MARSHAL 25EC INSECTICIDE

Hazard statements (CLP)

H226, H301, H304, H312, H316, H317, H320, H330, H335, H336, H351, H370, H372, H410

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

GHS Classification Manufacture, Storage and Import of Hazardous Chemicals Rules 1989

2.1 Classification of the substance or mixture

Highly Toxic, Highly flammable liquids GHS Classification Flammable liquids : Category 3 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 2 Acute toxicity (Dermal) : Category 4 Skin corrosion/irritation : Category 3 Serious eye damage/eye irri- : Category 2B tation Skin sensitization : Category 1 Carcinogenicity : Category 2 Specific target organ toxicity - : Category 1 (Nervous system) single exposure Specific target organ toxicity - : Category 3 (Respiratory system, Central nervous system) single exposure Specific target organ toxicity - : Category 1 (Nervous system) repeated exposure Aspiration hazard : Category 1 Short-term (acute) aquatic : Category 1 hazard Long-term (chronic) aquatic : Category 1 hazard

Aspiration hazard

Category 1 Short-term (acute) aquatic Category 1 hazard Long-term (chronic) aquatic Category 1 hazard

Signal word

Danger

Hazard statements

H226 Flammable liquid and vapor. H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H316 Causes mild skin irritation. H317 May cause an allergic skin reaction. H320 Causes eye irritation. H330 Fatal if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H370 Causes damage to organs (Nervous system). H372 Causes damage to organs (Nervous system) through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects.

Prevention

P203 Obtain, read and follow all safety instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe mist or vapors. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protec- tion/ face protection/ hearing protection. P284 Wear respiratory protection.

Response

P301 + P316 + P330 IF SWALLOWED: Get emergency medi- cal help immediately. Rinse mouth. P303 + P361 + P353 + P317 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Get medical help. P304 + P340 + P316 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Get emergency medical help immediately. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P316 IF exposed or concerned: Get emergency medi- cal help immediately. P331 Do NOT induce vomiting. P333 + P317 If skin irritation or rash occurs: Get medical help. P337 + P317 If eye irritation persists: Get medical help. P362 + P364 Take off contaminated clothing and wash it before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P391 Collect spillage.

Storage

P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up.

Disposal

P501 Dispose of contents/ container to an approved waste disposal plant.

Other hazards which do not result in classification

None known.