Note: Ingredients listed on restricted chemical lists
General Information
Revision date
2024-03-01
Product name
Blue Shield DF
Product Synonyms
Cupric Hydroxide 50 DF, Copper Hydroxide
CAS No.
20427-59-2
1.2.1 Relevant identified uses
Broad-spectrum fungicide and bactericide for use on fruit and vegetable crops
Icons in SDS
Company Information
company name
Fruitfed Supplies (part of PGG Wrightson Ltd)
GHS Information
Signal word
DANGER
Hazard Codes
Hazard statements (CLP)
H302, H317, H318, H373
Hazard statements
Code
Statements
H302
Harmful if swallowed
Section 2
SECTION 2: Hazards identification
HSNO Approval Product is classified as hazardous according to the Hazardous Substances (Hazard Classification) Notice 2020 of the HSNO Act, 1996. HSR000739 Hazardous classification Acute toxicity oral Category 4, Eye damage Category 1, Skin sensitisation Category 1, Specific target organ toxicity (repeated) Category 2, Hazardous to terrestrial vertebrates, Hazardous to the aquatic environment (acute) Category 1, Hazardous to the aquatic environment (chronic) Category 1
Signal word
DANGER
Hazard statements
H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H400H410 Very toxic to aquatic life, and with long-lasting effects. Harmful to terrestrial vertebrates.
Prevention
P102 Keep out of reach or children. P103 Read label before use. P260 Do not breathe dust and spray mist. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing, goggles and respirator.
Response
P101 If medical advice is needed, have product container or label at hand. P301+P312 IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical attention. P363 Wash contaminated clothing before re-use. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P314 Get medical attention if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor. P391 Collect spillage.
Storage
-
Disposal
P501 Dispose of product and containers in accordance with local Regulations. See Section 13 for more details. Additional Label Do not apply directly into or onto water. Requirements Take all reasonable steps to ensure that the substance does not cause any significant adverse effects to the environment beyond the application area.
2.1 Classification of the substance or mixture
Acute toxicity oral Category 4, Eye damage Category 1, Skin sensitisation Category 1, Specific target organ toxicity (repeated) Category 2, Hazardous to terrestrial vertebrates, Hazardous to the aquatic environment (acute) Category 1, Hazardous to the aquatic environment (chronic) Category 1. Pictograms: Signal word: DANGER Hazard statements: H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H400H410 Very toxic to aquatic life, and with long-lasting effects. Harmful to terrestrial vertebrates. Prevention statements: P102 Keep out of reach or children. P103 Read label before use. P260 Do not breathe dust and spray mist. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing, goggles and respirator. Response statements: P101 If medical advice is needed, have product container or label at hand. P301+P312 IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical attention. P363 Wash contaminated clothing before re-use. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P314 Get medical attention if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor. P391 Collect spillage. Storage statement: -