Titanium(IV) chloride, 1M solution in toluene

2.1 Classification of the substance or mixture

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids Category 2 Acute Inhalation Toxicity - Vapors Category 2 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Central nervous system (CNS), Respiratory system. Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Neurological effects, Eyes, Ears. Aspiration Toxicity Category 1

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor May be fatal if swallowed and enters airways Causes severe skin burns and eye damage May cause respiratory irritation Fatal if inhaled May cause drowsiness or dizziness Suspected of damaging the unborn child May cause damage to organs through prolonged or repeated exposure

Prevention

Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wear respiratory protection Wash face, hands and any exposed skin thoroughly after handling

Response

Immediately call a POISON CENTER or doctor/physician Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Ingestion Rinse mouth Do NOT induce vomiting Fire In case of fire: Use CO2, dry chemical, or foam for extinction

Storage

Store locked up Store in a well-ventilated place. Keep container tightly closed

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

Harmful to aquatic life with long lasting effects Reacts violently with water WARNING Reproductive Harm - https //www.p65warnings.ca.gov/.