1,1,2,2-Tetrafluoroethane

G Air Liquide

Revision date : 2013-11-18

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GHS04 GHS07
Health risk rating 2
Safety risk rating 4
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

359-35-3

Name of the chemical

1,1,2,2-Tetrafluoroethane

Concentration

628-3

Listed in

General Information

Revision date

2013-11-18

Product name

1,1,2,2-Tetrafluoroethane

Product Synonyms

G R134; R-134; Refrigerant 134

CAS No.

359-35-3

1.2.1 Relevant identified uses

G Semiconductor manufacture, thin film etch

Manufacturer Name

G Air Liquide

Emergency telephone

800-424-9300, +1 703-527-3887

Icons in SDS

GHS04 GHS07

Company Information

company name

G Air Liquide

e-mail address of the competent person responsible for the Safety Data Sheet

sds@airliquide.com

GHS Information

Signal word

WARNING

Hazard Codes

Hazard statements (CLP)

H280, H315, H319, H335, H336

Hazard statements

Code

Statements

H280

Contains gas under pressure; may explode if heated

Section 2

SECTION 2: Hazards identification

OSHA HCS 2012 EU/EEC

2.2 Label elements

CLP WARNING

Hazard statements

H280 - Contains gas under pressure; may explode if heated G H315 - Causes skin irritation H319 - Causes serious eye irritation H335+H336 - May cause respiratory irritation and drowsiness or dizziness G R36/37/38 - Irritating to eyes, respiratory system and skin. R67 - Vapours may cause drowsiness and dizziness. Contains gas under pressure; may explode if heated - H280 G Causes skin irritation - H315 Causes serious eye irritation - H319 May cause respiratory irritation - H335 May cause drowsiness or dizziness - H336 May displace oxygen and cause rapid suffocation

Prevention

G P261 - Avoid breathing gas. P264 - Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. G Avoid breathing gas. - P261 Wash thoroughly after handling. - P264 Use only outdoors or in a well-ventilated area. - P271 Wear protective gloves/protective clothing/eye protection/face protection. - P280

Response

G P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P321 - Specific treatment, see supplemental first aid information. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. Storage/Disposal G P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD G IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. - P304+P340 Call a POISON CENTER or doctor/physician if you feel unwell. - P312 IF ON SKIN: Wash with plenty of soap and water. - P302+P352 Specific treatment, see supplemental first aid information. - P321 If skin irritation occurs: Get medical advice/attention. - P332+P313 Take off contaminated clothing and wash before reuse. - P362 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. - P305+P351+P338 If eye irritation persists: Get medical advice/attention. - P337+P313 Storage/Disposal G Store in a well-ventilated place. Keep container tightly closed. - P403+P233 Store locked up. - P405 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P501

Precautionary statements

G S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Other hazards

CLP G Contact with gas or liquefied gas will cause burns, severe injury and/or frostbite. This material is a simple asphyxiant. May displace or reduce oxygen available for breathing especially in confined spaces.

Further information

NFPA

2.1 Classification of the substance or mixture

CLP G Liquefied Gas - H280 Skin Irritation 2 - H315 Eye Irritation 2 - H319 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects - H336 DSD/DPD G Irritant (Xi) Harmful (Xn) R36/37/38, R67

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