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Hazard statements (CLP)

H226, H302, H304, H312, H317, H332, H335, H372, H411

Code

Statements

H226

Flammable liquid and vapour

SECTION 2: Hazards identification

Hazard statements

This product is classified as Xi, Irritating. T, Toxic. N, Dangerous to the environment. F, Flammable. Hazardous according to the criteria of SW A. Dangerous according to Australian Dangerous Goods (ADG) Code, IATA and IMDG/IMSBC criteria. H226: Flammable liquid and vapour. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H312: Harmful in contact with skin. H317: May cause an allergic skin reaction. H332: Harmful if inhaled. H335: May cause respiratory irritation. H372: Causes damage to organs through prolonged or repeated exposure. H411: Toxic to aquatic life with long lasting effects.

SUSMP Classification

S6

ADG classification

Class 3 Flammable liquids

UN Number

1993, FLAMMABLE LIQUID, N.O.S

Signal word

DANGER Flammable liquids Category 3 Acute Toxicity Oral Category 4

Aspiration hazard

Category 1 Acute Toxicity Dermal Category 4 Skin Corrosion /Irritation Category 2 Skin Sensitisation Category 1 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 4 Specific Target Organ Toxicity- Single Exposure Category 3 Specific Target Organ toxicity - repeated exposure Category 1 Hazardous to aquatic environment Short term/Chronic Category 2

Prevention

P210: Keep away from heat, sparks, open flames and hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical ventilating, lighting and other equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P262: Do not get in eyes, on skin, or on clothing. P264: Wash contacted areas thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well ventilated area. P272: Contaminated wor1< clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P312: Call a POISON CENTRE or doctor if you feel unwell. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P303+P361+P353 IF ON SKIN (or hair) Remove immediately all contaminated clothing. Rinse skin with water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P381: Eliminate all ignition sources if safe to do so. P391: Collect spillage. P370+P378: In case of fire, use foam. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P402+P404: Store in a dry place. Store in a closed container. P403+P235: Store in a well-ventilated place. Keep cool.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Faint peach coloured liquid. Odour: Mercaptan/xylene odour.

Health hazards

Symptoms of acute exposure to organophosphate or cholinesterase-inhibiting compounds may include the following: numbness, tingling sensations, incoordination, headache, dizziness, tremor, nausea, abdominal cramps, sweating, blurred vision, difficulty breathing or respiratory depression, and slow heartbeat. Very high doses may result in unconsciousness, incontinence, and convulsions or fatality. danger of cumulative effects, harmful by inhalation, in contact with skin, and if swallowed, irritating to eyes and respiratory system, respiratory tract irritant, possible skin sensitiser, if aspirated, may cause lung damage. Signs and symptoms associated with mild exposures to organophosphate and carbamate pesticides include: headache, fatigue, dizziness, loss of appetite with nausea, stomach cramps and diarrhoea; blurred vision associated with excessive tearing; contracted pupils of the eye; excessive sweating and salivation; slowed heartbeat, often fewer than 50 per minute; rippling of surface muscles just under the skin. These symptoms may be mistaken for those of flu, heat stroke or heat exhaustion, or upset stomach. Moderately severe organophosphate and carbamate insecticide poisoning cases exhibit all the signs and symptoms found in mild poisonings, but in addition, the victim: is unable to walk; often complains of chest discomfort and tightness; exhibits marked constriction of the pupils (pinpoint pupils); exhibits muscle twitching; has involuntary urination and bowel movement. Severe poisonings are indicated by incontinence, unconsciousness and seizures.