Borane dimethyl sulfide complex, 2M solution in Toluene

Hazard statements (CLP)

H225, H260, H302+H312, H304, H315, H318, H336, H360, H373, H401, H412

Code

Statements

H225

Highly Flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid No information available Stench Emergency Overview Highly flammable liquid and vapor. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness and dizziness. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. In contact with water releases flammable gases which may ignite spontaneously. Harmful if swallowed. Harmful in contact with skin. Causes serious eye damage. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Reacts violently with water. Moisture sensitive. Stench.

2.1 Classification of the substance or mixture

Flammable liquids. Category 2 Substances/mixtures which, in contact with water, emit flammable gases Category 1 Aspiration Toxicity Category 1 Acute Oral Toxicity Category 4 Acute Dermal Toxicity Category 4 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 1B Specific target organ toxicity - (single exposure) Category 3 Specific target organ toxicity - (repeated exposure) Category 2 Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 3

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H336 - May cause drowsiness or dizziness H401 - Toxic to aquatic life H412 - Harmful to aquatic life with long lasting effects H318 - Causes serious eye damage H360 - May damage fertility or the unborn child H373 - May cause damage to organs through prolonged or repeated exposure H302 + H312 - Harmful if swallowed or in contact with skin

Prevention

P201 - Obtain special instructions before use P202 - Do not handle until all safety precautions have been read and understood P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P231 + P232 - Handle and store contents under inert gas. Protect from moisture P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection P273 - Avoid release to the environment

Response

P303 + P361 + P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P302 + P335 + P334 - IF ON SKIN: Brush off loose particles from skin. Immerse in cool water P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P402 + P404 - Store in a dry place. Store in a closed container

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Vapors may cause flash fire or explosion. Highly flammable. Reacts violently with water, liberating extremely flammable gases. Reacts violently with water.

Health hazards

Aspiration hazard if swallowed - can enter lungs and cause damage. Causes skin irritation. May cause drowsiness or dizziness. Harmful if swallowed. Harmful in contact with skin. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.

Environmental hazards

Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Reacts violently with water. . Is not likely mobile in the environment. Is not likely mobile in the environment due its low water solubility. Reacts violently with water. Spillage unlikely to penetrate soil. The product is insoluble and floats on water.

2.3 Other hazards

Stench. Toxic to terrestrial vertebrates. This product does not contain any known or suspected endocrine disruptors.