Flotilla Herbicide

Hazard statements (CLP)

H304, H315, H320, H331, H335, H401

Code

Statements

H304

May be fatal if swallowed and enters airways

SECTION 2: Hazards identification

Hazard statements

This product is classified as: Xn, Harmful. Xi, Irritating. N, Dangerous to the environment. Hazardous according to the criteria of SWA. Not subject to the ADG Code when transported in Australia by Road or Rail in packages 500kg(L) or less; or IBCs (refer to SP AU01). However if transported by Air or Sea, this provision does not apply. Then the product is classed as Dangerous (Class 9 Environmentally Hazardous) by IATA and IMDG/IMSBC respectively. See details below and in Section 14 of this SDS. AUH066: Repeated exposure may cause skin dryness or cracking. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H320: Causes eye irritation. H331: Toxic if inhaled. H335: May cause respiratory irritation. H401: Toxic to aquatic life.

SUSMP Classification

None allocated

ADG classification

Class 9 Miscellaneous Dangerous Goods

UN Number

3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

Signal word

DANGER

Aspiration hazard

Category 1 Skin Corrosion /Irritation Category 2 Serious eye damage/eye irritation Category 2B Acute Toxicity Inhalation Category 3 Specific Target Organ Toxicity - Single Exposure Category 3 Hazardous to aquatic environment Short term/Acute Category 2

Prevention

P261: Avoid breathing fumes, mists, vapours or spray. P264: Wash contacted areas thoroughly after handling. P271: Use only outdoors or in a well ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves, protective clothing and eye or face protection.

Response

P362: Take off contaminated clothing and wash before reuse. P301+P310 IF SWALLOWED Immediately call a POISON CENTRE or doctor P301+P330+P331 IF SWALLOWED Rinse mouth. Do NOT induce vomiting P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P332+P313 If skin irritation occurs Get medical advice P337+P313 If eye irritation persists Get medical advice P370+P378: In case of fire, use carbon dioxide, dry chemical, foam, water fog. Alcohol resistant foam is the preferred firefighting medium but, if it is not available, normal foam can be used.

Storage

P405: Store locked up. P403+P233: Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501: Dispose of contents and containers as specified on the registered label. Emergency Overview Physical Description & Colour: Amber coloured mobile liquid Odour: Solvent odour.

Health hazards

Acute toxicity. Fluroxypyr MHE has low acute toxicity. The rat oral LD50 is >5000 mg/kg, the rabbit dermal LD50 is >2000 mg/kg, and the rat inhalation LC50 is >1.0 mg/l, the maximum attainable concentration. Fluroxypyr MHE is not a skin sensitizer in guinea pigs, has no dermal irritation in rabbits, and shows mild ocular irritation in rabbits. irritating to eyes and skin, if aspirated, may cause lung damage, repeated exposure may cause skin dryness or cracking.