Adhesive H-AS

Ford-Werke GmbH

Revision date : 2022-03-31

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GHS07 GHS08
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

202-966-0/101-68-8

Name of the chemical

4,4’-Methylenediphenyl diisocyanate

Concentration

0,1-<1 0.1≤C<100 5≤C<100 5≤C<100 5≤C<100

EC/CAS

227-534-9/5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

0,01-< 0.1≤C≤100 5≤C≤100 5≤C≤100 5≤C≤100

General Information

Revision date

2022-03-31

Product name

Adhesive H-AS

supplier name

Ford-Werke GmbH

Emergency telephone

+49 (0) 6132-84463 (GBK GmbH – 24/7

Icons in SDS

GHS07 GHS08

Company Information

company name

Ford-Werke GmbH

e-mail address of the competent person responsible for the Safety Data Sheet

sdseu@ford.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H373

Hazard statements

Code

Statements

H315

Causes skin irritation

Section 2

EU Classification

Chemicals (Health and Safety) and Genetically Modified Organisms (Contained Use) (Amendment etc.) (EU Exit) Regulations

Health hazards

Acute toxicity (inhalation:dust,mist) H332 Harmful if inhaled. Category 4 Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Serious eye damage/eye irritation, H319 Causes serious eye irritation. Category 2 Respiratory sensitisation, Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitisation, Category 1 H317 May cause an allergic skin reaction. Specific target organ toxicity – Single H335 May cause respiratory irritation. exposure, Category 3, Respiratory tract irritation Specific target organ toxicity – H373 May cause damage to organs through Repeated exposure, Category 2 prolonged or repeated exposure. Full text of H- and EUH-statements: see section 16

Adverse physicochemical, human health and environmental effects

No additional information available

2.2 Label elements

Labelling according to The Chemicals (Health and Safety) and Genetically Modified Organisms (Contained Use) (Amendment etc.) (EU Exit) Regulations

Signal word

Danger

Contains

4,4'-methylenediphenyl diisocyanate, o-(p-isocyanatobenzyl)phenyl isocyanate, Methyloxirane, polymer with oxirane ether with 1,2,3-propanetriol polymer with 1,1'-methylenebis[4- isocyanatobenzene]

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.

Prevention

P261 Avoid breathing mist, gas, fume, dust, vapours. P280 Wear protective gloves.

Response

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER, doctor.

Additional information

As from 24 August 2023 adequate training is required before industrial or professional use.

Other hazards which do not result in classification

Persons suffering from allergic reactions to isocyanates should avoid contact with the product. . Persons already sensitised to diisocyanates may develop allergic reactions when using this product. This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII. This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII. The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %

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