Propargyl bromide, 80 wt% solution in toluene, stabilized

2.1 Classification of the substance or mixture

This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids Category 2 Acute oral toxicity Category 3 Skin Corrosion/Irritation Category 1 Serious Eye Damage/Eye Irritation Category 1 Reproductive Toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Target Organs - Respiratory system, Central nervous system (CNS). Specific target organ toxicity - (repeated exposure) Category 2 Target Organs - Liver, Kidney, Ears, Neurological effects, Eyes. Aspiration Toxicity Category 1

Signal word

Danger

Hazard statements

Highly flammable liquid and vapor Toxic if swallowed Causes severe skin burns and eye damage Suspected of damaging fertility or the unborn child May cause respiratory irritation May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways

Prevention

Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool

Response

Immediately call a POISON CENTER or doctor/physician Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Ingestion Do NOT induce vomiting Rinse mouth Fire In case of fire: Use CO2, dry chemical, or foam for extinction

Storage

Store locked up Store in a well-ventilated place. Keep container tightly closed

Disposal

Dispose of contents/container to an approved waste disposal plant

2.3 Other hazards

WARNING Reproductive Harm - https //www.p65warnings.ca.gov/.