Note: Ingredients listed on restricted chemical lists
EC/CAS
79622-59-6
Name of the chemical
Fluazinam (ISO); 3-Chlor-N-[3-chlor-2,6-dinitro-4-(trifluormethyl)phenyl]-5-(trifluormethyl)pyridin-2-amin (605/2014)
Concentration
>=30-<50
EC/CAS
2634-33-5
Name of the chemical
1,2-Benzisothiazol-3(2H)-one
Concentration
=0,0025-<0,025
General Information
Version
4.1
Revision date
2025-09-29
Product name
ZIGNAL
1.2.1 Relevant identified uses
Fungicide
1.2.2. Uses advised against
Use as recommended by the label
Icons in SDS
Company Information
company name
FMC QUÍMICA DO BRASIL LTDA
GHS Information
Signal word
DANGER
Hazard Codes
Hazard statements (CLP)
H303+H313, H315, H317, H318, H332, H361, H410
Hazard statements
Code
Statements
H303+H313
May be harmful if swallowed or in contact with skin
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Acute toxicity (Oral) : Category 5 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 5 Skin corrosion/irritation : Category 2 Serious eye damage/eye irri- : Category 1 tation Skin sensitization : Sub-category 1B Reproductive toxicity : Category 2 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard
2.2 Label elements
in accordance with ABNT NBR 14725 Standard
Signal word
DANGER
Hazard statements
H303 + H313 May be harmful if swallowed or in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H361 Suspected of damaging fertility or the unborn child. H410 Very toxic to aquatic life with long lasting effects.
Prevention
P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing mist or vapors. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection.
Response
P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. P312 Call a POISON CENTER/ doctor if you feel unwell. P333 + P313 If skin irritation or rash occurs: Get medical ad- vice/ attention. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.
Storage
P405 Store locked up.
Disposal
P501 Dispose of contents/ container to an approved waste disposal plant.
Other hazards which do not result in classification
None known.
