Quinella Upgrade Herbicide

Hazard statements (CLP)

H227, H304, H315, H320, H335, H360

Code

Statements

H227

Combustible liquid

Hazard statements

This product is classified as: Xi, Irritating. T, Toxic. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg (L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. H227: Combustible liquid. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H335: May cause respiratory irritation. H360: May damage fertility or the unborn child.

SUSMP Classification

S6

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER Flammable liquids Category 4

Aspiration hazard

Category 1 Skin Irritation Category 2 Eye irritation Category 2B Specific Target Organ Toxicity - Single Exposure Category 3 Reproductive Toxicity Category 1

Prevention

P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P261: Avoid breathing fumes, mists, vapours or spray. P262: Do not get in eyes, on skin, or on clothing. P271: Use only outdoors or in a well ventilated area. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 If exposed or concerned Get medical advice P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P404: Store in a closed container. P405: Store locked up. P410: Protect from sunlight. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Dark amber coloured liquid Odour: Characteristic odour.

Health hazards

Pure Quizalofop-p-ethyl is harmful by oral exposure. The reported oral LD50 values of the compound are 1210 to 1670 mg/kg in male rats, and 1182 to 1480 mg/kg in female rats. Mice are only slightly less susceptible to the compound. Quizalofop-p-ethyl has reported LD50 values of 1753 to 2350 mg/kg in male mice and 1805 to 2360 mg/kg in female mice. May cause harm to unborn children, irritating to eyes, respiratory system and skin, irritating to respiratory system and skin, if aspirated, may cause lung damage.