Note: Ingredients listed on restricted chemical lists
EC/CAS
618-498-9/9016-87-9
Name of the chemical
4,4'-Methylendiphenyldiisocyanat tech. (Polymeres) MDI, pMDI (in Form atembarer Aerosole, A-Fraktion)
Concentration
≥10
EC/CAS
202-966-0/101-68-8
Name of the chemical
4,4’-Methylenediphenyl diisocyanate
Concentration
≥1
General Information
Version
1.0
Revision date
2024-11-29
Product name
Express PU
1.2.1 Relevant identified uses
Consumer use,Professional use,Industrial use Industrial/Professional use spec As from 24 August 2023 adequate training is required before industrial or professional use
Manufacturer Name
fischerwerke GmbH & Co. KG
Emergency telephone
+49(0)6132-84463
Icons in SDS
Company Information
company name
fischerwerke GmbH & Co. KG
e-mail address of the competent person responsible for the Safety Data Sheet
info-sdb@fischer.de, info@fischer.co.uk
GHS Information
Signal word
Danger
Hazard Codes
Hazard statements (CLP)
H315, H317, H319, H334, H335, H351, H373
Hazard statements
Code
Statements
H315
Causes skin irritation
Section 2
SECTION 2: Hazards identification
According to Regulation (EC) No. 1272/2008 (CLP)] Classification of the substance or mixture
Hazard statements
see section 16 : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H319 - Causes serious eye irritation. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure.
Adverse physicochemical, human health and environmental effects
Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled
Hazard pictograms
GHS07 GHS08
Signal word
Danger
Contains
Isocyanic acid, polymethylenepolyphenylene ester;4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate;Reaction mass of 4,4'-methylenediphenyl diisocyanate and o-(p- isocyanatobenzyl)phenyl isocyanate
Precautionary statements
P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P260 - Do not breathe spray, vapours, gas, mist, fume, dust. P280 - Wear protective gloves, protective clothing/eye protection/face protection. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P405 - Store locked up. P501 - Dispose of contents/container to Collection point.
Supplemental label elements
EUH204 - Contains isocyanates. May produce an allergic reaction.
Additional information
Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used. As from 24 August 2023 adequate training is required before industrial or professional use.
Other hazards
Contains no PBT and/or vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or substance(s) are not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 H315 Eye Irrit. 2 H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 Carc. 2 H351 STOT SE 3 H335 STOT RE 2 H373 Full text of hazard classes, H- and EUH-statements: see section 16 Adverse physicochemical, human health and environmental effects Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. May cause respiratory irritation. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled.