Note: Ingredients listed on restricted chemical lists
EC/CAS
9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
N/A
EC/CAS
5873-54-1
Name of the chemical
2,4’-Methylenediphenyl diisocyanate
Concentration
N/A
General Information
Revision date
2023-07-20
Product name
10513506 - FIX-R Primer 10 4L
1.2.1 Relevant identified uses
Primers. For professional users/industrial user only
1.2.2. Uses advised against
All uses not specified in this section or in section 7.3
Emergency telephone
+44 (0) 1274 696979
Icons in SDS
Company Information
company name
FIX-R
e-mail address of the competent person responsible for the Safety Data Sheet
sigassured@sigplc.com
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H226, H315, H317, H319, H334, H335, H351, H373, H412
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Classification of this product has been carried out in accordance with GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567). Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412 Carc. 2: Carcinogenicity, Category 2, H351 Eye Irrit. 2: Eye irritation, Category 2, H319 Flam. Liq. 3: Flammable liquids, Category 3, H226 Resp. Sens. 1: Sensitisation, respiratory, Category 1, H334 Skin Irrit. 2: Skin irritation, Category 2, H315 Skin Sens. 1: Sensitisation, skin, Category 1, H317 STOT RE 2: Specific target organ toxicity — Repeated exposure, Hazard Category 2 (Oral), H373 STOT SE 3: Respiratory tract toxicity, single exposure, Category 3, H335
2.2 Label elements
GB CLP Regulation (UK S.I. 2019/720 and UK S.I. 2020/1567): Danger
Hazard statements
Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects. Carc. 2: H351 - Suspected of causing cancer. Eye Irrit. 2: H319 - Causes serious eye irritation. Flam. Liq. 3: H226 - Flammable liquid and vapour. Resp. Sens. 1: H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Irrit. 2: H315 - Causes skin irritation. Skin Sens. 1: H317 - May cause an allergic skin reaction. STOT RE 2 H373 - May cause damage to organs through prolonged or repeated exposure (Oral). Organs affected All gross lesions and masses. STOT SE 3: H335 - May cause respiratory irritation.
Precautionary statements
SECTION 2: HAZARDS IDENTIFICATION (continued) P201: Obtain special instructions before use. P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233: Keep container tightly closed. P260: Do not breathe vapours P261: Avoid breathing vapours P264: Wash thoroughly after use. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear protective gloves/face protection/protective clothing/respiratory protection/protective footwear. P284: Wear respiratory protection. P302+P352 IF ON SKIN Wash with plenty of soap and water P304+P340 IF INHALED Remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 IF IN EYES Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned Get medical advice/attention P312: Call a POISON CENTER or doctor/physician if you feel unwell. P342+P311 If experiencing respiratory symptoms Call a POISON CENTER or doctor/physician P370+P378 In case of fire Use Foam extinguisher (AB), Dry Chemical Powder (ABC) Fire Extinguisher, Carbon dioxide extinguisher (BC) to extinguish. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P403+P235: Store in a well-ventilated place. Keep cool. P501: Dispose of the contents and/or its container in line with regulations on dangerous waste or packaging and waste packaging respectively.
Supplemental label elements
EUH204: Contains isocyanates. May produce an allergic reaction.
Hazardous Ingredients
Reaction mass of ethylbenzene and m-xylene and p-xylene; 4,4´-methylenediphenyl diisocyanate, isomers and homologues (CAS: 9016-87-9); Reaction products of 1,1´-methylenebis(4-isocyanatobenzene) in excess with 2,2´-[(methylethylene)bis(oxy)]di (methylethanol), butane-1,3-diol, propane-1,2-diol and 1,1´-methylenebis(4-isocyanatobenzene) homopolymer
Additional information
As from 24 August 2023 adequate training is required before industrial or professional use. RCH004a Persons already sensitised to diisocyanates may develop allergic reactions when using this product. RCH004b Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. RCH004c This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.
2.3 Other hazards
Product does not meet PBT/vPvB criteria