Note: Ingredients listed on restricted chemical lists
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
0,1-<1 0.1≤C<100 5≤C<100 5≤C<100 5≤C<100
EC/CAS
227-534-9/5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
0,01-< 0.1≤C≤100 5≤C≤100 5≤C≤100 5≤C≤100
General Information
Revision date
2022-03-31
Product name
Adhesive H-AS
supplier name
Ford-Werke GmbH
Emergency telephone
+49 (0) 6132-84463 (GBK GmbH – 24/7
Icons in SDS
Company Information
company name
Ford-Werke GmbH
e-mail address of the competent person responsible for the Safety Data Sheet
sdseu@ford.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H332, H334, H335, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
EU Classification
Chemicals (Health and Safety) and Genetically Modified Organisms (Contained Use) (Amendment etc.) (EU Exit) Regulations
Health hazards
Acute toxicity (inhalation:dust,mist) H332 Harmful if inhaled. Category 4 Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Serious eye damage/eye irritation, H319 Causes serious eye irritation. Category 2 Respiratory sensitisation, Category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitisation, Category 1 H317 May cause an allergic skin reaction. Specific target organ toxicity – Single H335 May cause respiratory irritation. exposure, Category 3, Respiratory tract irritation Specific target organ toxicity – H373 May cause damage to organs through Repeated exposure, Category 2 prolonged or repeated exposure. Full text of H- and EUH-statements: see section 16
Adverse physicochemical, human health and environmental effects
No additional information available
2.2 Label elements
Labelling according to The Chemicals (Health and Safety) and Genetically Modified Organisms (Contained Use) (Amendment etc.) (EU Exit) Regulations
Signal word
Danger
Contains
4,4'-methylenediphenyl diisocyanate, o-(p-isocyanatobenzyl)phenyl isocyanate, Methyloxirane, polymer with oxirane ether with 1,2,3-propanetriol polymer with 1,1'-methylenebis[4- isocyanatobenzene]
Hazard statements
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure.
Prevention
P261 Avoid breathing mist, gas, fume, dust, vapours. P280 Wear protective gloves.
Response
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER, doctor.
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use.
Other hazards which do not result in classification
Persons suffering from allergic reactions to isocyanates should avoid contact with the product. . Persons already sensitised to diisocyanates may develop allergic reactions when using this product. This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII. This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII. The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %