------------> Aromatic 100

Hazard statements (CLP)

H226, H304, H315, H316, H319, H320, H332, H335, H336, H351, H373, H401, H411

Code

Statements

H226

Flammable liquid and vapour

Aspiration hazard

Category 1), H304 | | Acute aquatic toxicity (Category 1), H401 | Components: | 1,2,4-trimethyl 95-63-6 | 30-40 | Flammable liquids (Category 3), H226 benzene EC-No.202-436-9 | | Acute toxicity, Inhalation (Category 4), H332 Index-No. 601-043-00-3 | | Skin irritation (Category 2), H315 Reg.-No. 01-2119472135-42-XXXX | | Eye irritation (Category 2A), H319 | | STOT-SE (Category 3), Respiratory system, H335 | (Category 1), H304 | | Acute aquatic toxicity (Category 2), H401 | | Chronic aquatic toxicity (Category 2) , H411 | Cumene 98-82-8 |0.8-1.4 | Flammable liquids (Category 3), H226 EC-No.202-704-5 | | STOT-SE (Category 3), Respiratory system, H335 Index-No. 601-024-00-X | (Category 1), H304 Reg.-No. 01-2119473983-24-XXXX | | Carcinogenicity (Category 2), H351 | | Acute aquatic toxicity (Category 2), H401 | | Chronic aquatic toxicity (Category 2), H411 | Xylenes 1330-20-7 | 0-5 | Flammable liquids (Category 3), H226 EC-No. 215-535-7 | | Acute toxicity, Inhalation (Category 4), H332 Index-No.601-022-00-9 | | Skin irritation (Category 2), H315 Reg.-No. 01-2119488216-32-XXXX | | Serious eye damage (Category 2B), H320 | | STOT-SE (Category 3), Respiratory system, H332 | | STOT-RE, Inhalation (Category 2), Central | | Nervous System, Liver, Kidney, H373 | (Category 1), H304 | | Acute aquatic toxicity (Category 2), H401 ------------------------------------------------------------------------------------------------------------- 3.2 MIXTURE: Not applicable . FIRST-AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES: INHALATION: AROMATIC 100 **FIRST AID- Remove from exposure area to fresh air immediately. If breathing has stopped, perform artificial respiration. Keep person warm and at rest. Treat symptomatically and supportively. Get medical attention immediately. SKIN CONTACT: AROMATIC 100 **FIRST AID- Remove contaminated clothing and shoes immediately. Wash affected area with soap or mild detergent and large amounts or water until no evidence of chemical remains (approximately 15-20 minutes). Do not use ointments. Get medical attention immediately. EYE CONTACT: AROMATIC 100 **FIRST AID- Wash eyes immediately with large amounts of water, occasionally lifting upper and lower lids, until no evidence of chemical remains (approximately 15-20 minutes). Remove contact lenses, if worn, after initial flush. Get medical attention immediately. INGESTION: AROMATIC 100 **FIRST AID- Do not induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. If victim is drowsy or unconscious, place on the left side with head down. Immediately consult a physician or poison control center, treat symptomatically. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: Eye: Causes eye irritation; Skin: Irritating including redness, burning and drying. The degree of irritation depends on the amount of material applied to skin and the time until it is removed. Inhalation: Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Can cause central nervous system (CNS) depression. Symptoms are loss of appetite, muscle weakness, dizziness, and drowsiness. Ingestion: If swallowed, this material may irritate the mucous membranes of the mouth, throat and esophagus. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. It can be readily absorbed by the stomach and intestinal tract. Typical symptoms are cardiovascular disorders, sweetish taste in the mouth, nausea, vomiting, loss of appetite, strong thirst, burning of eyes and bleeding from the nose. Damage may occur to the kidney, liver, skin, respiratory system and central nervous system. All components may be fatal if swallowed and enters airways. May be fatal if swallowed and enters May be fatal if swallowed and enters No data available

Medical Conditions Generally Aggravated by Exposure

Skin contact may aggravate an existing dermatitis and people with chronic respiratory conditions. Significant exposure may adversely affect people with pre-existing heart disorders making them more susceptible to irregular heartbeats. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: Note to physicians: Exposure to high concentrations of this material may be associated with cardiac arrhythmias. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias. Other drugs with less arrhythmogenic potential should be considered. . FIRE FIGHTING MEASURES Flash Point: 46°C (115°F) (TCC) LEL %:0.9 Auto-ignition: 485°C (905°F) UEL %:6.2 UNIFORM FIRE CODE: Combustible Liquid Class II 5.1 SUITABLE EXTINGUISHING MEDIA: Foam--> x CO2--> x Dry Chemical-- > x Water-fog--> x Other--> Unsuitable extinguishing media: Do not use waterjet. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: FIRE AND EXPLOSION HAZARD: DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPOR-AIR MIXTURES ARE EXPLOSIVE. Keep containers tightly closed. Combustible liquid; isolate from all sources of ignition. Above flash point, vapor-air mixtures are explosive within flammable limits. Closed containers may explode when exposed to extreme heat. Liquid floats on water. CONDITIONS OF FLAMMABILITY: Flammable in the presence of a source of ignition when the temperature is above the flash point. HAZARDOUS COMBUSTION PRODUCTS: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and gases including carbon monoxide, carbon dioxide, carbon oxides and other unidentified organic compounds evolve when this material undergoes combustion. 5.3 ADVICE FOR FIREFIGHTERS: Keep unnecessary people away; isolate hazard area and deny entry. Avoid breathing vapors, stay upwind. Do not enter fire area without structural fire fighter's protective equipment including NIOSH/MSHA approved self-contained breathing apparatus (SCBA) in positive pressure mode. Use water spray to knock down vapors. Use halon, carbon dioxide extinguisher or dry powder for small fires. Large fires are best controlled by alcohol foam, fog, and water spray. Move container from fire area if you can do it without risk. Apply cooling water to sides of containers that are exposed to flames until well after fire is out. Stay away from ends of tanks. For massive fire in cargo area, use unmanned hose holder or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Withdraw immediately in case of rising sound from venting safety device or any discoloration of tank due to fire. Isolate for 1/2 mile in all directions if tank, rail car or tank truck is involved in fire. Extinguish only if fire can be stopped. Use flooding amounts of water as a fog; solid streams may be ineffective. Cool containers with flooding amounts of water from as far a distance as possible. Avoid breathing vapors; keep upwind. If fire is uncontrollable or containers are exposed to direct flame, water may be ineffective. Fire fighters should wear full protective clothing and NIOSH/MSHA approved self-contained breathing apparatus (SCBA) with full face-piece operated in the pressure demand or other positive pressure mode. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixtures. Do Not Use: Water in straight hose stream will scatter and spread fire and should not be used. Shut off source. Water fog may be used to cool closed containers to prevent pressure build up and possible auto ignition or explosion when exposed to extreme heat. Wear self-contained breathing apparatus for confined spaces and where there is exposure to vapors. Use full fire-fighting protective clothing. . ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Extremely Flammable; Eliminate ignition sources in the vicinity of the spill or released vapor. Immediately evacuate all nonessential people. Verify that responders are properly trained and wearing appropriate respiratory equipment and fire resistant protective clothing during cleanup operations. 6.2 ENVIRONMENTAL PRECAUTIONS: Keep out of water sources, drains and sewers. Do not flush into surface water or sanitary sewer system. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: Methods for cleanup and containment: Use explosion proof equipment. Shut off valves, contain spill, for small spills add non-flammable absorbent in spill area. For large spills use foam on spill to minimize vapors clean up by vacuuming then using non-flammable absorbent. Methods for disposal: Place all saturated absorbent, using non-sparking tools, in an approved container for disposal. Minimize breathing vapors and skin contact, ventilate confined areas, open all windows and doors, assure conformity with applicable government regulations. REPORTABLE QUANTITY (RQ): Xylenes - 100 lbs; Cumene – 5000lbs. Blend (Calculated for Xylene) – 4545lbs. The Superfund Amendments and Reauthorization Act Skin contact may aggravate an existing dermatitis and people with chronic respiratory conditions. Significant exposure may adversely affect people with pre-existing heart disorders making them more susceptible to irregular heartbeats. ACUTE TOXICITY: The effects of overexposure shown in Section III are based on acute toxicity profiles. Typical values are: Ingredient |Oral LD50 (Rat) |Skin LD50 (Rabbit) |Inhalation LC50 | ----------------------------------------------------------------------------------------------------------------- | Aromatic 100 | 3492mg/kg | >3160mg/kg | >6193mg/m3/4hr | | (OECD Test 401) | (OECD Test 402) | (OECD Test 403) | 1,2,4Trimethyl- | 6000mg/kg | | 18000mg/m3/4hr | benzene | Xylenes | 4300mg/kg | | 6700ppm/4hr | | Cumene | 2260mg/kg | 12300uL/kg | 10000mg/m3/7hr | | ----------------------------------------------------------------------------------------------------------------- AROMATIC 100 – SKIN CORROSION/IRRITATION: Mildly irritating to skin with prolonged exposure. Based on test data for the material. (OECD Test Guideline 404) SERIOUS EYE DAMAGE/EYE IRRITATION: May cause mild, short-lasting discomfort to eyes. Based on test data for the material. (OECD Test Guideline 405) RESPIRATORY SENSITIZATION: Not a sensitizer in humans or animals. Based on test data for the material. (OECD Test Guideline 406) SKIN SENSITIZATION: Not expected to be a skin sensitizer. MUTAGENIC EFFECTS: Not expected to be a germ cell mutagen, Based on test data for the material. (OECD Test Guidelines 471, 475, 476, and 479)) CARCINOGEN STATUS – IARC Group 1, 2 and 2B Possibly carcinogenic to humans ACGIH: Not classifiable as a human carcinogen. NTP: Reasonably anticipated to be a human carcinogen

Further information

Bulk Density 7.25lbs/gal. . STABILITY AND REACTIVITY INFORMATION 10.1 REACTIVITY: No data available. 10.2 CHEMICAL STABILITY: Unstable ( ) Stable (X) 10.3 POSSIBILITY OF HAZARDOUS REACTIONS: Vapors may form explosive mixtures with air. HAZARDOUS POLYMERIZATION: May occur ( ) Will not occur (X) 10.4 CONDITIONS TO AVOID: Heat, Sparks, Pilot Lights, Static Electricity, and Open Flame. 10.5 INCOMPATIBLE MATERIALS: Strong oxidants such as caustic soda, liquid chlorine, oxygen, sodium hypochlorite, inorganic acids e.g. hydrochloric acid hydrogen peroxide. Copper or copper alloys. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS: Fumes, Smoke, Carbon Monoxide and Carbon Dioxide.

TOXICOLOGICAL INFORMATION

11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:

Principle Routes of Exposure

Inhalation--> x Skin--> x Ingestion--> x

Potential Acute Health Effects

Effects of overexposure: Eye> Causes eye irritation; Skin> Irritating including redness, burning and drying. The degree of irritation depends on the amount of material applied to skin and the time until it is removed. Inhalation> Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Can cause central nervous system (CNS) depression. Symptoms are loss of appetite, muscle weakness, dizziness, and drowsiness. Ingestion> If swallowed, this material may irritate the mucous membranes of the mouth, throat and esophagus. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. It can be readily absorbed by the stomach and intestinal tract. Typical symptoms are cardiovascular disorders, sweetish taste in the mouth, nausea, vomiting, loss of appetite, strong thirst, burning of eyes and bleeding from the nose. Damage may occur to the kidney, liver, skin, respiratory system and central nervous system.

Teratogenic Effects

No data available Specific target organ toxicity (STOT-SE) - single exposure (Globally Harmonized System): May cause drowsiness and dizziness. May be irritating to the respiratory system. Specific target organ toxicity (STOT-RE) - repeated exposure (Globally Harmonized System): No expected to cause organ damage from prolonged and repeated exposure. Based on test data of structurally similar materials

Additional information

No data available 1,2,4-TRIMETHYLBENZENE – SKIN CORROSION/IRRITATION: No data available SERIOUS EYE DAMAGE/EYE IRRITATION: No data available. RESPIRATORY OR SKIN SENSITIZATION: No data available. MUTAGENIC EFFECTS: No data available CARCINOGEN STATUS: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Prolonged or repeated exposure can cause , narcosis, Bronchitis, Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. CUMENE – SKIN CORROSION/IRRITATION Skin - Rabbit Result No skin irritation (OECD Test Guideline 404) SERIOUS EYE DAMAGE/EYE IRRITATION Eyes - Rabbit Result No eye irritation (OECD Test Guideline 405) RESPIRATORY OR SKIN SENSITIZATION Guinea pig Result Did not cause sensitization on laboratory animals. (OECD Test Guideline 406) MUTAGENIC EFFECTS: Mutagenicity (micronucleus test) Mouse - male and female Result: negative CARCINOGEN STATUS: IARC 2B - Group 2B Possibly carcinogenic to humans (Cumene) NTP: Reasonably anticipated to be a human carcinogen (Cumene) Central nervous system depression, Dermatitis, Gastrointestinal disturbance, Damage to the lungs. Liver injury may occur., Kidney injury may occur. XYLENES – SKIN CORROSION/IRRITATION Rabbit Result Skin irritation - 24 h SERIOUS EYE DAMAGE/EYE IRRITATION Eyes - Rabbit Result Moderate eye irritation RESPIRATORY OR SKIN SENSITIZATION: No data available. MUTAGENIC EFFECTS: No information available. CARCINOGEN STATUS: IARC 3 - Group 3 Not classifiable as to its carcinogenicity to humans (Xylene) IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Alcohol may enhance the toxic effects Stimulants such as epinephrine or ephedrine may induce ventricular fibrillation. . ECOLOGICAL INFORMATION 12.1 AQUATIC TOXICITY (Acute): Aromatic 100 - Toxicity to Fish: LC50 Onchorhynus mykiss (Rainbow trout) – 9.2mg/L – 96 h Toxicity to daphnia and other aquatic crustaceans: EC50 Daphnia magna (water flea)- 3.2mg/L – 48 h Toxicity to Algae: EC50 Skeletonema costatum - <1mg/L 1, 2, 4-Trimethylbenzene - Toxicity to fish: LC50 Pimephales promelas (fathead minnow) - 7720 μg/l Fresh water 96 h LC50 Tilapia zillii (Redbelly Tilapia) - 22.4 mg/l Fresh water 96 h Toxicity to daphnia and other aquatic invertebrates: LC50 Cancer magister Zoeal (dinginess crab) 17000 μg/l Marine water 48 h LC50 Elasmopus pectenicrus - 4910 μg/l Marine water 48 h LC50 Palaemonetes pugio (Shrimp) - 5600 μg/l Marine water 48 h Xylenes, mixed isomers - Toxicity to fish: LC50 Lepomis macrochirus –Juvenile (Bluegill) - 15700 μg/l Fresh water 96 h LC50 Lepomis macrochirus (Bluegill 19000 μg/l Fresh water 96 h LC50 Carassius auratus (goldfish) - 16940 μg/l Fresh water 96 h Toxicity to daphnia and other aquatic invertebrates: LC50 Palaemonetes pugio (shrimp) - 8500 μg/l Marine water 48 h Cumene - Toxicity to fish: LC50 Oncorhynchus mykiss (rainbow trout) 2700 μg/l Fresh water 96 h Toxicity to daphnia and other aquatic invertebrates: EC50 Daphnia magna –Neonate (water flea) - 10600 μg/l Fresh water 48 h EC50 Artemia sp. –Nauplii (Brine shrimp eggs) 7400 μg/l Fresh water 48 h 12.2 PERSISTANCE AND DEGRADABILITY: Expected to be readily bio-degradable. 12.3 BIOACCUMULATIVE POTENTIAL: Light Aromatic Naphtha has the potential to bio-accumulate. Percent degraded in 28 days: 78% 1, 2, 4-Trimethylbenzene Log Pow 3.63 low potential Xylenes, mixed isomers Log Pow 3.12 low potential Cumene Log Pow 3.55 low potential Bioconcentration Factor: 1, 2, 4-Trimethylbenzene 243 Xylenes, mixed isomers 8.1-25.9 Cumene 94.69 12.4 MOBILITY IN SOIL: This material is highly volatile and will rapidly partition to air. It is not expected to partition to soil or wastewater solids. RESULTS OF PBT AND vPvB PBT assessment results This substance is not classified as PBT or vPvB. 12.6 OTHER ADVERSE EFFECTS: Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Do not allow this material to run into surface waters, wastewater or soil. . DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS: Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly it is the responsibility of the user to determine the proper storage, transportation, treatment and or disposal methodologies for spent materials and residues at time of disposition. Dispose in accordance with all applicable disposal regulations. Incinerate under controlled conditions in a permitted facility. CONTAMINATED PACKAGING: Dispose of as unused product. The information offered here is for the product as shipped. Use and/or alterations to the product such as mixing with other materials may significantly change the characteristics of the material and alter the RCRA classification and the proper disposal method. RCRA: The unused product is a RCRA hazardous waste if discarded. The RCRA ID numbers are: Xylene U239, Cumene U055, D001 and D018 If the waste is a spent solvent, the appropriate spent solvent code should be used. DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 48 CFR 262 . TRANSPORT INFORMATION Land Transport (DOT) 14.1 USDOT ID Number----------------------> UN1268 14.2 USDOT Shipping Name---------------> Petroleum Distillates, n.o.s. Naphtha Petroleum, (Light Aromatic) 14.3 USDOT Hazard Classification-------> 3 (Flammable Liquid) 14.4 USDOT Package Code-----------------> III 14.5 Marine Pollutant-------------------------> No 14.6 Special precautions for user--------> Yes Emergency Response Guide--------> 128 Reportable quantity---------------------> 4545.45 LBS - Xylenes Sea Transport (IMDG) 14.1 ID Number-----------------------------------> UN1268 14.2 Proper shipping name-------------------> PETROLEUM DISTILLATES, N.O.S. Naphtha Petroleum, (Light Aromatic) 14.3 Hazard Classification--------------------> 3 (Flammable Liquid) Label Codes--------------------------------> None 14.4 Package Code------------------------------> III 14.5 Marine Pollutant---------------------------> No 14.6 Special precautions for user----------> Yes EMS-Number--------------------------------> F-E, S-E Air Transport (IATA) 14.1 ID Number-----------------------------------> UN1268 14.2 Proper shipping name-------------------> Petroleum Distillates, n.o.s. Naphtha Petroleum, (Light Aromatic) 14.3 Hazard Classification--------------------> 3 (Flammable Liquid) Label Codes---------------------------------> 3 14.4 Package Code------------------------------> II 14.5 Environmental hazard-------------------> None 14.6 Special precautions for user----------> Yes Quantity Limitations: Cargo Aircraft-------------------------------> 220L Passenger Aircraft------------------------> 60L . REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: SARA TITLE III (Superfund Amendment and Reauthorization Act) SECTION 302 AND 304: Extremely Hazardous Substance List (40 CFR 355) - Not Listed SECTION 313: Toxic Chemicals Listing (40 CFR 372.65) - Listed; components listed: 1, 2, 4−Trimethylbenzene 95−63−6 <32%; Xylene 1330−20−7 <2.2%; Cumene 98−82−8 <1.1%; SECTION 311/312: Hazard Categorization (40 CFR 370) - Acute Health Hazard, Chronic Health Hazard, Fire Hazard. CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act) SECTION 102(A) Hazardous Substances (40 CFR 302.4) - Components Listed Cumene CAS-No. 98-82-8 <1.1% Reportable Quantity: 5000 lbs Xylenes CAS-No. 1330-20-7 <2.2% Reportable quantity: 100lbs. Blend (Calaculated from Xylene) – 4545lbs. Massachusetts Right to Know Components 1, 2, 4-Trimethylbenzene CAS-No. 95-63-6 Cumene CAS-No. 98-82-8 Xylenes CAS-No. 1330-20-7 Pennsylvania Right to Know Components 1, 2, 4-Trimethylbenzene CAS-No. 95-63-6 Cumene CAS-No. 98-82-8 Xylenes CAS-No. 1330-20-7 New Jersey Right to Know Components 1, 2, 4-Trimethylbenzene CAS-No. 95-63-6 Cumene CAS-No. 98-82-8 Xylenes CAS-No. 1330-20-7 California Prop. 65 Components This product does contain chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. Cumene CAS-No. 98-82-8 <1.1% TSCA (Toxic Substance Control Act) Aromatic 100 CAS 64742-95-6; 1, 2, 4 Trimethylbenzene CAS 95-63-6; Cumene CAS-No. 98-82-8; Xylenes CAS 1330-20-7 all components are listed on the TSCA Inventory International Inventories: Country or Region Inventory Name On inventory yes/no Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemicals Yes