Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
<55
EC/CAS
101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
N/A
EC/CAS
26447-40-5
Name of the chemical
Methylenediphenyl diisocyanate (see also specific isomers)
Concentration
1 - 10
General Information
Revision date
2016-09-22
Product name
LRF Adhesive O Part A
Manufacturer Name
GAF
Icons in SDS
Company Information
company name
GAF
GHS Information
Signal word
Danger
Section 2
SECTION 2: Hazards identification
GHS Classification NFPA and HMIS RATINGS: NFPA Hazard HMIS Hazard Rating Health 2 Health 2 Flammable 2 Flammable 2 Reactive 1 Reactive 1 Special Hazards - Personal Protection X
2.1 Classification of the substance or mixture
Eye Irritant - Category 2A Skin Irritant - Category 2 Skin Sensitizer - Category 1 Respiratory Sensitizer Target Organ (SE) - Category 3 Target Organ (RE) - Category 2 Acute Toxicity - Category 4
Signal word
Danger
Hazard statements
May cause damage to organs through prolonged or repeated exposure Causes skin irritation Causes serious eye irritation May cause an allergic reaction May cause allergy or asthma symptoms or breathing difficulties if inhaled Harmful if inhaled ADDITIONAL HAZARD IDENTIFICATION INFORMATION:
Principle Routes of Exposure
Inhalation, Skin Contact, Eye Contact SIGNS & SYMPTONS OF EXPOSURE EYES: Contact may cause eye irritation. May result in corneal opacity (clouding of the eye surface). SKIN: Causes skin burns, irritation and possible allergic reaction. In those who have developed skin sensitization, these symptoms can develop as a result of contact with a very small amount of the liquid material. INGESTION: Harmful if swallowed. Can burn mouth, throat and stomach. Gastrointestinal symptoms include nausea, vomiting and abdominal pain. INHALATION: Inhalation of MDI vapors may cause irritation of the mucous membranes of the nose, throat or trachea, breathlessness, chest discomfort, difficult breathing and reduced pulmonary function.
Acute Health Hazards
See above.
Health hazards
As a result of previous repeated overexposures or a single large dose, certain individuals will develop isocyanate sensitization (chemical asthma) which will cause them to react to a later exposure to isocyanate at levels well below the PEL/TLV. These symptoms, which include chest tightness, wheezing, cough, shortness of breath, or asthmatic attack, could be immediate or delayed up to several hours after exposure. Chronic overexposure to isocyanates has also been reported to cause lung damage, including a decrease in lung function, which may be permanent. Sensitization may be either temporary or permanent. Prolonged contact can cause reddening, swelling, rash, scaling, or blistering. In those who have developed skin sensitization, these symptoms can develop as a result of contact with very small amounts of liquid material. CARCINOGENICITY: None known.