Vinylmagnesium bromide 1M in THF

Hazard statements (CLP)

H225, H260, H302, H314, H335, H351

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture Classification H225 Flam. Liq. 2 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H335 STOT SE 3 H351 Carc. 2

Signal word

Danger

Hazard pictograms

GHS02 GHS05 GHS07 GHS08 H225 Highly flammable liquid and vapour. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. H351 Suspected of causing cancer.

Precautionary statements

P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223 Do not allow contact with water. P231+P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P235 Keep cool. P240 Ground and bond container and receiving equip- ment. P241 Use explosion-proof equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing and eye/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water or wrap in wet ban- dages. P303+P361+P353 IF ON SKIN (or hair): Take off immedi- ately all contaminated clothing. Rinse skin with water. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER/doctor. P321 Specific treatment (see Section 4 on this SDS). P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use dry sand to extinguish. P402+P404 Store in a dry place. Store in a closed con- tainer. P403+P233 Store in a well-ventilated place. Keep con- tainer tightly closed. P405 Store locked up. P501 Dispose of contents/container to hazardous waste disposal.

Supplemental label elements

EUH014 Reacts violently with water. EUH018 In use may form flammable/explosive vapour-air mixture. EUH019 May form explosive peroxides.

2.3 Other hazards

Other Classification Hazards This substance/mixture contains no components consid- ered to be either persistent, bioaccumulative and toxic PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties for environ- ment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

TOXICOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties affecting hu- man health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

2.1 Classification of the substance or mixture

Classification H225 Flam. Liq. 2 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H335 STOT SE 3