SHIBAOKE 250 EC

Hazard statements (CLP)

H227, H302+H332, H304, H315, H317, H319, H336, H351, H400, H411

Code

Statements

H227

Combustible liquid

SECTION 2: Hazards identification

GHS Classification Emergency Overview Appearance : liquid Color : Light yellow to yellow Odor : aromatic Combustible liquid. Harmful if swallowed or if inhaled. May be fatal if swallowed and enters air- ways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. GHS Classification Flammable liquids Category 4 Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irri- tation Category 2A Skin sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity - Category 3 (Narcotic effects) single exposure

Aspiration hazard

Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 2 hazard

Signal word

DANGER

Hazard statements

H227 Combustible liquid. H302 + H332 Harmful if swallowed or if inhaled. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects.

Prevention

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.

Response

P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ at- tention. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other physicochemical hazards

Combustible liquid.

Health hazards

Harmful if swallowed. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. May cause drowsiness or dizzi- ness. May be fatal if swallowed and enters airways

Environmental hazards

Very toxic to aquatic life. Toxic to aquatic life with long lasting effects

Other hazards which do not result in classification

None known.

2.1 Classification of the substance or mixture

Flammable liquids : Category 4 Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 2A tation Skin sensitization : Category 1 Carcinogenicity : Category 2 Specific target organ toxicity - : Category 3 (Narcotic effects) single exposure Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 2 hazard