Piperazine

Hazard statements (CLP)

H228, H314, H317, H334, H361

Code

Statements

H228

Flammable solid

SECTION 2: Hazards identification

Classification of the substance or mixture Classification H228 Flam. Sol. 1 H314 Skin Corr. 1B H317 Skin Sens. 1 H334 Resp. Sens. 1 H361 Repr. 2

Signal word

Danger

Hazard pictograms

GHS02 GHS05 GHS07 GHS08 H228 Flammable solid. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H361 Suspected of damaging fertility or the unborn child.

Precautionary statements

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof equipment. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing and eye/face protec- tion. P284 Wear respiratory protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all con- taminated clothing. Rinse skin with water or shower. P304+P340 IF INHALED: Remove person to fresh air and keep com- fortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for sev- eral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER/doctor. P321 Specific treatment (see Section 4 on this SDS). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON P361+P364 Take off immediately all contaminated clothing and wash it before reuse. P370+P378 In case of fire: Use dry sand to extinguish. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container to hazardous waste disposal.

Supplemental label elements

None

2.3 Other hazards

Other Classification Hazards This substance/mixture contains no components consid- ered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties for environ- ment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

TOXICOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties affecting hu- man health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

2.1 Classification of the substance or mixture

Classification H228 Flam. Sol. 1 H314 Skin Corr. 1B H317 Skin Sens. 1 H334 Resp. Sens. 1 H361 Repr. 2