1,4-Phenylene Diisocyanate

Hazard statements (CLP)

H315, H317, H319, H330, H334, H335, H411

Code

Statements

H315

Causes skin irritation

SECTION 2: Hazards identification

Classification of the substance or mixture Classification H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H330 Acute Tox. 2 H334 Resp. Sens. 1 H335 STOT SE 3 H411 Aquatic Chronic 2

Signal word

Danger

Hazard pictograms

GHS06 GHS07 GHS08 GHS09 H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H330 Fatal if inhaled. H334 May cause allergy or asthma symptoms or breath- ing difficulties if inhaled. H335 May cause respiratory irritation. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing and eye/face protection. P284 Wear respiratory protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immedi- ately all contaminated clothing. Rinse skin with water or shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with wa- ter for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P320 Specific treatment is urgent (see Section 4 on this SDS). P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P361+P364 Take off immediately all contaminated cloth- ing and wash it before reuse. P391 Collect spillage. P405 Store locked up. P501 Dispose of contents/container to hazardous waste disposal.

Supplemental label elements

None

2.3 Other hazards

Other Classification Hazards This substance/mixture contains no components consid- ered to be either persistent, bioaccumulative and toxic PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher

ECOLOGICAL INFORMATION

This substance/mixture contains no components consid- ered to have endocrine disrupting properties for environ- ment , according to REACH Article 57(f), Commission Regulation (EU) 2018/605 or Commission Delegated Regulation (EU) 2017/2100. an health, according to REACH Article 57(f), Commission

2.1 Classification of the substance or mixture

Classification H315 Skin Irrit. 2 H317 Skin Sens. 1 H319 Eye Irrit. 2 H330 Acute Tox. 2 H334 Resp. Sens. 1 H335 STOT SE 3 H411 Aquatic Chronic 2