ZIGNAL

Hazard statements (CLP)

H302+H312+H332, H317, H319, H361d, H373, H410

Code

Statements

H302+H312+H332

Harmful if swallowed, in contact with skin or if inhaled

SECTION 2: Hazards identification

GHS Classification GHS Classification Acute toxicity (Oral) Category 4 Acute toxicity (Inhalation) Category 4 Acute toxicity (Dermal) Category 4 Serious eye damage/eye irri- tation Category 2A Skin sensitization Category 1 Reproductive toxicity Category 2 Specific target organ toxicity - Category 2 (Liver, thymus, Lungs, Pancreas, Uterus (including repeated exposure cervix), eye ball, Central nervous system, Stomach) Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

WARNING

Hazard statements

H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H361d Suspected of damaging the unborn child. H373 May cause damage to organs (Liver, thymus, Lungs, Pancreas, Uterus (including cervix), eye ball, Central nervous system, Stomach) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P203 Obtain, read and follow all safety instructions before use. P260 Do not breathe mist or vapors. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or with adequate ventilation. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection.

Response

P301 + P317 + P330 IF SWALLOWED: Get medical help. Rinse mouth. P302 + P352 + P317 IF ON SKIN: Wash with plenty of water. Get medical help. P304 + P340 + P317 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get medical help. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P318 IF exposed or concerned, get medical advice. P333 + P317 If skin irritation or rash occurs: Get medical help. P337 + P317 If eye irritation persists: Get medical help. P362 + P364 Take off contaminated clothing and wash it before reuse. P391 Collect spillage.

Storage

P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

Hazard Statements required by Andean Technical Manual for the Registration and Control of Chemical Pesticides for Agricultural Use (Resolution no. 2075) Harmful if swallowed, in contact with skin or if inhaled.

2.1 Classification of the substance or mixture

Acute toxicity (Oral) : Category 4 Acute toxicity (Inhalation) : Category 4 Acute toxicity (Dermal) : Category 4 Serious eye damage/eye irri- : Category 2A tation Skin sensitization : Category 1 Reproductive toxicity : Category 2 Specific target organ toxicity - : Category 2 (Liver, thymus, Lungs, Pancreas, Uterus (including repeated exposure cervix), eye ball, Central nervous system, Stomach) Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard