Acrylonitrile

Hazard statements (CLP)

H225, H301, H310, H315, H317, H318, H330, H335, H336, H350, H360, H370, H372, H401, H411

Code

Statements

H225

Highly flammable liquid and vapour

H301

Toxic if swallowed

H310

Fatal in contact with skin

H315

Causes skin irritation

H317

May cause an allergic skin reaction

H318

Causes serious eye damage.

H330

Fatal if inhaled

H335

May cause respiratory irritation

H336

May cause drowsiness or dizziness

H350

May cause cancer

H360

May damage fertility or the unborn child

H370

Causes damage to organs

H372

Causes damage to organs through prolonged or repeated exposure

H401

Toxic to aquatic life

H411

Toxic to aquatic life with long lasting effects

SECTION 2: Hazards identification

GHS classification Classification of the substance or mixture Flammable liquids Category 2 Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 2 Acute toxicity - Inhalation (Vapors) Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Carcinogenicity Category 1B Reproductive Toxicity Category 1B Specific target organ toxicity (single exposure) Category 1, Category 3 Category 1 nervous system, liver, kidneys, blood system Category 3 Respiratory irritation, Narcotic effects Specific target organ toxicity (repeated exposure) Category 1 Category 1 nervous system, respiratory system, blood system, liver, kidneys, testes Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 2 Pictograms

Signal word

Danger Hazard statements H225 - Highly flammable liquid and vapor H315 - Causes skin irritation H318 - Causes serious eye damage H301 - Toxic if swallowed H310 - Fatal in contact with skin H330 - Fatal if inhaled H350 - May cause cancer H360 - May damage fertility or the unborn child H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H317 - May cause an allergic skin reaction H411 - Toxic to aquatic life with long lasting effects H401 - Toxic to aquatic life H370 - Causes damage to the following organs: nervous system, liver, kidneys, blood system H372 - Causes damage to the following organs through prolonged or repeated exposure: nervous system, respiratory system, blood system, liver, kidneys, testes Precautionary statements-(Prevention) Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not get in eyes, on skin, or on clothing Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Avoid release to the environment Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating / lighting / equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary statements-(Response) IF exposed: Call a POISON CENTER or doctor/physician IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician Wash contaminated clothing before reuse If skin irritation or rash occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth In case of fire: Use suitable extinguishing media for extinction Collect spillage Precautionary statements-(Storage) Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary statements-(Disposal) • Dispose of contents/container to an approved waste disposal plant Others

2.3 Other hazards

Not available

2.1 Classification of the substance or mixture

Classification of the substance or mixture Flammable liquids Category 2 Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 2 Acute toxicity - Inhalation (Vapors) Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Carcinogenicity Category 1B Reproductive Toxicity Category 1B Specific target organ toxicity (single exposure) Category 1, Category 3 Category 1 nervous system, liver, kidneys, blood system Category 3 Respiratory irritation, Narcotic effects Specific target organ toxicity (repeated exposure) Category 1 Category 1 nervous system, respiratory system, blood system, liver, kidneys, testes Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 2 Pictograms Signal word Danger Hazard statements H225 - Highly flammable liquid and vapor H315 - Causes skin irritation H318 - Causes serious eye damage H301 - Toxic if swallowed H310 - Fatal in contact with skin H330 - Fatal if inhaled H350 - May cause cancer H360 - May damage fertility or the unborn child H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H317 - May cause an allergic skin reaction H411 - Toxic to aquatic life with long lasting effects H401 - Toxic to aquatic life H370 - Causes damage to the following organs: nervous system, liver, kidneys, blood system H372 - Causes damage to the following organs through prolonged or repeated exposure: nervous system, respiratory system, blood system, liver, kidneys, testes