General Information
Version
FSUC4680
Revision date
2025-08-13
Product name
Chlorobenzene
Product Synonyms
Monochlorobenzene; Benzene chloride
CAS No.
108-90-7
supplier name
Fisher Scientific UK
Emergency telephone
(800) 424-9300, 001-703-527-3887
Icons in SDS
Company Information
company name
Fisher Scientific UK
e-mail address of the competent person responsible for the Safety Data Sheet
begel.sdsdesk@thermofisher.com
GHS Information
Signal word
Warning
Hazard Codes
Hazard statements (CLP)
H226, H315, H332, H411
Hazard statements
Code
Statements
H226
Flammable liquid and vapour
Section 2
SECTION 2: Hazards identification
Physical State
Appearance/Odor
Liquid Clear bitter almonds Emergency Overview Flammable liquid and vapor. Toxic to aquatic life with long lasting effects. Causes skin irritation. Harmful if inhaled. Classification of the substance or mixture Flammable liquids Category 3 Acute Inhalation Toxicity - Vapors Category 4 Skin Corrosion/Irritation Category 2 Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 2 Label Elements
Signal word
Warning Hazard Statements H226 - Flammable liquid and vapor H411 - Toxic to aquatic life with long lasting effects H315 - Causes skin irritation H332 - Harmful if inhaled
Prevention
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P233 - Keep container tightly closed P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response
P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor if you feel unwell P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish P362 + P364 - Take off contaminated clothing and wash it before reuse
Storage
P403 + P235 - Store in a well-ventilated place. Keep cool
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Other physicochemical hazards
Vapors may cause flash fire or explosion. Flammable liquid.
Health hazards
Causes skin irritation. Harmful if inhaled.
Environmental hazards
Toxic to aquatic life with long lasting effects. . Will likely be mobile in the environment due to its water solubility. The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. The product is water soluble, and may spread in water systems.
2.3 Other hazards
Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.
2.1 Classification of the substance or mixture
Category 3 Acute Inhalation Toxicity - Vapors Category 4 Skin Corrosion/Irritation Category 2 Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 2