F.S.A. Triallate 500 Herbicide

Hazard statements (CLP)

H227, H302, H304, H315, H317, H320, H332, H335, H373, H410

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H320: Causes eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation. H373: May cause damage to organs through prolonged or repeated exposure. H410: Very toxic to aquatic life with long lasting effects.

SUSMP Classification

S5

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Flammable liquids Category 4 Acute Toxicity Oral Category 4

Aspiration hazard

Category 1 Skin Irritation Category 2 Skin Sensitisation Category 1 Eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity - Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 2 Hazardous to aquatic environment Short term/Chronic Category 1

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P260: Do not breathe fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P363: Wash contaminated clothing before reuse. P301+P312 IF SWALLOWED Call a POISON CENTRE or doctor if you feel unwell P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P391: Collect spillage. P370+P378: In case of fire, use carbon dioxide, dry chemical, foam. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P410: Protect from sunlight. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Amber to brown liquid Odour: Characteristic solvent odour.

Health hazards

Technical Triallate is harmful by ingestion and practically nontoxic via dermal exposure or inhalation. Inhalation exposure to large amounts of thiocarbamates may cause itching, scratchy throat, sneezing, and coughing. Triallate is moderately irritating to the skin and is a mild eye irritant. Harmful by inhalation and if swallowed, irritating to eyes and skin, possible skin sensitiser, if aspirated, may cause lung damage.