tert-Butyllithium, 1.3 M solution in pentane

Hazard statements (CLP)

H224, H225, H250, H260, H304, H313, H314, H336, H411

Code

Statements

H224

Extremely flammable liquid and vapour

SECTION 2: Hazards identification

Physical State

Appearance/Odor

Liquid No information available Emergency Overview Highly flammable liquid and vapor. Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. May be fatal if swallowed and enters airways. May cause drowsiness and dizziness. Extremely flammable liquid and vapor. May be harmful in contact with skin. Causes severe skin burns and eye damage. Toxic to aquatic life with long lasting effects. Reacts violently with water. Moisture sensitive. Air sensitive.

2.1 Classification of the substance or mixture

Flammable liquids. Category 2 Category 1 Substances/mixtures which, in contact with water, emit flammable gases Category 1 Pyrophoric liquids Category 1 Aspiration Toxicity Category 1 Acute Dermal Toxicity Category 5 Skin Corrosion/Irritation Category 1 B Serious Eye Damage/Eye Irritation Category 1 Specific target organ toxicity - (single exposure) Category 3 Acute aquatic toxicity Category 2 Chronic aquatic toxicity Category 2

Signal word

Danger

Hazard statements

H225 - Highly flammable liquid and vapor H224 - Extremely flammable liquid and vapor H260 - In contact with water releases flammable gases which may ignite spontaneously H250 - Catches fire spontaneously if exposed to air H304 - May be fatal if swallowed and enters airways H336 - May cause drowsiness or dizziness H313 - May be harmful in contact with skin H314 - Causes severe skin burns and eye damage H411 - Toxic to aquatic life with long lasting effects

Prevention

P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P222 - Do not allow contact with air P231 + P232 - Handle and store contents under inert gas. Protect from moisture P240 - Ground and bond container and receiving equipment P242 - Use non-sparking tools P243 - Take action to prevent static discharges P264 - Wash face, hands and any exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves/protective clothing/eye protection/face protection

Response

P302 + P334 - IF ON SKIN: Immerse in cool water or wrap in wet bandages P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor P330 - Rinse mouth P331 - Do NOT induce vomiting P363 - Wash contaminated clothing before reuse P370 + P378 - In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish

Storage

P402 + P404 - Store in a dry place. Store in a closed container P422 - Store contents under inert gas

Disposal

P501 - Dispose of contents/ container to an approved waste disposal plant

Other physicochemical hazards

Vapors may cause flash fire or explosion. Highly flammable. Catches fire spontaneously if exposed to air. Reacts violently with water, liberating extremely flammable gases. Extremely flammable. Reacts violently with water.

Health hazards

Aspiration hazard if swallowed - can enter lungs and cause damage. May cause drowsiness or dizziness. May be harmful in contact with skin. Corrosive. Causes skin and eye burns.

Environmental hazards

Toxic to aquatic life with long lasting effects. Reacts violently with water.

2.3 Other hazards

This product does not contain any known or suspected endocrine disruptors. Toxic to terrestrial vertebrates.