10513506 - FIX-R Primer 10 4L

FIX-R

Revision date : 2023-07-20

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GHS02 GHS08 GHS07
Health risk rating 5
Safety risk rating 2
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

N/A

EC/CAS

5873-54-1

Name of the chemical

2,4’-Methylenediphenyl diisocyanate

Concentration

N/A

General Information

Revision date

2023-07-20

Product name

10513506 - FIX-R Primer 10 4L

1.2.1 Relevant identified uses

Primers. For professional users/industrial user only

1.2.2. Uses advised against

All uses not specified in this section or in section 7.3

Emergency telephone

+44 (0) 1274 696979

Icons in SDS

GHS02 GHS07 GHS08 M009 M010 M013 M017 M032 T021

Company Information

company name

FIX-R

e-mail address of the competent person responsible for the Safety Data Sheet

sigassured@sigplc.com

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H226, H315, H317, H319, H334, H335, H351, H373, H412

Hazard statements

Code

Statements

H226

Flammable liquid and vapour

Section 2

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Classification of this product has been carried out in accordance with GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567). Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Flam. Liq. 3: Flammable liquids, Category 3, H226 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Oral), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335

2.2 Label elements

GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Danger

Hazard statements

Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Flam. Liq. 3: H226 - Flammable liquid and vapour. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2 H373 - May cause damage to organs through prolonged or repeated exposure (Oral). Organs affected All gross lesions and masses. STOT SE 3: H335 - May cause respiratory irritation.

Precautionary statements

SECTION 2: HAZARDS IDENTIFICATION (continued) P201: Obtain special instructions before use. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P260: Do not breathe vapours P261: Avoid breathing vapours P264: Wash thoroughly after use. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P284: Wear respiratory protection. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P312: Call a POISON CENTER or doctor/physician if you feel unwell. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P370+P378 In case of fire Use Foam extinguisher (AB), Dry Chemical Powder (ABC) Fire Extinguisher, Carbon dioxide extinguisher (BC) to extinguish. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.

Supplemental label elements

EUH204: Contains isocyanates. May produce an allergic reaction.

Hazardous Ingredients

Reaction mass of ethylbenzene and m-xylene and p-xylene; 4,4´-methylenediphenyl diisocyanate, isomers and homologues (CAS: 9016-87-9); Reaction products of 1,1´-methylenebis(4-isocyanatobenzene) in excess with 2,2´-[(methylethylene)bis(oxy)]di (methylethanol), butane-1,3-diol, propane-1,2-diol and 1,1´-methylenebis(4-isocyanatobenzene) homopolymer

Additional information

As from 24 August 2023 adequate training is required before industrial or professional use. RCH004a Persons already sensitised to diisocyanates may develop allergic reactions when using this product. RCH004b Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. RCH004c This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

2.3 Other hazards

Product does not meet PBT/vPvB criteria

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