Methacrylonitrile

Hazard statements (CLP)

H225, H301, H311, H320, H330, H335, H361, H370, H372, H373, H402, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

GHS classification Classification of the substance or mixture Self-reactive substances and mixtures Type G Flammable liquids Category 2 Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Vapors) Category 2 Serious eye damage/eye irritation Category 2B Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 1, Category 3 Category 1 central nervous system Category 3 Respiratory irritation Specific target organ toxicity (repeated exposure) Category 1, Category 2 Category 1 central nervous system Category 2 blood system, nasal cavity, liver Acute aquatic toxicity Category 3 Chronic aquatic toxicity Category 3 Pictograms

Signal word

Danger Hazard statements H225 - Highly flammable liquid and vapor H320 - Causes eye irritation H301 - Toxic if swallowed H311 - Toxic in contact with skin H330 - Fatal if inhaled H361 - Suspected of damaging fertility or the unborn child H335 - May cause respiratory irritation H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects H370 - Causes damage to the following organs: central nervous system H372 - Causes damage to the following organs through prolonged or repeated exposure: central nervous system H373 - May cause damage to the following organs through prolonged or repeated exposure: blood system, nasal cavity, liver Precautionary statements-(Prevention) Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Avoid release to the environment Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating / lighting / equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary statements-(Response) IF exposed: Call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Call a POISON CENTER or doctor/physician if you feel unwell Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth In case of fire: Use suitable extinguishing media for extinction Precautionary statements-(Storage) Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary statements-(Disposal) • Dispose of contents/container to an approved waste disposal plant Others

2.3 Other hazards

Not available

2.1 Classification of the substance or mixture

Classification of the substance or mixture Self-reactive substances and mixtures Type G Flammable liquids Category 2 Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Vapors) Category 2 Serious eye damage/eye irritation Category 2B Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 1, Category 3 Category 1 central nervous system Category 3 Respiratory irritation Specific target organ toxicity (repeated exposure) Category 1, Category 2 Category 1 central nervous system Category 2 blood system, nasal cavity, liver Acute aquatic toxicity Category 3 Chronic aquatic toxicity Category 3 Pictograms Signal word Danger Hazard statements H225 - Highly flammable liquid and vapor H320 - Causes eye irritation H301 - Toxic if swallowed H311 - Toxic in contact with skin H330 - Fatal if inhaled H361 - Suspected of damaging fertility or the unborn child H335 - May cause respiratory irritation H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects H370 - Causes damage to the following organs: central nervous system H372 - Causes damage to the following organs through prolonged or repeated exposure: central nervous system H373 - May cause damage to the following organs through prolonged or repeated exposure: blood system, nasal cavity, liver