Freeman 2040AR Part A (Resin)

Freeman Manufacturing & Supply Company

Revision date : 2025-08-29

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

40-70

EC/CAS

26447-40-5

Name of the chemical

Methylenediphenyl diisocyanate (see also specific isomers)

Concentration

1-5

General Information

Revision date

2025-08-29

Product name

Freeman 2040AR Part A (Resin)

supplier name

Freeman Manufacturing & Supply Company

Emergency telephone

+1 800 321-8511, +1 800 424-9300

Icons in SDS

GHS07 GHS08

Company Information

company name

Freeman Manufacturing & Supply Company

e-mail address of the competent person responsible for the Safety Data Sheet

contactus@freemansupply.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H320, H332, H334, H335, H351, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

SECTION 2: Hazards identification

2.2 Label elements

Danger

Hazard statements

H334 – May cause allergy or asthma symptoms of breathing difficulties if inhaled. H317 – May cause an allergic skin reaction. H315 – Causes skin irritation. H351 – Suspected of causing cancer. H373 – May cause damage to the respiratory system through prolonged or repeated exposure by inhalation. H320 – Causes eye irritation. H335 – May cause respiratory irritation. H332 – Harmful if inhaled.

Precautionary statements

P201 – Obtain special instructions before use. P202 – Do not handle until all safety precautions have been read and understood. P260 – Do not breathe fumes, mist, and vapors. P264 – Wash skin and face thoroughly after handling. P271 – Use only outdoors or in a well-ventilated area. P272 – Contaminated work clothing should not be allowed out of the workplace. P280 – Wear protective gloves/protective clothing/eye protection/face protection. P284 – In case of inadequate ventilation, wear respiratory protection. P303+352 – IF ON SKIN (or hair): Wash with plenty of soap and water. P304+340 – IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P305+351+338 – IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P308+313 – IF exposed or concerned: Get medical advice/attention. P312 – Call a POISON CENTER or doctor/physician if you feel unwell. P314 – Get medical advice/attention if you feel unwell. P333+311 – If skin irritation occurs: Call a POISON CENTER or doctor/physician. P337+311 – If eye irritation persists: Call a POISON CENTER or doctor/physician. P342 – If experiencing respiratory symptoms: Call a doctor or emergency medical facility (i.e., 911) P362 – Take off contaminated clothing and wash before reuse. P403+233 – Store in a well-ventilated place. Keep container tightly closed. P405 – Store locked up. P501 – Dispose of contents/container in accordance with federal/state/local regulations.

2.3 Other hazards

Contains isocyanates. Inhalation of isocyanate mists or vapors may cause respiratory irritation, breathlessness, chest discomfort and reduced pulmonary function. Overexposure well above the PEL may result in bronchitis, bronchial spasms, and pulmonary edema. Long term exposure due to isocyanates has been reported to cause lung damage, including reduced lung function which may be permanent. Acute or chronic overexposure to isocyanates may cause sensitization in some individuals, resulting in allergic respiratory reactions including wheezing, shortness of breath, and difficulty breathing. Animal testing indicates that skin contact may be a factor in causing respiratory sensitization.

2.1 Classification of the substance or mixture

Respiratory Sensitization, Category 1 Skin Sensitization, Category 1B Skin Corrosion/Irritation, Category 2 Carcinogenicity, Category 2 Specific Target Organ Toxicity – Repeated Exposure, Category 2 Serious Eye Damage/Eye Irritation, Category 2B Specific Target Organ Toxicity – Single Exposure, Category 3 Acute Toxicity, Category 4 Inhalation

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