Samarium(II) iodide solution 0.1 M in THF, contains samarium chips as stabiliser

Hazard statements (CLP)

H224, H260, H302, H314, H319, H335, H336, H351

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture Classification EUH014 EUH019 H224 Flam. Liq. 1 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H319 Eye Irrit. 2 H335 STOT SE 3 H336 STOT SE 3 H351 Carc. 2

Signal word

Danger

Hazard pictograms

GHS02 GHS05 GHS07 GHS08 EUH014 Reacts violently with water. EUH019 May form explosive peroxides. H224 Extremely flammable liquid and vapour. H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer if inhaled.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P223 Do not allow contact with water. P231+P232 Handle and store contents under inert gas. Protect from moisture. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing and eye/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT in- duce vomiting. P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see Section 4 on this SDS). P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P370+P378 In case of fire: Use sand, extinguishing powder or alcohol-resistant foam to extinguish. P402+P404 Store in a dry place. Store in a closed container. P405 Store locked up. P501 Dispose of contents/container to hazardous waste disposal.

Supplemental label elements

None

2.3 Other hazards

Other Classification Hazards This substance/mixture contains no components con- sidered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

This substance/mixture contains no components con- sidered to have endocrine disrupting properties for envi- ronment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

TOXICOLOGICAL INFORMATION

This substance/mixture contains no components con- sidered to have endocrine disrupting properties affect- ing human health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

2.1 Classification of the substance or mixture

Classification EUH014 EUH019 H224 Flam. Liq. 1 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H319 Eye Irrit. 2 H335 STOT SE 3 H336 STOT SE 3