Titebond PROvantage Subfloor Adhesive

SECTION 2: Hazards identification

29 CFR 1910.1200) Category 1 Not determined Specific target organ toxicity (repeated exposure) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard Name (29 CFR 1910.1200). Category Route of Target organs Classification of the : FLAMMABLE LIQUIDS - Category 2 exposure substance or mixture n-hexane SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Category 1 Inhalation peripheral nervous CARCINOGENICITY (inhalation) - Category 2 system

Aspiration hazard

TOXIC TO REPRODUCTION (Fertility) (inhalation) - Category 2 TOXIC TO REPRODUCTION (Unborn child) (inhalation) - Category 2 Name SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Result n-hexane irritation) - Category 3 Category 1 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous Information on the likely : Routes of entry anticipated: Oral, Dermal, Inhalation. system (CNS), kidneys and liver) (inhalation) - Category 1

Hazard pictograms

Eye contact : Causes serious eye irritation. Inhalation : May cause respiratory irritation. Skin contact : Defatting to the skin. May cause skin dryness and irritation. Ingestion : Irritating to mouth, throat and stomach. : Marine water Marine water Larvae Acute LC50 14000 µg/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 1.58 mg/l Algae - Pseudokirchnerella 96 hours subcapitata Conclusion/Summary : Not available. information Limited quantity Limited quantity Limited quantity provisions Limited quantity 640 (E) Tunnel code (D/E)

Signal word

Symptoms related to the physical, chemical and toxicological characteristics : Danger Persistence and degradability : Danger Persistence and degradability : Danger

Hazard statements

Eye contact : Highly flammable liquid and vapor. : Adverse symptoms may include the following: Causes serious eye irritation. pain or irritation Suspected of damaging fertility or the unborn child if inhaled. watering Suspected of causing cancer if inhaled. redness May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure if inhaled. (central Date of issue/Date of revision : 6/2/2015. nervous system (CNS), kidneys, liver) Version : 4.1 9/15 : Highly flammable liquid and vapor. Product/ingredient name Aquatic half-life Causes serious eye irritation. Photolysis Biodegradability n-hexane - Suspected of damaging fertility or the unborn child if inhaled. - Readily methanol - Suspected of causing cancer if inhaled. - Readily vinyl acetate - May cause respiratory irritation. - Readily Causes damage to organs through prolonged or repeated exposure if inhaled. (central Date of issue/Date of revision : 6/2/2015. nervous system (CNS), kidneys, liver) Version : 4.1 10/1 : Highly flammable liquid and vapor. Limited quantity Limited quantity Causes serious eye irritation. Suspected of damaging fertility or the unborn child if inhaled. Suspected of causing cancer if inhaled. Date of issue/Date of revision : 6/2/2015. May cause respiratory irritation. Version : 4.1 11/1 Causes damage to organs through prolonged or repeated exposure if inhaled. (central 5 5 nervous system (CNS), kidneys, liver)

Precautionary statements

Date of issue/Date of revision : 6/2/2015. Version : 4.1 9/14 1/15 , it's worth GRABBER ®" www. 5 5 Date of issue/Date of revision : 6/2/2015. Version : 4.1 10/14 1/15 Date of issue/Date of revision : 6/2/2015. Version : 4.1 11/14 1/15 , it's worth GRABBER ®" www. Section 14: Transport information Section 14. Transport information Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Safety Data Sheet Transport in bulk according : Not available. to Annex II of MARPOL Titebond PROvantage Subfloor Adhesive 73/78 and the IBC Code Section 1. Identification Section 15: Regulatory information Section 15. Regulatory information

TOXICOLOGICAL INFORMATION

Inhalation : Adverse symptoms may include the following: respiratory tract irritation coughing increase in fetal deaths Safety Data Sheet reduced fetal weight skeletal malformations Skin contact Titebond PROvantage Subfloor Adhesive : Adverse symptoms may include the following: Skin contact : Adverse symptoms may include the following: irritation Section 1. Identification dryness dryness cracking

Product definition

Ingestion : Titebond PROvantage Subfloor Adhesive : No specific data. Ingestion : No specific data. Product type Delayed and immediate effects and also chronic effects from short and long term exposure : Liquid. Delayed and immediate effects and also chronic effects from short and long term exposure Address Short term exposure : Franklin International Potential immediate : Not available. 2020 Bruck Street Potential immediate : Not available. effects Columbus OH 43207 effects Contact person Potential delayed effects : Franklin Technical Services : Not available. Potential delayed effects : Not available. Telephone Long term exposure : (800) 877-4583 Long term exposure In case of emergency Potential immediate : Franklin Security : Not available. effects (614) 445-1300 Product code Potential delayed effects : 5482 : Not available. Date of issue/Date of revision : 6/2/2015. : Titebond PROvantage Subfloor Adhesive Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal Product type : Liquid. of this product, solutions and any by-products should at all times comply with the Address : Franklin International requirements of environmental protection and waste disposal legislation and any 2020 Bruck Street regional local authority requirements. Dispose of surplus and non-recyclable products Columbus OH 43207 via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Contact person : Franklin Technical Services Waste packaging should be recycled. Incineration or landfill should only be considered Telephone : (800) 877-4583 when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been In case of emergency : Franklin Security cleaned or rinsed out. Empty containers or liners may retain some product residues. (614) 445-1300 Vapor from product residues may create a highly flammable or explosive atmosphere Product code : 5482 inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact Date of issue/Date of revision : 6/2/2015. with soil, waterways, drains and sewers. Print date : 5/10/2016. Chemtrec (24 Hour) Section 14. Transport information : (800) 424 - 9300 Chemtrec International DOT : (703) 527 - 3887 TDG Mexico ADR/RID IMDG IATA Relevant identified uses of the substance or mixture and uses advised against U.S. Federal regulations : Titebond PROvantage Subfloor Adhesive : TSCA 8(a) PAIR: methyl acetate TSCA 8(a) PAIR: methyl acetate Product type : Liquid. TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA All components are listed or exempted. Address : Franklin International 8b): 2020 Bruck Street Clean Air Act Section 112 : Listed Columbus OH 43207 (b) Hazardous Air Contact person Pollutants (HAPs) : Franklin Technical Services Pollutants (HAPs) Telephone Clean Air Act Section 602 : (800) 877-4583 : Not listed Clean Air Act Section 602 : Not listed In case of emergency Class I Substances : Franklin Security Clean Air Act Section 602 : Not listed (614) 445-1300 Product code Class II Substances : 5482 Date of issue/Date of revision SARA 302/304 : 6/2/2015. Print date

ECOLOGICAL INFORMATION

Print date : 5/10/2016. Toxicity Chemtrec (24 Hour) : (800) 424 - 9300 Chemtrec International Product/ingredient name : (703) 527 - 3887 Result Species Exposure Relevant identified uses of the substance or mixture and uses advised against methyl acetate Acute LC50 408000 µg/l Fresh water Fish - Pimephales promelas - 96 hours Juvenile (Fledgling, Hatchling, Not applicable. Weanling) n-hexane Acute EC50 0.89 mg/l Acute EC50 3.9 mg/l Algae Crustaceans 96 hours 48 hours Acute EC50 3.9 mg/l Crustaceans 48 hours OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard Acute LC50 2.5 mg/l Fish - fathead minnow 96 hours Chronic NOEC 4.9 mg/l Crustaceans (29 CFR 1910.1200). 21 days Chronic NOEC 2.8 mg/l Fish - rainbow trout Classification of the methanol 28 days : FLAMMABLE LIQUIDS - Category 2 Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours substance or mixture Acute LC50 2500000 µg/l Marine water SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 Crustaceans - Crangon crangon - 48 hours CARCINOGENICITY (inhalation) - Category 2 Adult Acute LC50 3289 to 4395 mg/l Fresh TOXIC TO REPRODUCTION (Fertility) (inhalation) - Category 2 Daphnia - Daphnia magna - 48 hours water TOXIC TO REPRODUCTION (Unborn child) (inhalation) - Category 2 Neonate Acute LC50 290 mg/l Fresh water SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Fish - Danio rerio - Egg 96 hours Chronic NOEC 9.96 mg/l Marine water irritation) - Category 3 Algae - Ulva pertusa 96 hours vinyl acetate Acute EC50 8.81 mg/l SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous Algae - Pseudokirchnerella 96 hours system (CNS), kidneys and liver) (inhalation) - Category 1 subcapitata Acute EC50 12.6 mg/l Daphnia Bioaccumulative potential Product/ingredient name LogPow BCF Potential n-hexane 4 Safety Data Sheet 501.187 high methyl acetate 0.18 - low methanol -0.77 <10 low vinyl acetate 0.73 Titebond PROvantage Subfloor Adhesive 3.16 low

2.2 Label elements

48 hours Acute LC50 10000 to 100000 µg/l Crustaceans - Crangon crangon - 48 hours Additional

Other hazards

No known significant effects or critical hazards. Section 1. Identification Section 13: Disposal considerations Section 13. Disposal considerations

2.1 Classification of the substance or mixture

Not applicable.

UN Number

1133 UN proper ADHESIVES, OSHA/HCS status shipping name containing : This material is considered hazardous by the OSHA Hazard Communication Standard containing flammable liquid (29 CFR 1910.1200). liquid Classification of the : FLAMMABLE LIQUIDS - Category 2 Transport 3 substance or mixture 3 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2 hazard class(es) CARCINOGENICITY (inhalation) - Category 2 TOXIC TO REPRODUCTION (Fertility) (inhalation) - Category 2 TOXIC TO REPRODUCTION (Unborn child) (inhalation) - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Packing group III irritation) - Category 3 III Environmental No. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (central nervous No. system (CNS), kidneys and liver) (inhalation) - Category 1

Remarks

Special -