Methyl Formate Technical

Hazard statements (CLP)

H222

Code

Statements

H222

Extremely flammable aerosol

SECTION 2: Hazards identification

Hazard statements

H319 Causes serious eye irritation. H332 Harmful if inhaled. H302 Harmful if swallowed. H224 Extremely flammable liquid and vapour. H335 May cause respiratory irritation. H371 May cause damage to organs (central nervous system, optical nerv).

Prevention

P280f Wear protective gloves and eye/face protection. P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking. P271 Use only outdoors or in a well-ventilated area. P243 Take precautionary measures against static discharge. P280d Wear eye/face protection. P260i Do not breathe dust/gas/mist/vapours. P260h Do not breathe mist or vapour. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P233 Keep container tightly closed. P242 Use only non-sparking tools. P240 Ground/bond container and receiving equipment. P264 Wash with plenty of water and soap thoroughly after handling. P270 Do no eat, drink or smoke when using this product. www.foamsupplies.com | www.ecomatesystems.com fsispmsds50266

Response

P312 Call a POISON CENTER or doctor/physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P301 + P330 IF SWALLOWED: rinse mouth. P370 + P378.14 In case of fire: Use water spray, dry powder, foam or carbon dioxide for extinction. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P403 + P235 Store in a well-ventilated place. Keep cool.

Precautionary statements

(Disposal) P501 Dispose of contents/container to hazardous or special waste collection point.

Hazard pictograms

F+ Extremely flammable. Xn Harmful.

R-phrase(s)

R12 Extremely flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R68/20/21/22 Harmful: Possible risk of irreversible effects through inhalation, in contact with skin and if swallowed. R36/37 Irritating to eyes and respiratory system.

S-phrase(s)

S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S24 Avoid contact with skin. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33 Take precautionary measures against static discharges. S36/37 Wear suitable protective clothing and gloves.

Hazardous Ingredients

for labelling METHYL FORMATE, METHANOL

2.3 Other hazards

Assessment PBT / vPvB