PUP 750 B3

fischerwerke GmbH & Co. KG

Revision date : 2024-11-18

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GHS02 GHS07 GHS08
Health risk rating 5
Safety risk rating 4
Environmental risk rating 3

Note: Ingredients listed on restricted chemical lists

EC/CAS

618-498-9/9016-87-9

Name of the chemical

4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)

Concentration

≥40

EC/CAS

287-477-0/85535-85-9

Name of the chemical

Alkanes, C14-17, chloro

Concentration

≥20

General Information

Version

2.0

Revision date

2024-11-18

Product name

PUP 750 B3

Manufacturer Name

fischerwerke GmbH & Co. KG

Emergency telephone

+49(0)6132-84463

Icons in SDS

GHS02 GHS07 GHS08 M004 M009 M010 T013

Company Information

company name

fischerwerke GmbH & Co. KG

e-mail address of the competent person responsible for the Safety Data Sheet

info-sdb@fischer.de, info@fischer.co.uk

GHS Information

Signal word

Danger

Hazard Codes

Hazard statements (CLP)

H222, H229, H315, H317, H319, H332, H334, H335, H351, H362, H373, H413

Hazard statements

Code

Statements

H222

Extremely flammable aerosol

Section 2

SECTION 2: Hazards identification

According to Regulation (EC) No. 1272/2008 (CLP) Classification of the substance or mixture

Adverse physicochemical, human health and environmental effects

Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled

Hazard pictograms

GHS02 GHS07 GHS08

Signal word

Danger

Contains

Isocyanic acid, polymethylenepolyphenylene ester;alkanes, C14-17, chloro; chlorinated paraffins, C14-17 PBTvPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII C o m p o n e n t Substance(s) meeting the PBT criteria of REACH regulation, alkanes, C14-17, chloro; chlorinated paraffins, C14-17 (85535-85-9) in accordance with Annex XIII Substance(s) meeting the vPvB criteria of REACH regulation, alkanes, C14-17, chloro; chlorinated paraffins, C14-17 (85535-85-9) in accordance with Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % C o m p o n e n t Substance(s) not included in the list established in alkanes, C14-17, chloro; chlorinated paraffins, C14-17 (85535-85-9) accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605

Hazard statements

H222 - Extremely flammable aerosol. H229 - Pressurised container: May burst if heated. H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H332 - Harmful if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H362 - May cause harm to breast-fed children. H373 - May cause damage to organs through prolonged or repeated exposure. H413 - May cause long lasting harmful effects to aquatic life.

Precautionary statements

P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P210 - Keep away from heat, hot surfaces, sparks, open flames. No smoking. P211 - Do not spray on an open flame or other ignition source. P251 - Do not pierce or burn, even after use. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves, protective clothing/eye protection/face protection. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 - Store locked up. P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F. P501 - Dispose of contents/container to Collection point. P260 - Do not breathe dust, fume, gas, mist, vapours, spray.

Supplemental label elements

EUH204 - Contains isocyanates. May produce an allergic reaction. EUH066 - Repeated exposure may cause skin dryness or cracking.

Additional information

Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. Without adequate ventilation formation of explosive mixtures may be possible. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. As from 24 August 2023 adequate training is required before industrial or professional use. HSNO Approval Number: HSR002517 Aerosols (Flammable, Carcinogenic).

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol 1 H222;H229 Acute Tox. 4 (Inhalation:dust,mist) H332 Skin Irrit. 2 H315 Eye Irrit. 2 H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 Carc. 2 H351 Lact. H362 STOT SE 3 H335 STOT RE 2 H373 Aquatic Chronic 4 H413 Full text of hazard classes, H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Pressurised container: May burst if heated. Extremely flammable aerosol. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Harmful if inhaled. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.

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