PEL) for Mineral Dusts (29 CFR 1910.1000) Components Type Value Form Calcium Carbonate (CAS TWA 5 mg/m3 Respirable fraction. 1317-65-3) 15 mg/m3 Total dust. 50 mppcf Total dust. 15 mppcf Respirable fraction. Quartz (silica, crystalline) TWA 0.1 mg/m3 Respirable. (CAS 14808-60-7) 2.4 mppcf Respirable. US. ACGIH Threshold Limit Values (TLV) Components Type Value Form Asphalt (CAS 8052-42-4) TWA 0.5 mg/m3 Inhalable fume. DISTILLATES TWA 5 mg/m3 Inhalable fraction. (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5) Hydrogen sulfide (CAS STEL 5 ppm 7783-06-4) TWA 1 ppm Quartz (silica, crystalline) TWA 0.025 mg/m3 Respirable fraction. (CAS 14808-60-7) NIOSH. Immediately Dangerous to Life or Health (IDLH) Values, as amended Components Type Value DISTILLATES IDLH 2500 mg/m3 (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5) Hydrogen sulfide (CAS IDLH 4 % 7783-06-4) NIOSH. Immediately Dangerous to Life or Health (IDLH) Values, as amended Components Type Value 100 ppm Quartz (silica, crystalline) IDLH 50 mg/m3 (CAS 14808-60-7) US. NIOSH: Pocket Guide to Chemical Hazards Recommended Exposure Limits (REL) Components Type Value Form Asphalt (CAS 8052-42-4) Ceiling 5 mg/m3 Fume. Calcium Carbonate (CAS TWA 5 mg/m3 Respirable. 1317-65-3) 10 mg/m3 Total DISTILLATES Ceiling 1800 mg/m3 (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC (CAS 64742-52-5) STEL 10 mg/m3 Mist. Hydrogen sulfide (CAS Ceiling 15 mg/m3 7783-06-4) 10 ppm Quartz (silica, crystalline) TWA 0.05 mg/m3 Respirable dust. (CAS 14808-60-7) Biological limit values ACGIH Biological Exposure Indices (BEI) Components Value Determinant Specimen Sampling Time Asphalt (CAS 8052-42-4) 2.5 µg/l 1-Hydroxypyren Urine * e, with hydrolysis (1-HP) * - For sampling details, please see the source document. Appropriate engineering Good general ventilation should be used. Ventilation rates should be matched to conditions. If controls applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves. Other Normal work clothing (long sleeved shirts and long pants) is recommended. Respiratory protection Inhalation of dusts produced during cutting, grinding or sanding of this product may cause irritation of the respiratory tract Dust mask recommended. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Solid. Form Roll. Color Black. Odor Odorless. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point Not available. Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Negligible. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Explosive properties Not explosive. Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Contact with incompatible materials. Incompatible materials None known. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation Under normal conditions of intended use, this material is not expected to be an inhalation hazard. Skin contact No adverse effects due to skin contact are expected. Eye contact Dust may irritate the eyes. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Processing or heating may cause respiratory irritation and/or coughing. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not known. Components Species Test Results Asphalt (CAS 8052-42-4) Acute Dermal LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 5000 mg/kg Hydrogen sulfide (CAS 7783-06-4) Acute Inhalation LC50 Mouse 634 ppm, 1 Hours Skin corrosion/irritation Not applicable. Serious eye damage/eye