142 Solvent 66/3; Type IIC Mineral Spirits (meets ASTM D-235 Type 2C specifications); Distillates (petroleum), hydrotreated light; 140 Flash Solvent; High-Flash Mineral Spirits; High Flash Stoddard Solvent;

Hazard statements (CLP)

H227, H304, H315, H336, H402, H412

Code

Statements

H227

Combustible liquid

Aspiration hazard

Category 1), H304 | | Acute aquatic toxicity (Category 3), H402 | | Chronic aquatic toxicity (Category 3), H412 Components: | C9-C15 Cycloakanes mixture |60-100| C9-C15 Alkanes mixture |15-40 | | ------------------------------------------------------------------------------------------------------------- 3.2 MIXTURE: Not applicable. . FIRST-AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES: INHALATION: SOLVENT 142 **FIRST AID- Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. SKIN CONTACT: SOLVENT 142 **FIRST AID- Remove contaminated clothing and shoes immediately. Wash affected area with soap or mild detergent and large amounts or water until no evidence of chemical remains (approximately 15-20 minutes). Do not use ointments. Get medical attention immediately. EYE CONTACT: SOLVENT 142 **FIRST AID- Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids, until no evidence of chemical remains (approximately 15-20 minutes). Remove contact lenses, if worn, after initial flush. Get medical attention immediately. INGESTION: SOLVENT 142 **FIRST AID- Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. If victim is drowsy or unconscious, place on the left side with head down. Immediately consult a physician or poison control center, treat symptomatically. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: Eye: Causes serious eye irritation; Skin: Irritating including redness, burning and drying. The degree of irritation depends on the amount of material applied to skin and the time until it is removed. Inhalation: Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Can cause central nervous system (CNS) depression. Symptoms are loss of appetite, muscle weakness, dizziness, and drowsiness. Ingestion: If swallowed, this material may irritate the mucous membranes of the mouth, throat and esophagus. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. It can be readily absorbed by the stomach and intestinal tract. Typical symptoms are cardiovascular disorders, sweetish taste in the mouth, nausea, vomiting, loss of appetite, strong thirst, burning of eyes and bleeding from the nose. Damage may occur to the kidney, liver, skin, respiratory system and central nervous system. C9-C15 Cycloalkanes and C9-C15 Alkanes may be fatal if swallowed and enters airways. ADDITIONAL DATA: No data available . ECOLOGICAL INFORMATION AQUATIC TOXICITY: No data available WATERFOWL TOXICITY: None available PERSISTANCE AND DEGRADABILITY: No data available BIOACCUMULATION: No data available BIOCONCENTRATION FACTOR: No data available BIOLOGICAL OXYGEN DEMAND (BOD): No data available FOOD CHAIN CONCENTRATION POTENTIAL: None noted . DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS: Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly it is the responsibility of the user to determine the proper storage, transportation, treatment and or disposal methodologies for spent materials and residues at time of disposition. Dispose in accordance with all applicable disposal regulations. Incinerate under controlled conditions in a permitted facility. CONTAMINATED PACKAGING: Dispose of as unused product. The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method. RCRA: The unused product is a RCRA hazardous waste if discarded. The RCRA ID number is: D018 If the waste is a spent solvent, the appropriate spent solvent code should be used. DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 48 CFR 262 . TRANSPORT INFORMATION Non-bulk packages (less than or equal to 119 gal) of combustible liquids are not regulated as hazardous materials. Land Transport (DOT) 14.1 USDOT ID Number----------------------> NA1993 14.2 USDOT Shipping Name---------------> Combustible Liquid, n.o.s. (Contains petroleum distillates) `14.3 USDOT Hazard Classification------> Combustible Liquid USDOT Label Codes--------------------> Combustible Liquid 14.4 USDOT Package Code-----------------> III 14.5 Marine Pollutant-------------------------> No 14.6 Special precautions for user--------> Yes Emergency Response Guide--------> 128 Limited quantity Yes. Packaging instruction Exceptions 150. Non-bulk 203. Bulk 241 Quantity limitation Passenger aircraft/rail 60 L. Cargo aircraft 220 L Special provisions 148, IB3, T1, T4, TP1 Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Sea Transport (IMDG) 14.1 UN Number:------------------------------> N/A 14.2 Proper Shipping Name---------------> Not Regulated 14.3 Hazard Class:----------------------------> N/A USDOT Label Codes-------------------> N/A 14.4 Packing Group:-------------------------> N/A 14.5 Environmental hazard----------------> No Air Transport (IATA) 14.1 UN Number:------------------------------> N/A 14.2 Proper Shipping Name:--------------> Not Regulated 14.3 Hazard Class:----------------------------> N/A USDOT Label Codes-------------------> N/A 14.4 Packing Group:--------------------------> N/A 14.5 Environmental hazard-----------------> No . REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: SARA TITLE III (Superfund Amendment and Reauthorization Act) SECTION 302 AND 304: Extremely Hazardous Substance List (40 CFR 355) - Not Listed SECTION 313: Toxic Chemicals Listing (40 CFR 372.65) - Listed; Low level components listed: Toluene <0.1%; Ethylbenzene <0.0001%; Benzene <0.0001%; Naphthalene <0.0001%; Cumene <0.001% SECTION 311/312: Hazard Categorization (40 CFR 370) - Acute Health Hazard, Fire Hazard CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act) SECTION 102(A) Hazardous Substances (40 CFR 302.4) - Not listed SECTION 101(14) Reportable Quantity: None Massachusetts Right to Know Components Nonane CAS 111-84-2 Pennsylvania Right to Know Components Nonane CAS 111-84-2 New Jersey Right to Know Components Nonane CAS 111-84-2 California Prop. 65 Components This product does contain chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm at no more than 0.1%. Toluene <0.1%; Ethylbenzene <0.0001%; Benzene <0.0001%; Naphthalene <0.0001%; Cumene <0.001% TSCA (Toxic Substance Control Act) Nonane CAS-No. 111-84-2, Methylcyclohexane CAS-No. 108-87-2 and Distillates Petroleum, Hydrotreated Light CAS-No.64742-47-9 and all low level components are listed on the TSCA Inventory. International Inventories: All components are listed or exempted. Country or Region Inventory Name On inventory yes/no Australia Australian Inventory of Chemical Substances Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemicals Yes

Medical Conditions Generally Aggravated by Exposure

Skin contact may aggravate an existing dermatitis and people with chronic respiratory conditions. Significant exposure may adversely affect people with pre-existing heart disorders making them more susceptible to irregular heartbeats. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: Note to physicians: Exposure to high concentrations of this material may be associated with cardiac arrhythmias. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias. Other drugs with less arrhythmogenic potential should be considered. . FIRE FIGHTING MEASURES Flash Point: 67°C (152.6°F) (TCC) LEL %:0.8 (V) Auto-ignition: >220°C (>428°F) UEL %:6.0 (V) UNIFORM FIRE CODE: Combustible Liquid Class IIIA 5.1 SUITABLE EXTINGUISHING MEDIA: Foam--> x CO2--> x Dry Chemical--> x Water-fog--> x Other--> Unsuitable extinguishing media: Do not use waterjet. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE COMBUSTIBLE LIQUID DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. Keep containers tightly closed. Isolate from all sources of ignition. Above flash point, vapor-air mixtures are explosive within flammable limits. Closed containers may explode when exposed to extreme heat. Liquid floats on water. CONDITIONS OF FLAMMABILITY: Flammable in the presence of a source of ignition when the temperature is above the flash point. HAZARDOUS COMBUSTION PRODUCTS: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, carbon oxides and other unidentified organic compounds evolve when this material undergoes combustion. 5.3 ADVICE FOR FIREFIGHTERS: Keep unnecessary people away; isolate hazard area and deny entry. Avoid breathing vapors, stay upwind. Do not enter fire area without structural fire fighter's protective equipment including NIOSH/MSHA approved self-contained breathing apparatus (SCBA) in positive pressure mode. Use water spray to knock down vapors. Use halon, carbon dioxide extinguisher or dry powder for small fires. Large fires are best controlled by alcohol foam, fog, and water spray. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Extinguish only if fire can be stopped. Use flooding amounts of water as a fog; solid streams may be ineffective. Cool containers with flooding amounts of water from as far a distance as possible. Avoid breathing vapors; keep upwind. If fire is uncontrollable or containers are exposed to direct flame, water may be ineffective. Fire fighters should wear full fire fighting protective clothing and NIOSH/MSHA approved self-contained breathing apparatus (SCBA) with full face- piece operated in the pressure demand or other positive pressure mode. Water may be used to flush spills away from exposures and to dilute spills to non- flammable mixtures. Do Not Use: Water in straight hose stream will scatter and spread fire and should not be used. Shut off source. Water fog may be used to cool closed containers to prevent pressure build up and possible auto ignition or explosion when exposed to extreme heat. Wear self-contained breathing apparatus for confined spaces and where there is exposure to vapors. . ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Combustible Liquid; Eliminate ignition sources in the vicinity of the spill or released vapor. Immediately evacuate all nonessential people. Verify that responders are properly trained and wearing appropriate respiratory equipment and fire resistant protective clothing during cleanup operations. 6.2 ENVIRONMENTAL PRECAUTIONS: Keep out of water sources, drains and sewers. Do not flush into surface water or sanitary sewer system. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: Methods for cleanup and containment: Use explosion proof equipment. Shut off valves, contain spill, keep out of water sources and sewers, for smaller spills add non-flammable absorbent in spill area. For large spills use foam on spill to minimize vapors clean up by vacuuming then using non-flammable absorbent. Methods for disposal: Place all saturated absorbent, using non-sparking tools, in an approved container for disposal. Minimize breathing vapors and skin contact, ventilate confined areas, open all windows and doors, assure conformity with applicable government regulations. . HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING: This material presents a fire hazard. Liquid quickly evaporates and forms vapor (fumes), which can catch fire and burn with explosive violence. Vapor is heavier than air and can travel considerable distance to a source of ignition and flash back. Avoid breathing vapors in top of shipping container. Use with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid work practices that may release volatile components in the atmosphere. Avoid contaminating soil or releasing material into sewage and drainage systems. Use non-sparking tools to open or close containers. HYGIENE: Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking STATIC HAZARD: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To minimize this hazard, bonding and grounding may be necessary but may not be sufficient. For more information refer to OSHA Standard 29CFR 1910.106 “Flammable and Combustible Liquids” and National Fire Protection Association (NFPA 77) “Recommended Practice on Static Electricity”. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: Follow maximum allowed pile heights specified in the BOCA codes or the NFPA manual. Local fire authorities should be notified for storage of this material in any quantity. Local permits are required for storage in warehouse quantities. Recommended storage temperature: 15 - 25°C. Store large quantities only in cool, dry areas in buildings designed to comply with OSHA 1910.106. Keep containers tight and upright to prevent leakage. Do not contact with oxidizing materials. Keep containers closed when not in use. Do not take internally. CONTAINER WARNINGS: Containers should be Bonded and Grounded when pouring. Avoid free fall of liquid in excess of a few inches. Empty containers release residue and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, or expose such containers to heat, sparks, static electricity or other sources of ignition. Do not attempt to clean. "Empty" drums should be completely drained, properly bunged and promptly returned to a drum re- conditioner. 7.3 SPECIFIC END USES: Apart from the uses mentioned in section 1.2 no other specific uses are stipulated. . EXPOSURE CONTROL (PERSONAL PROTECTION) 8.1 CONTROL PARAMETERS: Ingredient CAS No. % by WT. Exposure Range Limits -------------------------------------------------------------------------------------------------------------- High Flash Mineral 64742-47-8 | 90-100 | 179ppm TWA (ACGIH) Spirits EC-No.265-149-8 | Index-No. 649-422-00-2 | Reg.-No.01-2119484819-18-XXXX | Components: | C9-C15 Cylcoalkanes mixture | 60-100 | 400ppm TWA (ACGIH) | | (Methylcyclohexane) C9-C15Alkanes mixture | 15-40 | 200ppm TWA (ACGIH) | | (Nonane) ------------------------------------------------------------------------------------------------------------ Key: (PEL) = Permissible Exposure Limit OSHA (TLV) = Threshold Limit Value OSHA & ACGIH (STEL) = Short Term Exposure Limit ACGIH (WEEL) = USA. Workplace Environmental Exposure Levels (TWA) = Time Weighted Average CAS = Chemical Abstracts Registry Number IDLH = Immediate Danger to Life and Health N.E. =None Established 8.2 EXPOSURE CONTROLS EXPOSURE GUIDELINES: Consider the potential hazards of this material (Section 2), applicable exposure limits, job activities, and other substances in the work place when designing engineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. ENGINEERING CONTROLS: Provide general dilution or local exhaust ventilation in volume and pattern to keep concentrations within permitted exposure limits. All areas should be ventilated in accordance with OSHA Regulation 29 CFR Part 1910. Explosion proof motors should be used in mechanical ventilation. RESPIRATORY PROTECTION: The specific respirator selected must be based on contamination levels found in the work place, must not exceed the working limits of the respirator and be jointly approved by the National Institute for Occupational Safety and Health and the Mine Safety and Health Administration (NIOSH-MSHA): For known vapor concentrations use a NIOSH/MSHA air purifying respirator with full face-piece and organic vapor cartridge for exposures >1 <10 times ACGIH TWA. For exposures greater than 10 times ACGIH TWA of for unknown vapor concentrations use NIOSH/MSHA approved positive pressure self-contained breathing apparatus (SCBA) with full face-piece. Air purifying respirators do not protect workers in oxygen-deficient atmospheres. BODY CLOTHING: Employee must wear appropriate protective (impervious) clothing and equipment to prevent repeated or prolonged contact with this substance. Use chemical resistant apron or other impervious clothing. Remove and wash contaminated clothing before reuse. SKIN PROTECTION: Employee must wear appropriate protective gloves to prevent contact with this substance. Full contact Material: Fluorinated rubber Minimum layer thickness: 0.7 mm Break through time: 480 min Splash contact Material: Nitrile rubber Minimum layer thickness: 0.4 mm Break through time: 35 min HYGIENE: Use good personal hygiene practices, wash hands before eating, drinking, smoking or using toilet facilities. EYE/FACE PROTECTION: Use safety eyewear with splash-guards or face shield. Emergency shower and eyewash should be easily accessible to the work area. . PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: Solvent 142 (High Flash Mineral Spirits) 64742-47-8 APPEARANCE: Clear liquid COLOR: Colorless ODOR: Characteristic hydrocarbon odor ODOR THRESHOLD: No data available pH: No data Available MOLECULAR WEIGHT: No data available MELTING POINT: -49°C (-56.2°F) BOILING POINT: 192 to 205°C (377.6 to 401°F) SPECIFIC GRAVITY: 0.79 DENSITY (20C): 0.79-0.82 g/ml (20C) VAPOR PRESSURE: 0.5mmHg @ 20C (68.0°F) VAPOR DENSITY: >1 WATER SOLUBILITY: 1.5g/l PARTITION COEFFICIENT N- No data available OCTANOL/WATER FLASH POINT: 67°C (152.6°F) - closed cup EVAPORATION RATE (BUTYL ACETATE=1): <1 UPPER FLAMMABILITY LIMIT: 6% (V) LOWER FLAMMABILITY LIMIT: 0.8% (V) AUTO INGNITION TEMPERATURE: >220°C (>428°F) DECOMPOSITION TEMPERATURE: No data available VISCOSITY: No data available EXPLOSIVE PROPERTIES: No data available OXIDIZING PROPERTIES: No data available Skin contact may aggravate an existing dermatitis and people with chronic respiratory conditions. Significant exposure may adversely affect people with pre-existing heart disorders making them more susceptible to irregular heartbeats. ACUTE TOXICITY: C9-C15 Alkanes: In animal studies utilizing mineral spirits containing up to 22% aromatics indicated that the acute central nervous system effects are reversible. Based on existing animal studies, the potential for persistent effects is not clear. Distillates (petroleum), hydrotreated light: Mineral spirits have produced slight to moderate skin irritation particularly with evaporation from the skin is prevented. Animal studies have demonstrated that mineral spirits produced mild respiratory tract irritation at elevated concentrations. The effects of overexposure shown in Section III are based on acute toxicity profiles. Typical values are: Ingredient |Oral LD50(Rat) |Skin LD50(Rabbit) |Inhalation LC50 | ----------------------------------------------------------------------------------------------------------------- | High Flash Mineral | N.D. | N.D. | N.D. | Spirits | ----------------------------------------------------------------------------------------------------------------- SKIN CORROSION/IRRITATION C9-C15 Alkanes Primary dermal irritation studies (four hour exposure) in rabbits utilizing mineral spirits containing less than 2% aromatics resulted in slight to moderate skin irritation. In humans, mineral spirits have produced slight to moderate skin irritation particularly with evaporation from the skin is prevented. SERIOUS EYE DAMAGE/EYE IRRITATION: No data available RESPIRATORY OR SKIN SENSITIZATION C9-C15 Alkanes In animal studies utilizing mineral spirits containing up to 18%, aromatics skin sensitization is not evident. MUTAGENIC EFFECTS C9-C15 Alkanes In vivo and in vitro studies on mineral spirits containing up to 22 % aromatics indicate that these products are not genotoxic. Carcinogenicity – C9-C15 Alkanes: The National Toxicology Program (NTP) conducted two-year carcinogenicity studies in rats and mice with Stoddard Solvent IIC (less than 2% aromatics). The studies indicated that there was some evidence of carcinogenic activity in male rats (adrenal medulla neoplasms and renal tubule adenoma) but no evidence of carcinogenic activity in female rats. Further, there was equivocal evidence of carcinogenic activity in female mice (hepatocellular adenoma) but no evidence of carcinogenic activity in male mice. A low carcinogenic potential is suggested. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. REPRODUCTIVE TOXICITY C9-C15 Alkanes There were no treatment-related effects on pregnancy rate, mortality or gross post mortem observations in animal studies utilizing mineral spirits containing less than 2% aromatics.

Further information

Bulk Density 6.67lbs/gal. . STABILITY AND REACTIVITY INFORMATION 10.1 REACTIVITY: No data available. 10.2 CHEMICAL STABILITY: Unstable ( ) Stable (X) 10.3 POSSIBILITY OF HAZARDOUS REACTIONS: Vapors may form explosive mixtures with air. HAZARDOUS POLYMERIZATION: May occur ( ) Will not occur (X) 10.4 CONDITIONS TO AVOID: Heat, Sparks, Pilot Lights, Static Electricity, and Open Flame. 10.5 INCOMPATIBLE MATERIALS: Strong oxidants such as caustic soda, liquid chlorine, oxygen, sodium hypochlorite, inorganic acids e.g. hydrochloric acid hydrogen peroxide. Copper or copper alloys. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS: Fumes, Smoke, Carbon Monoxide and Carbon Dioxide.

TOXICOLOGICAL INFORMATION

11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:

Principle Routes of Exposure

Inhalation--> x Skin--> x Ingestion--> x Eye--> x

Potential Acute Health Effects

Effects of overexposure: Eye> Causes serious eye irritation; Skin> Irritating including redness, burning and drying. The degree of irritation depends on the amount of material applied to skin and the time until it is removed. Inhalation> Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Can cause central nervous system (CNS) depression. Symptoms are loss of appetite, muscle weakness, dizziness, and drowsiness. Ingestion> If swallowed, this material may irritate the mucous membranes of the mouth, throat and esophagus. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. It can be readily absorbed by the stomach and intestinal tract. Typical symptoms are cardiovascular disorders, sweetish taste in the mouth, nausea, vomiting, loss of appetite, strong thirst, burning of eyes and bleeding from the nose. Damage may occur to the kidney, liver, skin, respiratory system and central nervous system.

Teratogenic Effects

C9-C15 Alkanes There were no treatment-related effects on pregnancy rate, mortality or gross post mortem observations in animal studies utilizing mineral spirits containing less than 2% aromatics. Specific target organ toxicity (STOT-SE) - single exposure (Globally Harmonized System): Narcotic Effects. Specific target organ toxicity (STOT-RE) - repeated exposure (Globally Harmonized System): no data available