Technical Grade d-Limonene Substance Name (EINECS): Orange, extractives

SECTION 2: Hazards identification

Most important adverse effects

R10 – Flammable R38 – Irritating to skin R43 – May cause sensitization by skin contact R50/53 – Very toxic to aquatic organisms; may cause long term adverse effects in the aquatic

Environmental hazards

R65 – Harmful: may cause lung damage if swallowed Per Regulation 67/548/EEC Danger! Graphical indication of hazards

Hazard statements

H226 – Flammable liquid and vapor H304 – May be fatal if swallowed and enters airways H315 – Causes skin irritation H317 – May cause an allergic skin reaction H400 – Very toxic to aquatic life H410 – Very toxic to aquatic life with long lasting effects

Precautionary statements

P210 – Keep away from heat/sparks/open flames/hot surfaces. — No smoking P233 – Keep container tightly closed P240 – Ground/bond container and receiving equipment P241 – Use explosion-proof electrical/ventilating/lighting/equipment P242 – Use only non-sparking tools P243 – Take precautionary measures against static discharge P261 – Avoid breathing dust/fume/gas/mist/vapors/spray P264 – Wash contaminated items thoroughly after handling P272 – Contaminated work clothing should not be allowed out of the workplace P273 – Avoid release to the environment P280 – Wear protective gloves/protective clothing/eye protection/face protection P301 + P310 – IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302 + P352 – IF ON SKIN: Wash with plenty of soap and water P303 + P361 +P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P321 - Specific treatment See first aid instructions. P331 – Do NOT induce vomiting P332 + P313 – If skin irritation occurs: Get medical advice/attention P362 – Take off contaminated clothing and wash before reuse P363 – Wash contaminated clothing before reuse P370 + P378 – In case of fire: Use carbon dioxide, foam or dry chemical for extinction P391 – Collect spillage P403 + P235 - Store in a well-ventilated place Keep cool. P405 – Store locked up 501 – Dispose of contents/containers in accordance with local/regional/national/international regulations. FDA – Food Additives Generally Recognized as Safe (GRAS) 182.20

2.1 Classification of the substance or mixture

Substance Marine pollutant