Blue Shield DF

Fruitfed Supplies (part of PGG Wrightson Ltd)

Revision date : 2024-03-01

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GHS07 GHS08 GHS05 GHS09
Health risk rating 4
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

20427-59-2

Name of the chemical

Copper hydroxide

Concentration

100%

General Information

Revision date

2024-03-01

Product name

Blue Shield DF

Product Synonyms

Cupric Hydroxide 50 DF, Copper Hydroxide

CAS No.

20427-59-2

1.2.1 Relevant identified uses

Broad-spectrum fungicide and bactericide for use on fruit and vegetable crops

Icons in SDS

GHS05 GHS07 GHS08 GHS09

Company Information

company name

Fruitfed Supplies (part of PGG Wrightson Ltd)

GHS Information

Signal word

DANGER

Hazard Codes

Hazard statements (CLP)

H302, H317, H318, H373

Hazard statements

Code

Statements

H302

Harmful if swallowed

Section 2

SECTION 2: Hazards identification

HSNO Approval Product is classified as hazardous according to the Hazardous Substances (Hazard Classification) Notice 2020 of the HSNO Act, 1996. HSR000739 Hazardous classification Acute toxicity oral Category 4, Eye damage Category 1, Skin sensitisation Category 1, Specific target organ toxicity (repeated) Category 2, Hazardous to terrestrial vertebrates, Hazardous to the aquatic environment (acute) Category 1, Hazardous to the aquatic environment (chronic) Category 1

Signal word

DANGER

Hazard statements

H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H400H410 Very toxic to aquatic life, and with long-lasting effects. Harmful to terrestrial vertebrates.

Prevention

P102 Keep out of reach or children. P103 Read label before use. P260 Do not breathe dust and spray mist. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing, goggles and respirator.

Response

P101 If medical advice is needed, have product container or label at hand. P301+P312 IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical attention. P363 Wash contaminated clothing before re-use. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P314 Get medical attention if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor. P391 Collect spillage.

Storage

-

Disposal

P501 Dispose of product and containers in accordance with local Regulations. See Section 13 for more details. Additional Label Do not apply directly into or onto water. Requirements Take all reasonable steps to ensure that the substance does not cause any significant adverse effects to the environment beyond the application area.

2.1 Classification of the substance or mixture

Acute toxicity oral Category 4, Eye damage Category 1, Skin sensitisation Category 1, Specific target organ toxicity (repeated) Category 2, Hazardous to terrestrial vertebrates, Hazardous to the aquatic environment (acute) Category 1, Hazardous to the aquatic environment (chronic) Category 1. Pictograms: Signal word: DANGER Hazard statements: H302 Harmful if swallowed. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure. H318 Causes serious eye damage. H400H410 Very toxic to aquatic life, and with long-lasting effects. Harmful to terrestrial vertebrates. Prevention statements: P102 Keep out of reach or children. P103 Read label before use. P260 Do not breathe dust and spray mist. P264 Wash exposed skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves, protective clothing, goggles and respirator. Response statements: P101 If medical advice is needed, have product container or label at hand. P301+P312 IF SWALLOWED: Call a POISON CENTRE or doctor if you feel unwell.. P330 Rinse mouth. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor if you feel unwell. P333+P313 If skin irritation or rash occurs: Get medical attention. P363 Wash contaminated clothing before re-use. P304+P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P314 Get medical attention if you feel unwell. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTRE or doctor. P391 Collect spillage. Storage statement: -

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