Marshal 25 EC

FMC Agroquímica de México, S. de R.L. de C.V

Revision date : 2021-04-27

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GHS06 GHS08 GHS07 GHS09 GHS02
Health risk rating 5
Safety risk rating 1
Environmental risk rating 1

Note: Ingredients listed on restricted chemical lists

EC/CAS

64742-95-6

Name of the chemical

Solvent naphtha (petroleum), light arom

Concentration

20-30

EC/CAS

64742-56-9

Name of the chemical

Distillates (petroleum), solvent-dewaxed light paraffinic

Concentration

20-30

EC/CAS

98-82-8

Name of the chemical

Cumol (2022/692)

Concentration

0.1-1

General Information

Revision date

2021-04-27

Product name

Marshal 25 EC

Product Synonyms

CARBOSULFAN (FMC 35001): 2,3-dihydro-2,2-dimethyl-7-benzofuranyl [(dibutylamino)thio]methylcarbamate (CAS name); 2,3-dihydro-2,2-dimethylbenzofuran-7-yl (dibutylaminothio)methylcarbamate (IUPAC name)

Chemical name

Carbamate

1.2.1 Relevant identified uses

Insecticide

1.2.2. Uses advised against

Use as recommended by the label

Emergency telephone

1 703 / 741-5970

Icons in SDS

GHS02 GHS06 GHS07 GHS08 GHS09 T016

Company Information

company name

FMC Agroquímica de México, S. de R.L. de C.V

e-mail address of the competent person responsible for the Safety Data Sheet

contactomexico@fmc.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H304, H312, H315, H317, H319, H340, H350, H370, H372

Hazard statements

Code

Statements

H304

May be fatal if swallowed and enters airways

Section 2

SECTION 2: Hazards identification

General Hazards This material is considered a dangerous substance or mixture according to the Globally Harmonized System (GHS) Aspiration toxicity Category 1 Acute toxicity - Oral Category 2 Acute toxicity - Dermal Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 2 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Skin sensitization Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Specific target organ toxicity (single exposure) Category 1 Specific target organ toxicity (repeated exposure) Category 1 Acute aquatic toxicity Category 1 Chronic aquatic toxicity Category 1 FLAMMABLE LIQUIDS Category 3

Signal word

Danger

Hazard statements

H304 - May be fatal if swallowed and enters airways H312 - Harmful in contact with skin H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H340 - May cause genetic defects H350 - May cause cancer H370 - Causes damage to organs H372 - Causes damage to organs through prolonged or repeated exposure

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P281 - Use personal protective equipment as required P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P272 - Contaminated work clothing should not be allowed out of the workplace P280 - Wear protective gloves P260 - Do not breathe dust/fume/gas/mist/vapors/spray P273 - Avoid release to the environment P210 - Keep away from heat/sparks/open flames/hot surfaces. No smoking P233 - Keep container tightly closed P240 - Ground/bond container and receiving equipment P241 - Use explosion-proof electrical/ventilating/lighting/.?/equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge

Response

P308 + P311 - If exposed or concerned: Call a POISON CENTER or doctor IF IN EYES P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/ attention IF ON SKIN P312 - Call a POISON CENTER or doctor if you feel unwell P333 + P313 - If skin irritation or rash occurs: Get medical advice/attention P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P363 - Wash contaminated clothing before reuse IF SWALLOWED P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor P331 - Do NOT induce vomiting P330 - Rinse mouth FIRE P370 + P378 - In case of fire: Use CO2, dry chemical, or foam for extinction P391 - Collect spillage

Storage

P405 - Store locked up P403 + P235 - Store in a well-ventilated place. Keep cool

Precautionary statements

Disposal P501 - Dispose of contents/container according to label directions

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