CHEMICAL PRODUCT IDENTIFICATION

From Raabe Corporation

Revision date : 2005-07-29

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GHS02
Health risk rating 1
Safety risk rating 2
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

100-41-4

Name of the chemical

Ethylbenzene

Concentration

N/A

Listed in

EC/CAS

1330-20-7

Name of the chemical

Xylene

Concentration

108-88-

Listed in

General Information

Revision date

2005-07-29

Product name

CHEMICAL PRODUCT IDENTIFICATION

Icons in SDS

Company Information

company name

From Raabe Corporation

GHS Information

Signal word

Warning!

Section 2

Contains

one or more reported | carcinogens or suspected carcinogens which are noted NTP, IA RC, of OSHA-Z in the other limits recommended | EMERGENCY _OVERVIEL May be fatal j Harmful if int h ed. Harmful if absorbed through skin. Causes eye irritation. Causes Sxin irritation. apors irritating to eyes and respiratory tract. excreme ly flammable liquid and vapor. Vapors may cause flash Fire or explosion. Extremely Flammable aerosol. Contents under pressure. EYE: May Cause sévere eye irritation. 4 Pp ni burns. Harmru SKTA con INHALATION: Harmful if inhal Prolonged inhal harmful. Exposure to hig! ons of vapors may cause dizziness, breathing difficulty, hea respiratory irritation. Extremely high concentrations may cause drowsiness, staggering, confusion, unconsciousness, coma or death. Excessive inhalation of vapors can cause nasal and respiratory irritation. Liquid or vapor may be irritating to skin, eyes, throat or lungs. Prolonged inhal lation of dusts containing free silica may result in the development of a disabling pulmonary fibrosisClung di isease) known as silicosis. Intentional misuse by deliberately concentrating and inhaling the Respi ratory symptoms associated with pre- ext ur aggravated by exposure to material(s) is this pr duct INGESTION: ; Moderately toxic. May cause stomach discomfort, nausea, vomiting, iarrhea, and narcosis. May cause serious health effects if swallowed. Aspiration of material into the Jungs if swallowed or if vomiting occurs can Cause chemical pneumonitis which can be fatal. May cause nausea, vomiting and diarrhea.

Potential chronic health

chronic overexposure to a component or components in this material has been Found to cause the following effects in laboratory animals: dney damage Eye damage Lung damage Liver damage Spleen damage Anemia - Brain damage Red blood cel] damage Chronic overexposure to a component or components is this product has been suggested as a cause of the following effects in humans: Live r damage Cardiac abnormalities Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. Rats exposed to titanium dioxide dust at 250 mg/m3 developed Tung cancer, however, such exposure levels are not attainable in the workplace with this material. There is evidence that repeated long-term exposure to vapor ; oncentrations areater than 50 pom of n-buty! alcoho] may result in some hearing Toss. Product contains toluene which may be harmful to the fetus based on animal studies Repeated exposure to toluene has been associated with high Frequency hearing loss in laboratory animals. The human consequences of this inding is uncertain. in April 1996, The International Agency for Research on Cancer (IARC) published Monograph 65 which reclassifies Carbon Black into Group 28 Cpossibly carcinogenic to humans). In February 2000 the International Agency for Research on Cancer (TARC) classified e thy lbenzene as possibly carcinogenic to humans (Group 28) on the basis of sufficient evidence for carcinogeni city in experimental animals but jnadeéquate evidence for canter . EYE CONT: Immed es with plenty of water. Get medical atte , iF irritat Flush wit! antities of water for 15 minutes. SKIN CONTACT: Immediately Flush skin with olenty of water. Remove clothin Get medical attention immediately. Wash clothing separately before reuse, Wash thoroughly with soap and water and seek medical attention if irritation persists. Remove contaminated clothing. Launder contaminated clothing before reuse. INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical attention. For inhala Clon overexposure move person to fresh air. If breathing stops, apply rtificial respiration and seek medical attention. Page 4 INGESTION: Since this produc may contain materials which can cause lung damage if a aspirated in nto the a lungs, the decision whether te induce vomit ing or not must be made by a physician after careful consideration of al] materials ingested. FIRE AND EXPLOSIVE PROPERTIES OF THE PRODUCT: Flashpoint . . .......... . ! Less Than -25 @F Explosion Level... ... 2... ' Low CLEL) ~ 1.0 High CUEL)- 13.1 EXTINGUISHING MEDIA: Use Dry Chemical, Carbon Dioxide or Chemical Foam. FIRE-FIGHTING PROCEDURES AND EQUIPMENT: Keep containers tightly closed. Isolate from heat, sparks, and cpen Flame. Closed containers may explode when exposed to extreme heat. contents under pressure. Do not use or store near sources of neat, Sparks or open flame. Keep away from any source of neat such as sunlight, heaters or stoves that could cause the container to burst. Do not puncture or incinerate. Do not crush or place in a garbage compactor. 50 not store above 120 degrees F. Aerosol containers may explode when exposed to extreme heat. Product vapors are heavier than air and may travel a long distance to a source of ignition and flash back. Full protective equipment including self-contained breathing apparatus et oO avoid inhalation of vapors should be used. Water spray should not be used except to keep down vapors or cool closed containers to prevent build-up of pressure. If water is used, fog nozzles are preferred. - ACCIDENTAL RELEASE MEASUR ES CLEAN-UP AND CONTAINMENT : . ; / - Remove all sources of ignition. Avoid heat, sparks, flames and anything which could cause fire. ; . ventilate area of spill and adjacent low lying areas. Avoid breathing solvent vapors. Remove with inert absorbent materials and non-sparking toois. Use water spray to disperse vapors. Minimize br thing gases, vapor, Fumes or decomposition products. Use self- containe d breathing apparatus with full face piece operated in positive pressure mode as needed. HANDLING: Oo Wash hands thoroughly after handling. This product contains chemical(s) which alifornia! proposition 65 list. If the product used an Cali forni a a clear and reasonable warning must Warning! This 5 Ss product contains a che: known to the State ef californi iferm a te cause use cancer.

Storage

Store in a cool dry area with ventilation suitable for storing materials shown in section 2. Keep away from heat, sparks and flame. Keep container closed when not in use, Store in a cool place away from direct sunlight by or any source of ignition. Do not store at temperatures above 120 degrees F. TION 8 ~ EXPOSURE CONTROLS, PERSONAL PROT ECTION RZO35919 ENGINEERING CONTROLS « Sufficient ventilati ion, in volume and Dp a rt be provi ided to keep air contamination below current appli cab a ool sib le exposure ‘pa imgt wna or ACGTH's TLV limit. RESPIRATORY PROTECTION: If workp! ace exposure limits are exceeded f or any component(see section 2 for Razarcous components and exposure 14 imits), @ NIOSH/OSHA approved respirator suitable for components listed is recommended. SKIN PROTECTION: Chemical resistant plastic or rubber gloves recommended for prolonged or repeated contact. EYE PROTECTION: chemical goggles with side shields or face shield recommended if contact with the eyes is likely. OTHER PROTECTIVE EQUIPMENT: Appropriate Impervious clothing is recommended if prolonged or repeated contact is likely HYGIENTC PRACTICES: Wasn hands before eating or smoking. Smoke in designated areas only. SECT TON 9 - PHYSTCAL AND CHEMICAL PROPERTIES Vapor Pressure . ...... .. 5585.20 mm Ha @ 20 C Vapor Density... 2... ee I 3.706 Bolling Range . 2... . ee ew eS LOWer = 1.0 @F Higner - 999.0 oF Specific Gravity. foe eee 2785 Formula weight per volume woe ee 6.5393 LB/GL oc (Calculated, LB/GAL}) . 2... 2: 4,438 voc (calculated) GM/L) . woe ew we ww £6 6537.80 Percent Volatile by weignt. . 79.8662 Percent Volatile by volume os es ww t)) 89.4784 Eva poration Rate 2 ww ee ew ee 7.700 Cn-Butyl Acetate = 1) Viscosity 2... 1 ee ew ee ERS CONDITIONS YO AVOID: Avoid contact with heat, sparks, and open flame. Product may explode if heated. Keep cool, avoid exposure to heat. ENCOMPATIBILITIES: strong oxidizing agents.

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