Note: Ingredients listed on restricted chemical lists
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
55-80
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
20-45
General Information
Revision date
2014-12-23
Product name
M-Thane (Part B)
Product name
M-Thane (Part B)
Identification on the label/Trade name
Pro Pack, Seal Pack, Flash Pack, Hardener
Chemical name
Polymeric Isocyanate (Compounded)
Manufacturer Name
GAF
Icons in SDS
Company Information
company name
GAF
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
GHS Classification NFPA and HMIS RATINGS: NFPA Hazard HMIS Hazard Rating Health 2 Health 2 Flammable 1 Flammable 1 Reactive 1 Reactive 1 Special Hazards - Personal Protection X
2.1 Classification of the substance or mixture
Eye Irritant - Category 2 Skin Irritant - Category 2 Skin Sensitizer - Category 1 Respiratory Irritant Target Organ (SE) - Category 3 Target Organ (RE) - Category 2 Carcinogen - Category 2 Acute Toxicity - Category 2 Hazardous to the Aquatic Environment - Category 1
Signal word
Danger
Hazard statements
May cause damage to organs through prolonged or repeated exposure Causes skin irritation Causes serious eye irritation May cause an allergic reaction May cause respiratory irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled Suspected of causing cancer Repeated exposure may cause skin dryness and cracking Harmful if inhaled Toxic to aquatic life ADDITIONAL HAZARD IDENTIFICATION INFORMATION:
Principle Routes of Exposure
Dermal contact, Skin absorption, Eye contact, Inhalation and Ingestion. SIGNS & SYMPTOMS OF EXPOSURE EYES: Liquid, aerosols or vapors are irritating and can cause tearing, reddening and swelling. If left untreated, corneal damage can occur and injury is slow to heal. SKIN: Isocyanates react with skin protein and moisture and can cause irritation, which may include reddening, rash or blistering. INGESTION: Can result in irritation and corrosive action in the mouth, stomach tissue and digestive tract. Symptoms can include sore throat, abdominal pains, nausea, vomiting and diarrhea. INHALATION: Certain operations such as material heating may generate vapor or aerosol concentrations sufficient to cause irritation. Excessive exposure may irritate upper respiratory tract, causing sensitization in susceptible individuals. MDI concentrations below the exposure guidelines may cause allergic reactions to such persons. Symptoms include coughing, difficulty in breathing and a feeling of tightness in the chest. Such effects may be delayed.
Acute Health Hazards
See signs and symptoms above.
Health hazards
Prolonged contact may cause skin and or respiratory sensitization. CARCINOGENICITY: N/A
