Ethylmagnesium bromide, 3M in 2-MeTHF

Hazard statements (CLP)

H225, H260, H302, H314, H315, H318

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Classification of the substance or mixture Classification H225 Flam. Liq. 2 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H315 Skin Irrit. 2 H318 Eye Dam. 1

Signal word

Danger

Hazard pictograms

GHS02 GHS05 GHS07 H225 Highly flammable liquid and vapour. H260 In contact with water releases flammable gases which may ig- nite spontaneously. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P223 Do not allow contact with water. P231+P232 Handle and store contents under inert gas. Protect from moisture. P233 Keep container tightly closed. P240 Ground and bond container and receiving equipment. P241 Use explosion-proof equipment. P242 Use non-sparking tools. P243 Take action to prevent static discharges. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing and eye/face protec- tion. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all con- taminated clothing. Rinse skin with water. P304+P340 IF INHALED: Remove person to fresh air and keep com- fortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for sev- eral minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see Section 4 on this SDS). P335 Brush off loose particles from skin. P337+P313 If eye irritation persists: Get medical advice/attention. P370+P378 In case of fire: Use dry sand to extinguish. P403+P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. P501 Dispose of contents/container to hazardous waste disposal.

Supplemental label elements

EUH014 Reacts violently with water. EUH019 May form explosive peroxides

2.3 Other hazards

Other Classification Hazards This substance/mixture contains no components consid- ered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

ECOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties for environ- ment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

TOXICOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties affecting hu- man health, according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100.

2.1 Classification of the substance or mixture

Classification H225 Flam. Liq. 2 H260 Water-react. 1 H302 Acute Tox. 4 H314 Skin Corr. 1B H315 Skin Irrit. 2 H318 Eye Dam. 1