Five Star Crack Repair SLV/Component A

Hazard statements (CLP)

H315, H317, H319, H332, H334, H335, H373

Code

Statements

H315

Causes skin irritation

2.1 Classification of the substance or mixture

Skin Irritation, Category 2 Eye Irritation, Category 2 Acute Toxicity, Category 4 Skin Sensitivity, Category 1 Respiratory Sensitivity, Category 1 STOT Single Exposure, Category 3 STOT Repeated Exposure, Category 2 Label Elements/Hazard Eye Irritation, Category 2 Label Elements/Hazard

Signal word

Danger Warning

Hazard statements

H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. H319 Causes serious eye irritation Precautionary P264 Wash thoroughly after handling.

Precautionary statements

P261 Avoid breathing dust / fume / gas / mist / vapors / spray.

Prevention

P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves / eye protection / face protection. P280 Wear protective gloves / eye protection / face protection

Response

P302+352 IF ON SKIN: Wash with plenty of soap and water. P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P313 Get medical advice / attention. P314 Get Medical advice / attention if you feel unwell. P321 Specific treatment (see information on this label). P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P337+313 If eye irritation persists: Get medical advice / attention. P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing. P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing. P337+313 If eye irritation persists: Get medical advice / attention

Storage

P403+233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up. Handle containers carefully to prevent damage and spillage. Precautions should be taken to minimize exposure to atmospheric humidity or water as carbon dioxide may be formed which, in closed containers can result in pressurization. Care should be taken when re- opening partly used containers. Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used. Examination of lung function should be carried out on a regular basis on persons applying this preparation. Incompatible materials: Water, amines, strong bases, alcohols, metal compounds and surface-active materials Store away from all moisture. If container is exposed to high heat, it can be pressurized and possibly rupture explosively. Keep the container tightly closed and in a cool, well-ventilated place. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (Component A) Exposure Guidelines: Component CAS No. ACGIH (TLV) OSHA (PEL) TWA: 0.005 ppm Ceiling: 0.01 C 0.2 mg/m3 (0.02 Diphenylmethanediisocyanate 0000101-68-8 ppmSkin, S ppm) Polymeric Diphenylmethane Diisocyanate 0009016-87-9 No Established Limit (Benzene,(1-methylpropyl)(1-phenylethyl)-) 0101646-62-2 No Established Limit Benzene, (1-methylpropyl)(phenylmethyl) 0101646-63-3 No Established Limit Benzene, (1-methylpropyl)(2-phenylethyl)- 0142828-65-7 No Established Limit Isocyanates, reaction product of polyol with methylenediphenyl diisocyanate Proprietary No Established Limit Engineering Measures: Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn. PERSONAL PROTECTIVE EQUIPMENT (PPE) Eye/Face Protection: Wear splash proof chemical goggles / full face shield if there is a potential for splashing. Skin / Body Protection: Wear suitable gloves (neoprene, nitrile rubber or PVC) and protective clothing to mitigate exposure. Other Protective Clothing or Use protective clothing which is chemical resistant to this material. Equipment: Safety shoes and boots should also be chemical resistant. Respiratory Protection When the product is sprayed or heated without adequate ventilation, an approved MSHA/NIOSH positive-pressure, supplied-air respirator may be required. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (Component A) Physical State: Liquid Appearance: Yellow Evaporation Rate: Not Available Odor: Slightly Musky Solubility in Water: Insoluble; reacts with water Flash Point: > 300°F (149°C) Specific Gravity (g/cc): approximately 1.117 @ 77°F (25°C) Vapor Density (air = 1): Not Available Vapor Pressure: ~4 x 10-6 mmHg @ 68°F (20°C) VOC Content: None Freezing Point: Not Available pH: Not Available Initial Boiling Point and Boiling Range: 500°F (260°C) (decomposes) SECTION 10: STABILITY AND REACTIVITY (Component A) Reactivity: Polymerization may occur at elevated temperatures in the presence of alkalis, tertiary amines and metal compounds. Stability: Stable under normal circumstances Possibility of Hazardous High heat and fire may produce carbon dioxide, carbon monoxide, Reactions: hydrogen cyanide, and oxides of nitrogen. Conditions to Avoid: No data available Incompatible Materials: Water, amines, strong bases, alcohols, metal compounds and surface- active materials Hazardous Decomposition Carbon monoxide, hydrogen cyanide, nitrogen oxides, aromatic Products: isocyanates, gases/vapors No GHS storage statements.

Disposal

P501 Dispose of contents / container in accordance with local / national regulations. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (Component A) Chemical Name(s) CAS No. No GHS storage statements.

Contains

Diphenylmethanediisocyanate 0000101-68-8 25-50 Benzene, (1-methylpropyl)(phenylmethyl) 0101646-63-3 10-25 Polymeric Diphenylmethane Diisocyanate 0009016-87-9 10-25 (Benzene,(1-methylpropyl)(1-phenylethyl)- ) 0101646-62-2 10-25 Isocyanates, reaction product of polyol with methylenediphenyl diisocyanate Proprietary 10-25 Benzene, (1-methylpropyl)(2-phenylethyl) 0142828-65-7 1.0-10 SECTION 4: FIRST AID MEASURES (Component A) Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth. Eye Contact: Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention. Skin Contact: Remove contaminated clothing. Wash with mild soap and water. Get medical attention if skin irritation or dermatitis persists. Ingestion: Give plenty of water. DO NOT induce vomiting. Call a physician immediately. Other: Referral to a physician is recommended if there is any question about the seriousness of the injury/exposure. If sensitization occurs, future contact with the material should be avoided. Most important symptoms and effects, both acute and delayed Overview: Inhalation: Inhalation at levels above the occupational exposure limit could cause respiratory sensitization and risk of serious damage to respiratory system. The onset of the respiratory symptoms may be delayed for several hours after exposure. A hyper-reactive response to even minimal concentrations of MDI may develop in sensitized persons. Sensitized persons should not be exposed to any mixture containing unreacted MDI. Ingestion: Swallowing small amounts of this material during normal handling is unlikely, and is not likely to cause harmful effects. Swallowing large amounts may be harmful. Inhalation: Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms of breathing difficulties if inhaled. Eyes: Causes serious eye irritation. Skin: May cause an allergic skin reaction. Causes skin irritation. SECTION 5: FIRE-FIGHTING MEASURES (Component A) Extinguishing Media Water spray, dry chemical, alcohol foam, carbon dioxide Special Hazards arising from Hazardous decomposition: Carbon monoxide, hydrogen cyanide, the Substance or Mixture: nitrogen oxides, aromatic isocyanates, gases/vapors Avoid breathing dust / fume / gas / mist / vapors / spray. Advice for Fire-fighters: Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing, and face mask. SECTION 6: ACCIDENTAL RELEASE MEASURES (Component A) Personal Precautions: Avoid all personal contact. In enclosed areas, cleanup personnel should wear self-contained breathing apparatus. Environmental Precautions: Do not allow spills to enter drains or waterways. Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse. SECTION 7: HANDLING AND STORAGE (Component A) Handling: Avoid breathing aerosols, mists and vapors. Avoid contact with skin and eyes. Avoid personal contact with the product or reaction mixture. Use only with adequate ventilation to ensure that the occupational exposure limit is not exceeded. The efficiency of the ventilation system must be monitored regularly because of the possibility of blockage.

TOXICOLOGICAL INFORMATION

Component A) Acute Oral Toxicity: Not determined Ingredient Oral LD50, Skin LD50, Inhalation mg/kg Vapor LC50, Dust/Mist Gas LC50, mg/L/4hr LC50, ppm mg/L/4hr Diphenylmethanediisocyanate 4,700.00, No data (101-68-8) Rat available Category: 5 Benzene, (1-methylpropyl) No data (phenylmethyl) available (101646-63- 3) Polymeric Diphenylmethane 49,000.00, 9,400.00, No data Diisocyanate - (9016-87-9) Rat Rabbit - available Category: NA Category:NA (Benzene,(1-methylpropyl) (1- No data phenylethyl)- ) available (101646- 62-2) Isocyanates, reaction product No data of polyol with available methylenediphenyl diisocyanate - (Proprietary) Benzene, (1-methylpropyl)(2- No data phenylethyl)- - (142828-65-7) available Acute Oral Toxicity: Not Applicable Acute Dermal Toxicity: Not Applicable Acute Inhalation Toxicity: Harmful if inhaled. Skin Irritation: Causes skin irritation. Eye Irritation: Causes serious eye irritation. Respiratory Sensitization: May cause allergy or asthma symptoms of breathing difficulties if inhaled. Skin Sensitization: May cause an allergic skin reaction. Germ Cell Mutagenicity: Not Applicable Carcinogenicity: Not Applicable Reproductive toxicity: Not Applicable STOT – Single exposure: May cause respiratory irritation. STOT – Repeated exposure: May cause damage to organs through prolonged or repeated exposure.

Aspiration hazard

Not Applicable

ECOLOGICAL INFORMATION

Component A) Aquatic Ecotoxicity 96 hr 48 hr EC50 ErC50 algae, Ingredient LC50 fish, crustacea, mg/l mg/l mg/l Diphenylmethanediisocyanate - (101-68-8) Not Available 129.70, Daphnia Not Available magna Benzene, (1-methylpropyl)(phenylmethyl)- - Not Available (101646-63- 3) Polymeric Diphenylmethane Diisocyanate - (9016- Not Available 87-9) (Benzene,(1-methylpropyl)(1-phenylethyl)- ) - Not Available (101646- 62-2) Isocyanates, reaction product of polyol with Not Available methylenediphenyl diisocyanate - (Proprietary) Benzene, (1-methylpropyl)(2-phenylethyl)- - (142828-65- 7) Not Available Persistence and degradability: There is no data available on the preparation itself. Bioaccumulative Potential: Not Measured. Mobility in Soil: No data available. Results of PBT & vPvB Assessment: This product contains no PBT/vPvB chemicals.

Other hazards

No data available. SECTION 13: DISPOSAL CONSIDERATIONS (Component A) If the material as supplied becomes a waste, dispose in accordance with federal, state and local regulations. SECTION 14: TRANSPORT INFORMATION (Component A) US DEPARTMENT of TRANSPORTATION (DOT) Proper Shipping Name: Not regulated Class: None UN #: None Packing Group: None CANADA Transportation of Dangerous Goods (TDG) Proper Shipping Name: Not regulated Class: None UN #: None Packing Group: None INTERNATIONAL AIR TRANSPORTATION Proper Shipping Name (ICAO/IATA): Not regulated Class: None UN #: None Packing Group: None WATER TRANSPORTATION Proper Shipping Name (IMO/IMDG): Not regulated Class: None UN #: None Packing Group: None Marine Pollutant: No SECTION 15: REGULATORY INFORMATION (Component A) Regulatory Overview: The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented. Toxic Substance Control Act All components of this material are either listed or exempt from listing (TSCA): on the TSCA Inventory.

WHMIS Classification

D2A US EPA Tier II Hazards: Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): Yes EPCRA 311/312 Chemicals and RQs (lbs): Diphenylmethanediisocyanate (5000.00) EPCRA 302 Extremely To the best of our knowledge, there are no chemicals at levels which Hazardous: require reporting under this statute. EPCRA 313 Toxic Chemicals: Diphenylmethanediisocyanate Polymeric Diphenylmethane Diisocyanate Proposition 65 - Carcinogens To the best of our knowledge, there are no chemicals at levels which (>0.0%): require reporting under this statute. Proposition 65 - Developmental Toxins To the best of our knowledge, there are no chemicals at levels which (>0.0%): require reporting under this statute. Proposition 65 - Female To the best of our knowledge, there are no chemicals at levels which Repro Toxins (>0.0%): require reporting under this statute. Proposition 65 - Male Repro To the best of our knowledge, there are no chemicals at levels which Toxins (>0.0%): require reporting under this statute. New Jersey RTK Diphenylmethanediisocyanate Substances (>1%): Polymeric Diphenylmethane Diisocyanate Pennsylvania RTK Substances (>1%): Diphenylmethanediisocyanate

Further information

Component A)

HMIS® ratings

Health Flammability

Physical hazards

Personal Protection 2 1 B Disclaimer: This information is furnished without warranty of any kind, expressed or implied. Five Star Products, Inc. bases the information and recommendations in this document on data believed to be current and accurate. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product Name(s): Five Star® Crack Repair SLV/Component B Synonyms: N/A Product Use: Concrete Repair Manufacturer/Supplier Five Star Products, Inc. 60 Parrott Drive Shelton, CT 06484 USA Phone #: 203-336-7900 Emergency Phone #: CHEM-TEL 1-800-255-3924 (Outside the U.S. 1-813-248-0585) SECTION 2: HAZARD(S) IDENTIFICATION-GHS INFORMATION (Component B)